A novel method to quantify the amount of surfactant at the oil/water interface and to determine total interfacial area of emulsions

Journal of Colloid and Interface Science

Volumn 310, Issue 2, 2007, Pages 590-598

  James Smith, Monica A ^a,c   Alford, Kile ^a   Shah, Dinesh O ^a,b,c  

^a University of Florida   (United States)

^b UNIVERSITY OF FLORIDA COLLEGE OF MEDICINE   (United States)

^c UNIVERSITY OF FLORIDA   (United States)

Author keywords

Droplet size; Effect of oil chain length; Effect of SDS concentration; Light scattering; Oil in water emulsion; Partitioning; Sodium dodecyl sulfate; Total interfacial area; Ultrafiltration

Indexed keywords

DROPS; EMULSIONS; INTERFACES (MATERIALS); LIGHT SCATTERING; MOLECULAR WEIGHT; ULTRAFILTRATION;

DROPLET SIZE; OIL CHAIN LENGTH; OIL IN WATER EMULSION; SODIUM DODECYL SULFATE (SDS); TOTAL INTERFACIAL AREA;

SURFACE ACTIVE AGENTS;

CARBON; DODECYL SULFATE SODIUM; OIL; SURFACTANT; WATER;

ARTICLE; EMULSION; FILTRATION; LIGHT SCATTERING; MOLECULAR WEIGHT; NANOPORE; PRIORITY JOURNAL; SURFACE PROPERTY; ULTRAFILTRATION;

ALKANES; EMULSIONS; FATTY ALCOHOLS; MEMBRANES, ARTIFICIAL; OILS; PHASE TRANSITION; SENSITIVITY AND SPECIFICITY; SODIUM DODECYL SULFATE; SURFACE-ACTIVE AGENTS; ULTRAFILTRATION; WATER;

EID: 34247518096     PISSN: 00219797     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jcis.2007.01.085     Document Type: Article

References (30)

1. Shinoda K., and Friberg S. Emulsions and Solubilization (1986), Wiley, New York
2. Oh S.G., Jobalia M., and Shah D.O. J. Colloid Interface Sci. 156 2 (1993) 511-514
3. Becher P. Emulsions: Theory and Practice. second ed. (1965), Reinhold, New York
4. Rosen M.J. Surfactants and Interfacial Phenomena. third ed. (2004), Wiley, Hoboken, NJ
5. Walstra P. In: Becher P. (Ed). Encyclopedia of Emulsion Technology (1983), Dekker, New York 57-128
6. Cosgrove T., Phipps J.S., and Richardson R.M. Colloids Surf. 62 3 (1992) 199-206
7. Staples E., Penfold J., and Tucker I. J. Phys. Chem. B 104 3 (2000) 606-614
8. Midura R.J., and Yanagishita M. Anal. Biochem. 228 2 (1995) 318-322
9. Ray A., Reynolds J.A., Polet H., and Steinhardt J. Biochemistry 5 8 (1966) 2606
10. Rump H.H. Laboratory Manual for Examination of Water, Waste Water and Soil (1999), Wiley-VCH Verlag, Weinheim
11. Adamson A.W. Physical Chemistry of Surfaces. fourth ed. (1982), New York, Wiley
12. Kong L., Beattie J.K., and Hunter R.J. Aust. J. Chem. 54 8 (2001) 503-511
13. Rehfeld S. J. Phys. Chem. 71 5 (1967) 738
14. van deHulst H.C. Light Scattering by Small Particles (1981), Dover, New York
15. Hallwort G.W., and Carless J.E. J. Pharm. Pharmacol. 24 (1972) 71
16. Hallwort G.W., and Carless J.E. J. Pharm. Pharmacol. 25 (1973) P87-P95
17. Patist A., Chhabra V., Pagidipati R., Shah R., and Shah D.O. Langmuir 13 3 (1997) 432-434
18. Cameron A., and Crouch R.F. Nature (London) 198 4879 (1963) 475-476
19. Sharma M.K., Shah D.O., and Brigham W.E. Ind. Eng. Chem. Res. 23 2 (1984) 213-220
20. Shiao S.Y., Chhabra V., Patist A., Free M.L., Huibers P.D.T., Gregory A., Patel S., and Shah D.O. Adv. Colloid Interface Sci. 74 (1998) 1-29
21. Chattopadhyay A.K., Shah D.O., and Ghaicha L. Langmuir 8 1 (1992) 27-30
22. Patist A., Axelberd T., and Shah D.O. J. Colloid Interface Sci. 208 1 (1998) 259-265
23. Rabinovich Y.I., Pandey S., Shah D.O., and Moudgil B.M. Langmuir 22 16 (2006) 6858-6862
24. Shiao S.Y., Patist A., Free M.L., Chhabra V., Huibers P.D.T., Gregory A., Patel S., and Shah D.O. Colloids Surf. A 128 1-3 (1997) 197-208
25. Leung R., and Shah D.O. J. Colloid Interface Sci. 111 1 (1986) 286-287
26. Chiang M.Y., Chan K.S., and Shah D.O. J. Can. Pet. Technol. 17 4 (1978) 1-8
27. Bansal V.K., O'Connell J.P., and Shah D.O. J. Colloid Interface Sci. 75 2 (1980) 462-475
28. Leung R., and Shah D.O. J. Colloid Interface Sci. 113 2 (1986) 484-499
29. Weiss J., Herrmann N., and McClements D.J. Langmuir 15 20 (1999) 6652-6657
30. Tadros T., and Vincent B. In: Becher P. (Ed). Encyclopedia of Emulsion Technology: Basic Theory (1983), Dekker, New York/Basel 129