Permeability of water in poly(perfluorosulfonic) acid membrane with different counterions

Journal of Membrane Science

Volumn 295, Issue 1-2, 2007, Pages 21-27

  Suresh, G ^a   Pandey, A K ^a   Goswami, A ^a  

^a BHABHA ATOMIC RESEARCH CENTRE   (India)

Author keywords

Ion exchange; Nafion 117; Partition coefficient; Self diffusion coefficient; Water volume fraction

Indexed keywords

PARTITION COEFFICIENT; SELF-DIFFUSION COEFFICIENT; WATER VOLUME FRACTION;

DESORPTION; DIFFUSION; ION EXCHANGE; MECHANICAL PERMEABILITY; VOLUME FRACTION; WATER;

POLYMERIC MEMBRANES;

CESIUM ION; COPPER ION; EUROPIUM; LITHIUM ION; POLY(PERFLUOROSULFONIC ACID); POTASSIUM ION; PROTON; SODIUM ION; SULFONIC ACID DERIVATIVE; TRITIUM; UNCLASSIFIED DRUG;

DESORPTION; DIFFUSION; ION EXCHANGE; MECHANICAL PERMEABILITY; POLYMERIC MEMBRANES; VOLUME FRACTION; WATER;

ARTICLE; CHEMICAL STRUCTURE; DESORPTION; DIFFUSION COEFFICIENT; ION EXCHANGE; MEMBRANE; PARTITION COEFFICIENT; PRIORITY JOURNAL; SURFACE PROPERTY; WATER PERMEABILITY;

EID: 34247132550     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2007.02.023     Document Type: Article

References (31)

1. Higa M., and Kira A. Theory and simulation of ion transport in nonstationary states against concentration gradients across ion-exchange membranes. J. Phys. Chem. 96 (1992) 9518-9523
2. Pintauro P.N., Tondon R., Chao L., Xu W., and Evilia R. Equilibrium partitioning of monovalent/divalent cation-salt mixture in Nafion ion-exchange membranes. J. Phys. Chem. B 99 (1995) 12915-12924
3. Hollerbach U., Chen D.P., Busath D.D., and Eisenberg B. Predicting function from structure using the Poisson-Nernst-Planck equations: sodium current in the Gramicidin A channel. Langmuir 16 (2000) 5509-5514
4. Mafe S., Manzanares J.A., and Ramirez P. Modeling of surface vs. bulk ionic conductivity in fixed charged membranes. Phys. Chem. Chem. Phys. 5 (2003) 376-383
5. Heitner-Wirguin C. Recent advances in perfluorinated ionomer membranes: structure, properties and applications. J. Membr. Sci. 120 (1996) 1-33
6. Mauritz K.A., and Moore R.B. State of understanding of Nafion. Chem. Rev. 104 (2004) 4535-4585
7. Steck A., and Yeager H.L. Water sorption and cation-exchange selectivity of a perfluorosulfonate ion-exchange polymer. Anal. Chem. 52 (1980) 1215-1218
8. Goswami A., Acharya A., and Pandey A.K. Study of self-diffusion of monovalent and divalent cations in Nafion-117 ion-exchange membrane. J. Phys. Chem. B 105 (2001) 9196-9201
9. + and alkali metal cations. J. Phys. Chem. B 106 (2002) 1267-1278
10. Yeager H.L., and Kipling B. Ionic diffusion and ion clustering in a perfluorosulfonate ion-exchange membrane. J. Phys. Chem. 83 (1979) 1836-1839
11. Yeager H.L., and Steck A. Cation and water diffusion in Nafion ion exchange membranes: influence of polymer structure. J. Electrochem. Soc. 128 (1981) 1880-1884
12. Herrera A., and Yeager H.L. Halide and sulfate ion diffusion in Nafion membranes. J. Electrochem. Soc. 134 (1987) 2446-2451
13. 2 solutions. J. Membr. Sci. 110 (1996) 69-78
14. Verbrugge M.W., Scheneider E.W., Conell R.S., and Hill R.F. The effect of temperature on the equilibrium and transport properties of saturated poly(perfluorosulfonic acid) membranes. J. Electrochem. Soc. 139 (1992) 3421-3428
15. Rollet A.-L., Simonin J.P., and Turq P. Study of self-diffusion of alkali metal cations inside a Nafion membrane. Phys. Chem. Chem. Phys. 2 (2000) 1029-1034
16. R membrane from ion-exchange measurements. J. Phys. Chem. 98 (1994) 6352-6358
17. R perfluorosulfonic membranes. J. Electrochem. Soc. 144 (1997) 4236-4242
18. Millet P. Determination of self-diffusion coefficients from conductivity measurements in perfluorinated ionomer membranes. J. Membr. Sci. 50 (1990) 325-328
19. R perfluorosulfonic membrane. J. Membr. Sci. 45 (1989) 37-53
20. Zawodzinski Jr. T.A., Neeman M., Sillerud L.O., and Gottesfeld S. Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranrs. J. Phys. Chem. 95 (1991) 6040-6044
21. Saito M., Hayamizu K., and Okada T. Temperature dependence of ion and water transport in perfluorosulfonated ionomer membranes for fuel cells. J. Phys. Chem. B 109 (2005) 3112-3119
22. Suresh G., Scindia Y.M., Pandey A.K., and Goswami A. Isotopic and ion-exchange kinetics in the Nafion-117 membrane. J. Phys. Chem. B 108 (2004) 4104-4110
23. Suresh G., Scindia Y.M., Pandey A.K., and Goswami A. Self-diffusion coefficient of water in Nafion-117 membrane with different monovalent counterions: a radiotracer study. J. Membr. Sci. 250 (2005) 39-45
24. Suresh G., Pandey A.K., and Goswami A. Self-diffusion coefficients of water in Nafion-117 membrane with multivalent counterions. J. Membr. Sci. 284 (2006) 193-197
25. Yasuda H., Lamaze C.E., and Peterlin A. Diffusive and hydraulic permeabilities of water in water-swollen polymer membrane. J. Polym. Sci., Part A-2 9 (1971) 1117-1131
26. Crank J., and Park G.S. Diffusion in Poymer (1968), Academic Press, London Chapter 1
27. Okada T., Xie G., Gorseth O., Kjelstrup S., Nakamura N., and Arimura T. Ion and water transport characteristics of Nafion membranes as electrolytes. Electrochim. Acta 43 (1998) 3741-3747
28. Xia X.-R., Baynes R.E., Monterio-Riviere N.A., and Riviere J.E. Detrmination of the partition coeffcients and absorption kinetics parameters of chemicals in a lipophilic membrane/water system by using a membrane-coated fiber technique. Eur. J. Pharm. Sci. 24 (2005) 15
29. Helfferich F. Ion-Exchange (1962), McGraw-Hill Book Company, New York Chapter 6
30. + and alkali metal cations in perfluorosulfonated ionomer. Electrochim. Acta 50 (2005) 3569-3575
31. James P.J., McMaster T.J., Newton J.M., and Miles M.J. In situ rehydration of perfluorosulphonate ion-exchange membrane studied by AFM. Polymer 41 (2000) 4223-4231