Effects of dissolved carbonates and carboxylates on the sorption of thiuram disulfide pesticides on humic acids and model surfaces

Environmental Science and Technology

Volumn 41, Issue 8, 2007, Pages 2782-2788

  Stathi, Panagiota ^a   Louloudi, Maria ^a   Deligiannakis, Yiannis ^a  

^a UNIVERSITY OF IOANNINA   (Greece)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONATES; DISSOLUTION; ESTERS; HYDROPHOBICITY; PH EFFECTS; SORPTION;

DEPROTONATED CARBOXYLATES; INTERACTION PHENOMENA; THIRAM;

PESTICIDES;

BICARBONATE; CARBONIC ACID DERIVATIVE; CARBOXYLIC ACID DERIVATIVE; DISULFIRAM; FORMIC ACID; HUMIC ACID; OXALIC ACID; PESTICIDE; SILICON DIOXIDE; THIRAM;

CARBONATES; DISSOLUTION; ESTERS; HYDROPHOBICITY; PESTICIDES; PH EFFECTS; SORPTION;

CARBONATE; CARBOXYLIC ACID; DISSOLVED INORGANIC CARBON; HUMIC ACID; HYDROPHOBICITY; MODEL; PESTICIDE; SOIL POLLUTION; SORPTION; SULFIDE (ORGANIC);

ADSORPTION; ARTICLE; ENVIRONMENTAL IMPACT; HYDROPHOBICITY; PH; SOIL POLLUTION; SURFACE PROPERTY; THEORETICAL MODEL;

ADSORPTION; CARBONATES; CARBOXYLIC ACIDS; HUMIC SUBSTANCES; HYDROGEN-ION CONCENTRATION; PESTICIDE RESIDUES; TEMPERATURE; THIRAM;

EID: 34247210292     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es0630792     Document Type: Article

References (27)

1. Stevenson, J. F. Humus Chemistry: Genesis, Composition, Reactions, John Willey & Sons Inc: New York, 1994.
2. Chiou, T. C. Partition and Adsorption of Organic Contaminants in Environmental Systems; Wiley-Interscience: Hobooken, NJ, 2002.
3. Rutherford, D. W.; Chiou, C. T.; Kile, D. E. Influence of soil organic matter composition on the partition of organic compounds. Environ. Sci. Technol. 1993, 26, 336-340.
4. Luthy, R. G.; Aiken, G. R.; Brusseau, M. L.; Cunningham, S. D.; Gschwend, P. M.; Pignatello, J. J.; Reinhard, M.; Traina, S. J.; Weber, W. J.; Westall, J. C. Sequestration of hydrophobic contaminants by geosorbents. Environ. Sci. Technol. 1997, 12, 3341-3347.
5. Sheng, H. L. G.; Teppen, B. J.; Johnston, C. T.; Boyd, S. A. Sorption and desorption of pesticides by clay minerals and humic acid-clay complexes. Soil Sci. Soc. Am. J. 2003, 67, 122-131.
6. Schwarzenbach, R. P.; Gschwend, P. M.; Imboden, D. M. Environmental Organic Chemistry; John Willey & Sons Inc: New York, 2003.
7. Weber, W. J.; Huang, W.; LeBoeuf, E. J. Geosorbent organic matter and its relationship to the binding and sequestration of organic contaminants. Colloids Surf., A 1999, 151, 167-179.
8. Murphy, E. M.; Zachara, J. M.; Smith, S. C.; Philips, J. L.; Wletsma, T. W. Interactions of hydrophobic organic compounds with mineral-bound humic acids. Environ. Sci. Technol. 1994, 28, 1291-1299.
9. Murphy, E. M.; Zachara, J. M.; Smith, S. C. Influence of mineral-bound humic substances on the sorption of hydrophobic organic compounds. Environ. Sci. Technol. 1990, 24, 1507-1516.
10. Koopal, L. K.; Yang, Y.; Minnard, A. J.; Theunissen, P. L. M.; Van Riemsdijk, W. H. Chemical immobilization of humic acids on silica. Colloids Surf., A 1998, 141, 385-395.
11. Yang, Y.; Koopal, L. K. Immobilization of humic acids and binding of nitrophenol to immobilized humics. Colloids Surf., A 1999, 151, 201-212.
12. Chiou, T. C.; Kile, D. E. Deviations from sorption linearity on soils of polar and non polar organic compounds at low relative concentrations. Environ. Sci. Technol. 1998, 32, 338-343.
13. Spurlock, F. C.; Biggar, J. W. Thermodynamics of organic chemical partition in soils. 2. Nonlinear partition of substituted phenylureas from aqueous solution. Environ. Sci. Technol. 1994, 28, 996-1002.
14. Leboeuf, E. J.; Weber, W. J. A distributed reactivity model for sorption by soils and sediments. 9. Sorbent organic domains: Discovery of a humic acid glass transition and an argument for a polymer-based model. Environ. Sci. Technol. 1997, 36, 1697-1702.
15. Xia, G. S.; Ball, W. P. Polani-based models for the competitive sorption of low polarity organic contaminants on a natural sorbent. Environ. Sci. Technol. 2000, 34, 1246-1253.
16. Pignatello, J. J. Soil organic matter as a nanopopous sorbent of organic pollutants. Adv. Colloid Interface Sci. 1998, 77, 445-467.
17. Sheng, G. Y.; Johnston, C. T.; Teppen, B. J.; Boyd, S. A. Potential contributions of smectite clays and organic matter to pesticide retention in soils. J. Agric. Food Chem. 2001, 49, 2899-2907.
18. Wauchope, R. D.; Yeh, S.; Lindres, J. B. H. J.; Kloskowski, R.; Tanaka, K.; Rubin, B.; Katayama, A.; Kördel, W.; Gerstl, Z.; Lane, M.; Unsworth, J. B. Pesticide soil sorption parameters: theory, measurement, uses, limitations and reliability. Pest Manage. Sci. 2002, 58, 419-445.
19. Morgenroth, U. Adsorption/Desorption of 14C-Thiram on Four Soils; RCC project 354780; RCC Umweltchemie AG: Switzerland, 1995.
20. Stathi, P.; Christoforidis, K. C.; Tsipis, A.; Hela, D. G.; Deligiannakis, Y. Effects of dissolved carboxylates and carbonates on the adsorption properties of thiuram disulfate pesticides. Environ. Sci. Technol. 2006, 40, 221-227.
21. Butterworth, A. J.; Clark, J. H.; Walton, P. H.; Barlow, S. J. Environmentally friendly catalysis using supported reagents: Catalytic epoxidation using a chemically modified silica gel. Chem. Commun. 1996, 1859-1860.
22. 2+ on restricted phyllomorphous clay. Langmuir 2006, 22, 1859-1860.
23. Procopio, J. J.; Escribano, M. T. S.; Hernandez, L. H. Fresenius J. Anal. Chem. 1988, 311, 27-29.
24. Herbelin, A. L.; Westall, J. C. FITEQL 4.0 A Computer Program for Determining Chemical Equilibrium Constants from Experimental Data; report 99-01; Department of Chemistry Oregon State University: Corvalis Oregon, 1999.
25. Giles, C. H.; Smith, D.; Huiton, A. General treatment and classification of solute adsorption-isotherm. 1. Theoretical. J. Colloid Interface Sci. 1974, 47, 85-91.
26. Kosmulski, M. Chemical Properties of Material Surfaces; CRC Press: Boca Raton, FL, 2001.
27. 4 concentration. Environ. Sci. Technol. 1995, 29, 951-959.