Charge-remote metastable ion decomposition of free fatty acids under FAB MS: Evidence for biradical ion structures

Analytical Chemistry

Volumn 79, Issue 7, 2007, Pages 2822-2826

  Ji, Hong ^a   Morré, Jeff ^a   Voinov, Valery G ^a,b   Deinzer, Max L ^a   Barofsky, Douglas F ^a  

^a OREGON STATE UNIVERSITY   (United States)

^b PACIFIC INSTITUTE OF BIOORGANIC CHEMISTRY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

DECOMPOSITION; DISSOCIATION; FREE RADICALS; HYDROGEN; MASS SPECTROMETRY; NEGATIVE IONS;

BIRADICAL ION STRUCTURES; COLLISIONAL ACTIVATION; ION FORMATION; NEUTRAL LOSSES;

FATTY ACIDS;

CARBOXYLIC ACID; FATTY ACID; HYDROGEN; MONOUNSATURATED FATTY ACID; SATURATED FATTY ACID;

ARTICLE; CHEMICAL STRUCTURE; FAST ATOM BOMBARDMENT MASS SPECTROMETRY; LIPID ANALYSIS; LIPID DEGRADATION; MOLECULE; TANDEM MASS SPECTROMETRY;

FATTY ACIDS; FREE RADICALS; IONS; SENSITIVITY AND SPECIFICITY; SPECTROMETRY, MASS, FAST ATOM BOMBARDMENT;

EID: 34247166655     PISSN: 00032700     EISSN: None     Source Type: Journal    
DOI: 10.1021/ac0610356     Document Type: Article

References (38)

1. Tomer, K. B.; Crow, F. W.; Gross, M. L. J. Am. Chem. Soc. 1983, 105, 5487.
2. M. Bambagiotti A., M.; Coran, S. A.; Giannellini, V.; Vincieri, F. F.; Daolio, S.; Traldi, P. Org. Mass Spectrom. 1983, 18, 133.
3. (a) Bowie, J. H. Int. J. Mass Spectrom. Ion Phys. 2001, 212, 249.
4. (b) Seto, C.; Grossert, J. S.; Waddle, D. S.; Curtis, J. M.; Boyd, R. K. Int. J. Mass Spectrom. Ion Phys. 1999, 188, 27.
5. (c) Seto, C.; Grossert, J. S.; Waddle, D. S.; Curtis, J. M.; Boyd, R. K. J. Am. Soc. Mass Spectrom. 2001, 12, 571.
6. (d) Contado, M. J.; Adams, J.; Jensen, N. J.; Gross, M. L. J. Am. Soc. Mass Spectrom. 1991, 2, 180.
7. (e) Jensen, N. J.; Tomer, K. B.; Gross, M. L. J. Am. Chem. Soc. 1985, 107, 1863.
8. (f) Huysmans, L.; Nizigiyimana, L.; Van, den Heuvel, H.; Claeys, M. Int. J. Mass Spectrom. 1999, 188, 39.
9. (g) Denekamp, C.; Van den Heuvel, H.; Voinov, V. G.; Claeys, M.; Seto, C.; Grossert, J. S.; Waddell, D. S.; Curtis, J. M.; Boyd, R. K. Rapid Commun. Mass Spectrom. 2000, 14, 1035.
10. (h) Bambagiotti-Alberti, M.; Coran, S. A.; Benvenuti, F.; LoNosto, P.; Catinella, S.; Favretto, D.; Traldi, P. J. Mass Spectrom. 1995, 30, 1742.
11. Griffiths, W. J.; Brown, A.; Reimendal, R.; Yang, Y.; Zhang, J.; Sjövall, J. Rapid Commun. Mass Spectrom. 1996, 10, 1169.
12. Siegel, M. M.; Colthup, N. B. Appl. Specrosc. 1988, 42, 1214.
13. (a) Cheng, C.; Gross, M. L. Mass Spectrom. Rev. 2000, 19, 398.
14. (b) Gross, M. L. Int. J. Mass Spectrom. 2000, 200, 611.
15. Bambagiotti-Alberti, M.; Coran, S.; Giannellini, V.; Favretto, D.; Traldi, P. Rapid Commun. Mass Spectrom. 1994, 8, 439.
16. Laprévote, O.; Girard, C.; Das, B.; Laugel, T.; Roblot, F.; Leboeuf, M.; Cavé, A. Rapid Commun. Mass Spectrom. 1992, 6, 352.
17. Griffiths, W. J.; Yang, Y.; Lindgren, J. Å.; Sjövall, J. Rapid Commun. Mass Spectrom. 1996, 10, 21.
18. Bambagiotti-Alberti, M.; Coran, S.; Vincieri, F. F.; Petrucciani, T.; Traldi, P. Org. Mass Spectrom. 1986, 21, 485.
19. Voinov, V. G.; Claeys, M. Int. J. Mass Spectrom. 2000, 198, 23.
20. Stapel, D.; Brox, O.; Benninghoven, A. Appl. Surf. Sci. 1999, 140, 156.
21. Shiea, J.; Sunner, J. Int. J. Mass Spectrom. Ion Phys. 1991, 109, 265.
22. In a recent review, a new "charge-assisted" mechanism is suggested that leads to terminally unsaturated CRF ions with resonance-stabilized structures: Harvey, D. J. J. Am. Soc. Mass Spectrom. 2005, 16, 280.
23. Boyd, R. K. Mass Spectrom. Rev. 1994, 13, 359, and references therein.
24. Jensen, N. J.; Tomer, K. B.; Gross, M. L. Anal. Chem. 1985, 57, 2018.
25. Voinov, V. G.; Claeys, M. Int. J. Mass Spectrom. 2001, 205, 57.
26. Adams, J.; Gross, M. L. J. Am. Chem. Soc. 1989, 111, 435.
27. Haddon, W. F. Org. Mass Spectrom. 1980, 15, 539-543.
28. Adams, J.; Gross, M. L. J. Am. Chem. Soc. 1986, 108, 6915.
29. Lyon, P. A.; Crow, F. W.; Tomer, K. B.; Gross, M. L. Anal. Chem. 1984, 56, 2278.
30. Dua, S.; Bowie, J. H.; Cerda, B. A.; Wesdemiotis, C.; Raftery, M. J.; Kelly, J. F.; Taylor, M. S.; Blanksby, S. J.; Buntine, M. A. J. Chem. Soc. Perkin Trans. 2 1997, 4, 695.
31. Wysocki, V. H.; and Ross, M. M. Int. J. Mass Spectrom. Ion Phys. 1991, 104, 179.
32. (a) Clayes, M.; Nizigiyimana, L.; Van den Heuvel, H.; Derrick, P. J. Rapid Commun. Mass Spectrom. 1996, 10, 770.
33. (b) Nizigiyimana, L.; Rajan, P. K.; Haemers, A.; Claeys, M.; Derrick, P. J. Rapid Commun. Mass Spectrom. 1997, 11, 1808.
34. (c) Clayes, M.; Nizigiyimana, L; Van den Heuvel, H.; Vedernikova, I.; Haemers, A. J. Mass Spectrom. 1998, 33, 631.
35. (d) Huysmans, L.; Nizigiyimana, L.; Van den Heuvel, H.; Claeys, M. Int. J. Mass Spectrom. 1999, 188, 39.
36. Voinov, V. G.; Van den Heuvel, H.; Claeys, M. J. Mass Spectrom. 2002, 37, 313.
37. Wysocki, V. H.; Ross, M. M.; Horning, S. R.; Cooks, R. G. Rapid Commun. Mass Spectrom. 1988, 2, 214.
38. Holmes, J. L. Org. Mass Spectrom. 1985, 20, 169.