Synthesis, characterization, electrochemical and spectroscopic studies of two new heteroleptic Ru(II) polypyridyl complexes

Dyes and Pigments

Volumn 75, Issue 2, 2007, Pages 385-394

  Ocakoglu, Kasim ^a   Zafer, Ceylan ^a   Cetinkaya, Bekir ^a   Icli, Siddik ^a  

^a EGE UNIVERSITY   (Turkey)

Author keywords

Charge transfer sensitizer; Photosensitizers; Polypyridyl complexes; Ruthenium complexes

Indexed keywords

CHARACTERIZATION; ELECTROCHEMISTRY; ELECTRON ENERGY LEVELS; ELECTRON TRANSPORT PROPERTIES; EXOTHERMIC REACTIONS; PHOTOSYNTHESIS; RATE CONSTANTS; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

CHARGE TRANSFER SENSITIZER; PHOTODECOMPOSITION; PHOTOSTABILITY; POLYPYRIDYL COMPLEX;

DYES;

ABSORPTION; INFRARED RADIATION; INORGANIC COMPOUND; LUMINESCENCE; MAGNETIC RESONANCE IMAGING; SYNTHESIS; THERMOGRAVIMETRY; ULTRAVIOLET RADIATION;

EID: 34248160958     PISSN: 01437208     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.dyepig.2006.06.016     Document Type: Article

References (49)

1. Juris A., Balzani V., Barigelletti F., Campagna S., Belser P., and Zelewsky A.V. Ruthenium(II) polypyridine complexes: photophysics, photochemistry, electrochemistry, and chemiluminescence. Coordination Chemistry Reviews 277 (1988) 84-85
2. Kalyanasundaram K. Photochemistry of polypyridine and porphyrin complexes (1992), Academic Press Limited, London p. 87-212
3. Campagna S., Pietro C.D., Loiseau F., Maubert B., McClenaghan N., Passalacqua R., et al. Recent advances in luminescent polymetallic dendrimers containing the 2,3-bis(2′-pyridyl)pyrazine bridging ligand. Coordination Chemistry Reviews 229 (2002) 67-74
4. Duer H., and Bossmann S. Ruthenium polypyridine complexes. On the route to biomimetic assemblies as models for the photosynthetic reaction center. Accounts of Chemical Research 34 (2001) 905-917
5. Meijer M.D., Gerard P.M., Klink V., and Koten G.V. Metal-chelating capacities attached to fullerenes. Coordination Chemistry Reviews 230 (2002) 141-163
6. Meyer T.J. Chemical approaches to artificial photosynthesis. Accounts of Chemical Research 22 (1989) 163-170
7. Sun L., Hammarstrom L., Akermark B., and Styring S. Towards artificial photosynthesis: ruthenium-manganese chemistry for energy production. Chemical Society Reviews 30 (2001) 36-49
8. Barigelletti F., and Flamigni L. Photoactive molecular wires based on metal complexes. Chemical Society Reviews 29 (2000) 1-12
9. Robertson N., and McGowan C.A. A comparison of potential molecular wires as components for molecular electronics. Chemical Society Reviews 32 (2003) 96-103
10. Ziessel R., Hissler M., El-Ghayoury A., and Harriman A. Multifunctional transition metal complexes. Information transfer at the molecular level. Coordination Chemistry Reviews 178 180 (1998) 1251-1298
11. De Silva A.P., Gunaratne H.Q.N., Gunnlaugsson T., Huxley A.J.M., McCoy C.P., Rademacher J.T., et al. Signaling recognition events with fluorescent sensors and switches. Chemical Reviews 97 (1997) 1515-1566
12. Ashton P.R., Ballardini R., Balzani V., Credi A., Dress K.R., Ishow E., et al. A photochemically driven molecular-level abacus. Chemistry A European Journal 6 (2000) 3558-3574
13. Metcalfe C., and Thomas J.A. Kinetically inert transition metal complexes that reversibly bind to DNA. Chemical Society Reviews 32 (2003) 215-224
14. Meyer T.J. Photochemistry of metal coordination complexes: metal to ligand charge transfer excited states. Pure and Applied Chemistry 58 (1986) 1193-1206
15. Black D.S.C., Deacon G.B., and Thomas N.C. New decarbonylation reactions of carbonylruthenium(II) complexes. Inorganica Chimica Acta 65 (1982) L75-L76
16. 2+ complexes. Australian Journal of Chemistry 35 (1982) 2445
17. Anderson P.A., Strouse G.F., Treadway J.A., Keene F.R., and Meyer T.J. Black MLCT absorbers. Inorganic Chemistry 33 (1994) 3863
18. Hendersen L.J., Fronczek F.R., and Cherry W.R. Selective perturbation of ligand field excited states in polypyridine ruthenium(II) complexes. Journal of the American Chemical Society 106 (1984) 5876-5879
19. Yamada M., Tanaka Y., Yoshimoto Y., Kuroda S., and Shimao I. Synthesis and properties of diamino-substituted dipyrido[3.2-a:2′,3′-c]phenazine. Bulletin of the Chemical Society of Japan 65 (1992) 1006-1011
20. Calderazzo F., Marchetti F., Pampaloni G., and Passarelli V. Coordination properties of 1,10-phenanthroline-5,6-dione towards group 4 and 5 metals in low and high oxidation states. Journal of the Chemical Society Dalton Transactions (1999) 4389-4396
21. Wang P., Zakeeruddin S.M., Moser J.E., Nazeeruddin M.K., Sekiguchi T., and Grätzel M. A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte. Nature Materials 2 (2003) 402-407
22. Freedman D.A., Evju J.K., and Pomije M.K. Convenient synthesis of tris-heteroleptic ruthenium(II) polypyridyl complexes. Inorganic Chemistry 40 (2001) 5711-5715
23. Strouse G.F., Anderson P.A., Schnoover J.R., Meyer T.J., and Kene F.R. Synthesis of polypyridyl complexes of ruthenium(II) containing three different bidentate ligands. Inorganic Chemistry 31 (1992) 3004-3006
24. Zelewsky A.V., and Gremaund G. Ruthenium(II) complexes with three different diimine ligands. Helvetica Chimica Acta 71 (1988) 1108-1115
25. Juris A., Campagna S., Balzani V., Gremaud G., and Zelewsky A.V. Absorption spectra, luminescence properties, and electrochemical behavior of tris-heteroleptic ruthenium(II) polypyridine complexes. Inorganic Chemistry 27 (1988) 3652-3655
26. Thummel R.P., Lefoulon F., and Chirayil S. A ruthenium tris(diimine) complex with three different ligands. Inorganic Chemistry 26 (1987) 3072-3074
27. Anderson P.A., Deacon G.B., Harman K.H., Keene F.R., Meyer T.J., Reitsma D.A., et al. Designed synthesis of mononuclear tris(heteroleptic) ruthenium complexes containing bidentate polypyridyl ligands. Inorganic Chemistry 34 (1995) 6145
28. Zakeeruddin S.M., Nazeeruddin M.K., Humphry-Baker R., and Grätzel M. Stepwise assembly of tris-heteroleptic polypyridyl complexes of ruthenium(II). Inorganic Chemistry 37 (1998) 5251-5259
29. 2 films. Langmuir 18 (2002) 952-954
30. Nazeeruddin M.K., Zakeeruddin S.M., Baker R.H., Jirousek M., Liska P., Vlachopoulos N., et al. Acid-base equilibria of (2,2′-bipyridyl-4,4′-dicarboxylic acid)ruthenium(II) complexes and the effect of protonation on charge-transfer sensitization of nanocrystalline titania. Inorganic Chemistry 38 (1999) 6298-6305
31. -) on nanocrystalline titanium dioxide electrodes. Journal of the American Chemical Society 115 (1993) 6382-6390
32. Belser P., Zelewsky A.V., Jurius A., Barigelletti F., and Balzani V. Luminescence of dichlorobis(diimine)ruthenium complexes. Gazzetta Chimica Italiana 113 (1983) 731
33. Wajda S., and Rachlewicz K. Spectroscopic properties and bonding character of thiocyanate ligand in some pyridine and 2,2′-dipyridyl ruthenium(II) mixed complexes. Inorganica Chimica Acta 31 (1978) 35-40
34. Nakamoto K. Infrared and Raman spectra of inorganic and coordination compounds (1970), Wiley-Interscience, New York
35. Herber R.H., Nan G., Potenza J.A., Schugar H.J., and Bino A. Bis(2,2′-bipyridine)bis(isothiocyanato)ruthenium. Solvate (solvate = acetonitrile, DMSO) and related compounds: crystal structure, VTFTIR and NMR study. Inorganic Chemistry 28 (1989) 938-942
36. Orellana G., Alvarez-İbarra C., and Santoro J. Hydrogen-1 and carbon-13 NMR coordination-induced shifts in a series of tris(α-diimine)ruthenium(II) complexes containing pyridine, pyrazine, and thiazole moieties. Inorganic Chemistry 27 (1988) 1025-1030
37. Cook M.J., Lewis A.P., and McAuliffe G.S.G. Luminescent metal complexes 4 - carbon-13 NMR spectra of the tris chelates of substituted 2,2′-bipyridyls and 1,10-phenanthrolines with ruthenium(II) and osmium(II). Organic Magnetic Resonance 22 (1984) 388-394
38. Kohle O., Ruile S., and Grätzel M. Ruthenium(II) charge-transfer sensitizers containing 4,4′-dicarboxy-2,2′-bipyridine. Synthesis, properties, and bonding mode of coordinated thio- and selenocyanates. Inorganic Chemistry 35 (1996) 4779-4787
39. 2 films. Thermochimica Acta 348 (2000) 105-114
40. Root M.J., Sullivan B.P., Meyer T.J., and Deutsch E. Thioether, thiolato, and 1,1-dithioato complexes of bis(2,2′-bipyridine)ruthenium(II) and bis(2,2′-bipyridine)osmium(II). Inorganic Chemistry 24 (1985) 2731-2739
41. Wang Y., Perez W., Zheng G.Y., and Rillema D.P. Syntheses and electrochemical, photophysical, and photochemical properties of ruthenium(II) 4,5-diazafluorenone complexes and their ketal derivatives. Inorganic Chemistry 37 (1998) 2051-2059
42. Gregg B.A., Sprague J., and Peterson M.W. Long-range singlet energy transfer in perylene bis(phenethylimide) films. The Journal of Physical Chemistry B 101 (1997) 5362-5369
43. Icli S., Demic S., Dindar B., Doroshenko A.O., and Timur C. Photophysical and photochemical properties of a water-soluble perylenediimide derivative. Journal of Photochemistry and Photobiology A Chemistry 136 (2000) 15-24
44. Turro NJ, Benjamin WA. Molecular photochemistry. London; 1965. p. 4-48.
45. El-Daly S.A. Spectral, lifetime, fluorescence quenching, energy transfer and photodecomposition of N,N′-bis(2,6-dimethyl phenyl)-3,4:9,10-perylentetracarboxylic diimide (DXP). Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy 55 (1999) 143
46. İçli S., İcil H., Whitten D.G., Sayil C., and Dityapak I. Fluorescence quenching between strong π-electron donor-acceptors of carbazolocarbazole and tetranitrofluorenone leading to electron transfer. Journal of Luminescence 75 (1997) 353-359
47. İçli S., Astley A.S., Timur C., Anaç O., Sezer O., and Dabak K. Fluorescence emission studies on 1-phenyl-4-aroyl (and acyl)-1H-1,2,3-triazoles. Journal of Luminescence 82 (1999) 41-48
48. Kavarnos G.J., and Turro N.J. Photosensitization by reversible electron transfer: theories, experimental evidence, and examples. Chemical Reviews 86 (1986) 401-449
49. Jones G., Griffin S.F., Choi C.Y., and Bergmark W.R. Electron donor-acceptor quenching and photoinduced electron transfer for coumarin dyes. The Journal of Organic Chemistry 49 (1984) 2705-2708