Synthesis and proton conductivity of anhydrous dendritic electrolytes

Central European Journal of Chemistry

Volumn 5, Issue 2, 2007, Pages 546-556

  Şenel, Mehmet ^a   Tülü, Metin ^a   Bozkurt, Ayhan ^a  

^a FATIH UNIVERSITY   (Turkey)

Author keywords

Dendritic electrolyte; Imidazole; Proton conductivity; Thermal properties

Indexed keywords

EID: 34247186307     PISSN: 18951066     EISSN: 16443624     Source Type: Journal    
DOI: 10.2478/s11532-007-0016-x     Document Type: Article

References (24)

1. Y.G. Wang and X.G. Zhang: "All solid-state supercapacitor with phosphotungstic acid as the proton-conducting electrolyte", Solid State Ionics, Vol. 166, (2004), pp. 61-67.
2. A. Bozkurt: "Application of Proton Conducting Polymer Electrolytes to Electrochromic Devices", Turk. J. Chem., Vol. 26, (2002), pp. 663-668.
3. P. Jannasch: "Recent developments in high-temperature proton conducting polymer electrolyte membranes", Curr. Opin. Colloid In., Vol. 8, (2003), pp. 96-102.
4. A. Bozkurt and W.H. Meyer: "Proton conducting blends of poly(4-vinylimidazole) with phosphoric acid", Solid State Ionics, Vol. 138, (2001), pp. 259-265.
5. M.F.H. Schuster and W.H. Meyer: "Anhydrous proton conducting polymers", Annu. Rev. Mater. Res., Vol. 33, (2003), pp. 233-261.
6. M. Yamada and I. Honma: "Alginic acid-imidazole composite material as anhydrous proton conducting membrane", Polymer, Vol. 45, (2004), pp. 8349-8354.
7. A. Bozkurt, W.H. Meyer and G. Wegner: "PAA/imidazol-based proton conducting polymer electrolytes", J. Power Sources, Vol. 123, (2003), pp. 126-131.
8. A. Bozkurt: "Anhydrous Proton Conductive Polystyrene Sulfonic Acid Membranes", Turk J. Chem., Vol. 29, (2005), pp. 117-123.
9. x)", Solid State Ionics, Vol. 28/30, (1988), pp. 969-974.
10. W.H. Meyer: "Polymer Electrolytes for Lithium-Ion Batteries", Adv. Mater., Vol. 10, (1998), pp. 439-448.
11. M.F.H. Schuster, W.H. Meyer, G. Wegner, H.G. Herz, M. Ise, M. Schuster, K.D. Kreuer and J. Maier: "Proton mobility in oligomer-bound proton solvents: Imidazole immobilization via flexible spacers", Solid State Ionics, Vol. 145, (2001), pp. 85-92.
12. G.R. Newkome, R.K. Behera, C.N. Moorefield and G.R. Baker: "Cascade polymers: Synthesis and characterisation of four-directional spherical dendritic macromolecules based on adamantane", J. Org. Chem., Vol. 57, (1992), pp. 358-362.
13. J.J. Przyluski, W. Wieczorec and S. Glowinkowski: "Novel Proton Polymer Ionic Conductors", Electrochim. Acta, Vol. 37, (1992), pp. 1733-1745.
14. G.R. Newkome, C.N. Moorefield, G.R. Baker, R.K. Behara, G.H. Escamilia and M.J. Saunders: "Supramolecular self-assemblies of two-directional cascade molecules: Automorphogenesis", Angew. Chem., Vol 31, (1992), pp. 917-919.
15. H. Namazi and M. Adeli: "Novel linear-globular thermoreversible hydrogel ABA type copolymers from dendritic citric acid as the A blocks and poly(ethyleneglycol) as the B block", Eur. Polym. J., Vol. 39, (2003), pp. 1491-1500.
16. M. Tülü and K.E. Geckeler: "Synthesis and properties of hydrophilic polymers. Part 7. Preparation, characterization and metal complexation of carboxy-functional polyesters based on poly(ethylene glycol)", Polymer Int., Vol. 48, (1999), pp. 909-914.
17. A. Bozkurt and T. Pakula: "Dielectric and dynamic mechanical relaxations in polymer-heterocycle hybrid materials", Chem. Phys. Lett., Vol. 422, (2006) pp. 496-499.
18. W. Münch, K.D. Kreuer, W. Silvestri, J. Maier and G. Seifert: "The diffusion mechanism of an excess proton in imidazole molecule chains: First results of an ab initio molecular dynamics study" Solid State Ionics, Vol. 145, (2001), pp. 437-443.
19. C. Yang, P. Costamagna, S. Srinivasan, J. Benziger and A.B. Bocarsly: "Approaches and technical challenges to high temperature operation of proton exchange membrane fuel cells", J. Power Sources, Vol. 103, (2001), pp. 1-9.
20. F. Sevil and A. Bozkurt: "Proton conducting polymer electrolytes on the basis of poly(vinylphosphonic acid) and imidazole", J. Phys. Chem. Solids, Vol. 65, (2004), pp. 1659-1662.
21. A. Bozkurt and T. Pakula: "Dielectric and dynamic mechanical relaxations in polymer-heterocycle hybrid materials", Chem. Phys. Lett., Vol. 422, (2006), pp. 496-499.
22. M. Yamada and I. Honma: "Proton conducting acid-base mixed materials under water-free condition", Electrochim. Acta, Vol. 48, (2003), pp. 2411-2415.
23. K.D. Kreuer, A. Fuchs, M. Ise, M. Spaeth and J. Maier: "Imidazole and pyrazole-based proton conducting polymers and liquids", Electrochim. Acta, Vol. 43, (1998), pp. 1281-1288.
24. M. Morita, J.L. Qiao, N. Yoshimoto and M. Ishikawa: "Application of proton conducting polymeric electrolytes to electrochemical capacitors", Electrochim. Acta, Vol. 50, (2004), pp. 837-841.