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An example of an Ir(V) intermediate has been reported in the silane activation: Klei, S. R.: Tilley, T. D.: Bergman, R. G. J. Am. Chem. Soc. 2000, 122, 1816-1817.
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Examples of activation of aldehydes by a cationic methyl Rh(III) complex has been reported but the mechanism is not defined.4
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A larger deviation in the linear region from experimental points was observed using σp, indicating little resonance interaction
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+, indicating little resonance interaction.
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