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Volumn 12, Issue 4, 2007, Pages 716-722

Synthesis and X-ray structure of the inclusion complex of dodecamethylcucurbit[6]uril with 1,4-dihydroxybenzene

Author keywords

Crystal structure; Dodecamethylcucurbit 6 uril; Inclusion host guest complex

Indexed keywords

BRIDGED COMPOUND; CUCURBIT(6)URIL; HYDROQUINONE; HYDROQUINONE DERIVATIVE; IMIDAZOLE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 34247869830     PISSN: None     EISSN: 14203049     Source Type: Journal    
DOI: 10.3390/12040716     Document Type: Article
Times cited : (27)

References (24)
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    • We have found that the symmetry of fully methyl-substituted Q[5] (DEMeQ[5]) is higher than that of the partially methyl-substituted Q[5]; the corresponding dipole (0.0393 Debye) is quite smaller than that of dimethyl-substituted Q[5], (0.7444 Debye), or hexamethyl-substituted Q[5] (1.2115 Debye). The normal Q[5] has the smallest dipole, 0.0216 Debye, due to its high symmetry. On the other hand, among the four Q[5]s, HMeQ[5] has the best water solubility (up to 17 g/100 g water); while the Q[5] has the least water solubility (only 0.03 g/100 g water). The order of dipoles of the four Q[5]s is qualitatively consistent with that of the solubility of these Q[5]s, that is HMeQ[5] > DMeQ[5] > DEMeQ[5] > Q[5].
    • We have found that the symmetry of fully methyl-substituted Q[5] (DEMeQ[5]) is higher than that of the partially methyl-substituted Q[5]; the corresponding dipole (0.0393 Debye) is quite smaller than that of dimethyl-substituted Q[5], (0.7444 Debye), or hexamethyl-substituted Q[5] (1.2115 Debye). The normal Q[5] has the smallest dipole, 0.0216 Debye, due to its high symmetry. On the other hand, among the four Q[5]s, HMeQ[5] has the best water solubility (up to 17 g/100 g water); while the Q[5] has the least water solubility (only 0.03 g/100 g water). The order of dipoles of the four Q[5]s is qualitatively consistent with that of the solubility of these Q[5]s, that is HMeQ[5] > DMeQ[5] > DEMeQ[5] > Q[5].
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.