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Volumn 111, Issue 15, 2007, Pages 2811-2813

Primary photoreactions of the 3′,5′-dimethoxybenzoin cage and determination of the release rate in polar media

Author keywords

[No Author keywords available]

Indexed keywords

PHOTOEXCITATION; PROTEIN FOLDING; SOLVENTS; WATER;

EID: 34247622809     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp071350b     Document Type: Article
Times cited : (17)

References (27)
  • 2
    • 68049115101 scopus 로고    scopus 로고
    • Goeldner, M, Givens, R. S, Eds, Wiley-VCH: Weinheim
    • (b) Dynamic Studies in Biology; Goeldner, M., Givens, R. S., Eds., Wiley-VCH: Weinheim, 2005.
    • (2005) Dynamic Studies in Biology
  • 18
    • 34247618208 scopus 로고    scopus 로고
    • The reaction was performed with (diethylamino)sulfur trifluoride (DAST) in dichloromethane at -80 °C
    • DMB fluoride was prepared by substitution of the hydroxyl group of DMB (ref 3a) by fluorine
    • DMB fluoride was prepared by substitution of the hydroxyl group of DMB (ref 3a) by fluorine. The reaction was performed with (diethylamino)sulfur trifluoride (DAST) in dichloromethane at -80 °C. The product was purified by column chromatography (silica gel, dichloromethane).
    • The product was purified by column chromatography (silica gel, dichloromethane)
  • 19
    • 34247572884 scopus 로고    scopus 로고
    • The amount of conversion was determined by GC/MS analysis, actinometry was done with ferrioxalate. The standard error defines reproducibility
    • The amount of conversion was determined by GC/MS analysis, actinometry was done with ferrioxalate. The standard error defines reproducibility.
  • 21
    • 34247647452 scopus 로고    scopus 로고
    • The rate constant is not accurately defined, because the reaction end point is not reached at the end of the delay line 1.85 ns
    • The rate constant is not accurately defined, because the reaction end point is not reached at the end of the delay line (1.85 ns).
  • 24
    • 0033552267 scopus 로고    scopus 로고
    • 1,3-Diphenyl-1,3-cyclopentanediyl radicals absorb at 320 nm: Kita, F.; Adam, W.; Jordan, P.; Nau, W. M.; Wirz, J. J. Am. Chem. Soc. 1999, 121, 9265-9275.
    • 1,3-Diphenyl-1,3-cyclopentanediyl radicals absorb at 320 nm: Kita, F.; Adam, W.; Jordan, P.; Nau, W. M.; Wirz, J. J. Am. Chem. Soc. 1999, 121, 9265-9275.
  • 27
    • 34247569373 scopus 로고    scopus 로고
    • Rock and Chan gave a lower limit of 5 ps for the lifetime of intermediate D assuming diffusion-controlled reaction with water.
    • Rock and Chan gave a lower limit of 5 ps for the lifetime of intermediate D assuming diffusion-controlled reaction with water.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.