A new composition for co(II)-porphyrin-based membranes used in thiocyanate-selective electrodes

Sensors

Volumn 6, Issue 8, 2006, Pages 892-900

  Vlascici, Dana ^a   Fagadar Cosma, Eugenia ^b   Bizerea Spiridon, Otilia ^a  

^a WEST UNIVERSITY OF TIMISOARA   (Romania)

^b ACADEMY OF ROMANIAN SCIENTISTS   (Romania)

Author keywords

Anion selective electrode; Metalloporphyrins; Near Nernstian slope; Thiocyanate

Indexed keywords

ELECTRODES; IONOPHORES; MEMBRANES; NEGATIVE IONS; POLYMER MEMBRANE ELECTRODES; PORPHYRINS; SLOPE STABILITY;

ANION SELECTIVE ELECTRODES; CONCENTRATION RANGES; METALLO-PORPHYRINS; NEAR-NERNSTIAN SLOPE; POLYVINYL CHLORIDE (PVC); POTENTIOMETRIC RESPONSE; THIOCYANATE; THIOCYANATE SELECTIVE ELECTRODES;

POLYVINYL CHLORIDES;

EID: 34248153226     PISSN: 14243210     EISSN: 14248220     Source Type: Journal    
DOI: 10.3390/s6080892     Document Type: Article

References (15)

1. Malinowska, E.; Meyerhoff, M.E.; Role of axial ligation on potentiometric response of Co(III) tetraphenylporphyrin-doped polymeric membrane to nitrite ion, Anal. Chim. Acta 1995, 300, 33-43.
2. Bakker, E.; Pretsch, E. Lipophilicity of tetraphenylborate derivatives as anionic sites in neutral carrier-based solvent polymeric membranes of corresponding ion-selective electrochemical and optical sensors, Anal. Chim. Acta 1995, 309, 7-17.
3. Chaniotakis, N.A.; Chasser, A.M.; Meyerhoff, M.E.; Groves, J.T. Influence of porphyrin structure on anion selectivities of manganese (III) porphyrin-based membrane electrodes, Anal. Chem. 1988, 60, 185-188.
4. Shamsipur, M.; Khayatian, G.; Tangestaninejad, S. Thiocyanate-selective membrane electrode based on (octabromotetraphenylporphyinato) manganese(III) chloride, Electroanalysis 1999, 11, 1340-1348.
5. Khorasani, J.H.; Amini, M.K.; Mataghi, H.; Tangestaninejad, S.; Moghadam, M. Manganese porphyrin derivatives as ionophores for thiocyanate-selective electrodes: the influence of porphyrin substituents and additives on the response properties, Sensors and Acuators B 2002, 87, 448-456.
6. Bakker, E.; Malinowska, E.; Schiller, R.D.; Meyerhoff, M.E. Anion-selective membrane electrodes based on metalloporphyrins. The influence of lipophilic anionic and cationic sites on potentiometric selectivity, Talanta 1994, 41, 881-890.
7. 2- - Selective, Sensors 2002, 2, 164-173.
8. Heliövaara, M. et al. Serum thiocyanate concentration and cigarette smoking in relation to overall mortality and to deaths from coronary heart disease and lung cancer, J. Chron. Dis. 1981, 34, 305-311.
9. Meberg, A.;Marstein, S. Smoking During Pregnancy: Effects on the Fetal Thyroid Function, Acta Paediatrica Scandinavica 1986, 75(5), 762-766.
10. Vlascici, D.; Spiridon-Bizerea, O.; Fǎgǎdar-Cosma, E., Thiocyanate-selective electrode based on rhodium porphyrin derivates, J. Optoelectron. Adv. Mat. 2006, 8(2), 883-887
11. Huang, X.; Chai, Y.; Yuan, R.; Wang, X.; Li, Q., Highly selective thiocyanate electrode based on bis-[N-(2hydroxyethyl)salicylaldimino]copper(II) complex as a neutral carrier, Anal. Sci., 2004, 20, 1185-1188
12. Umezawa, Y.; Buhlmann, P.; Umezawa, K.; Tohda, K.; Amemiya, S. Potentiometric selectivity coefficients of ion-selective electrodes. Part I. Inorganic cations, Pure Appl. Chem. 2002, 74 (6), 923-994.
13. Walker, F. A. An ESR Study of Coordination to the Fifth and Sixth Position of α, β, γ, δ-Tetra-(p-methoxyphenyl) porphinatocobalt(II). J. Am. Chem. Soc. 1970, 92, 4235-4244.
14. Adler, A.D.; Longo, F.R.; Goldmacher, J.; Assour, J.; Korsakoff, L. A simplified synthesis for meso-tetraphenylporphine. J. Org. Chem. 1967, 32, 476-487.
15. Dorough, G.D.; Miller, J.R.; Huennekens, P.M. Spectra of the Metallo-derivatives of α,β,γ,δ-Tetraphenylporphine, J. Am. Chem.Soc. 1951, 73, 4315-4320.