Sulphur mustard vapor breakthrough behaviour on reactive carbon systems

Journal of Hazardous Materials

Volumn 143, Issue 1-2, 2007, Pages 150-155

  Prasad, G K ^a   Mahato, T H ^a   Yadav, S S ^a   Singh, Beer ^a  

^a PD Division   (India)

Author keywords

Active carbon; Breakthrough time; Modified Wheeler equation; Sulphur mustard

Indexed keywords

CONCENTRATION (PROCESS); FILTRATION; KINETIC PARAMETERS; NUMERICAL METHODS; RATE CONSTANTS;

BREAKTHROUGH TIME; KINETIC SATURATION CAPACITY; MODIFIED WHEELER EQUATION; SULFUR MUSTARD;

ACTIVATED CARBON;

ACTIVATED CARBON; CHEMICAL WARFARE AGENT; MUSTARD GAS;

ACTIVATED CARBON; CONCENTRATION (PROCESS); FILTRATION; KINETIC PARAMETERS; NUMERICAL METHODS; RATE CONSTANTS;

BREAKTHROUGH CURVE; CARBON; CONCENTRATION (COMPOSITION); FILTRATION; FLOW VELOCITY; KINETICS; ORGANIC SULFUR COMPOUND;

AIRFLOW; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL WARFARE; CORRELATION ANALYSIS; FLOW KINETICS; PREDICTION; TEMPERATURE;

AIR POLLUTANTS; CARBON; CHROMIUM COMPOUNDS; ETHYLENEDIAMINES; MUSTARD GAS; RUTHENIUM COMPOUNDS; SODIUM HYDROXIDE;

EID: 34147210986     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2006.09.003     Document Type: Article

References (26)

1. Jonas L.A., and Rehrmann J.A. Predictive equations in gas adsorption kinetics. Carbon 11 (1973) 59-64
2. Wood G.O., and Stampfer J.F. Adsorption rate coefficients for gases and vapors on active carbon. Carbon 31 1 (1993) 195-200
3. W.A. Noyes, In Summary of technical report of NDRC, D10, Military problems with aerosols and non-persistent gases 1(1) (1946) 40-168.
4. Blacet F.E., and Grabenstetter R.J. Whetlerite adsorbents for poisonous gases. Chem. Abstr. 54 7 (1960) 13500
5. Smisek M., and Cerny S. Active Carbon, Manufacture, Properties and Applications (1970), Elsevier, Amsterdam
6. Jonas L.A. Reactive steps in gas adsorption by impregnated carbon. Extended Abstr. Porg-Bienn Conf. Carbon 13 (1977) 117
7. Jonas L.A., and Svirbely W.J. The kinetics of adsorption of carbon tetrachloride and chloroform from air mixtures by active carbon. J. Catal. 24 (1972) 446-459
8. Damico G.R. Destruction of thioether of mustard analogues by divanado decamolybdophosphoric acid. Chem. Abstr. 126 (1997) 224933
9. Singh B., Prasad G.K., Suryanarayana M.V.S., and Banerjee S. The reaction of thiodiglycol on metal impregnated carbons. Carbon 39 14 (2001) 2131-2142
10. Prasad G.K., and Singh B. J. Hazard. Mater. B126 (2005) 195-197
11. Prasad G.K., Singh B., Saradhi U.V.R.V., Suryanarayana M.V.S., and Pandey D. Adsorption and reaction of diethyl sulphide on active carbon with and without impregnants under static conditions. Langmuir 18 (2002) 4300-4306
12. Prasad G.K., and Singh B. Reactions of sulphur mustard on impregnated carbons. J. Hazard. Mater. B116 (2004) 213-217
13. Prasad G.K., Singh B., Suryanarayana M.V.S., and Batra B.S. Kinetics of degradation of sulphur mustard on impregnated carbons. J. Hazard. Mater. 121 1-3 (2005) 159-165
14. Wheeler A. In: Emmet P.H. (Ed). Catalysis (1955), Reinhold, New York
15. Wood G.O., and Moyer E.S. A review of the Wheeler equation and comparison of its applications to organic vapors respirator cartridge breakthrough data. Am. Ind. Hyg. Assoc. J. 50 8 (1989) 400
16. Wheeler A. In: Emmet P.H. (Ed). Catalysis 11 (1955), Reinhold, New York
17. Rehrmann J.A., and Jonas L.A. Dependence of gas adsorption rates on carbon granule size and linear flow velocity. Carbon 16 (1978) 47-51
18. Jonas L.A., and Rehrmann J.A. The rate of gas adsorption kinetics by activate carbon. Carbon 12 (1974) 95-101
19. Jonas L.A., and Rehrmann J.A. The kinetics of adsorption of organ phosphorous vapors from air mixtures by active carbons. Carbon 10 (1972) 657-663
20. Prasad G.K., and Singh B. Breakthrough behaviour of sulphur mustard vapours on whetlerite carbons. J. Hazard. Mater. 137 1 (2006) 277-281
21. Singh B., Prasad G.K., Mahato T.H., and Sekhar K. Breakthrough behaviour of diethyl sulphide vapours on active carbon systems. J. Hazard. Mater. 139 (2007) 38-43
22. Singh B., Bhise P.P., Suryanarayana M.V.S., Yadav S.S., Rao V.K., Polke B.G., Pandey D., Ganesan K., and Rao N.B.S.N. Silica gel detector tubes for toxic chemicals and their evaluation. J. Sci. Ind. Res. 58 (1999) 25
23. Suryanarayana M.V.S., Shrivastava R.K., Pandey D., Swamy R.V., Sumeet M., and Debdas M. Simple time weighted average level air-monitoring method for sulphur mustard in work places. J. Chromatogr. A 907 (2001) 229-234
24. Wheeler G.D. Annu. Rev. Cancer Res. 22 (1962) 651
25. Shilov N.A., Lepin L.N., and Voznesenskii S.A. Zhur. RussKovo Fis. Khim Obshchestva 61 (1929) 1107
26. Mecklenburg W., and Kubelka P. Z. Elektrochem. 31 (1925) 488