Direct measurements of deuterium kinetic isotope effects in anionic, gas-phase substitution and elimination reactions

Journal of the American Chemical Society

Volumn 129, Issue 17, 2007, Pages 5330-5331

  Gronert, Scott ^a,b   Fagin, Adelaide E ^a   Wong, Lawrence ^a  

^a SAN FRANCISCO STATE UNIVERSITY   (United States)

^b VIRGINIA COMMONWEALTH UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANION; ISOTOPE;

ARTICLE; ELIMINATION REACTION; GAS; ION TRANSPORT; KINETICS; MASS SPECTROMETRY; ROOM TEMPERATURE; SUBSTITUTION REACTION;

EID: 34247863742     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja070093l     Document Type: Article

References (23)

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20. D.
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22. A truncated Boltzmann distribution would have the same effect.
23. 3 also suggest an E2 isotope effect of about 7 with these nucleophiles.