Adducts of Tröger bases and activated acetylenes: synthesis and structure

Tetrahedron Letters

Volumn 48, Issue 19, 2007, Pages 3363-3366

  Lenev, D A ^a   Chervin, I I ^a   Lyssenko, K A ^b   Kostyanovsky, R G ^a  

^a SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

^b A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE DERIVATIVE; ACETYLENEDICARBOXYLIC ACID DIMETHYL ESTER; BASE; CARBOXYLIC ACID DERIVATIVE; TROGER BASE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE; SUBSTITUTION REACTION; SYNTHESIS; X RAY DIFFRACTION;

EID: 34147119471     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.03.076     Document Type: Article

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31. b(a)), 6.44 (s, 2H, H(Ar)), 6.86 (s, 2H, H(Ar)).
32. -3. Intensities of 27,822 reflections were measured with a 'Smart APEX2' diffractometer (ω-scans, θ < 30.0°) and 18,052 independent reflections were used in further refinement. The refinement converged to wR2 = 0.1281 and GOF = 1.027 for all independent reflections (R1 = 0.04712 was calculated against F for 5227 observed reflections with I > 2σ(I). The crystallographic data have been deposited with the Cambridge Crystallographic Data Centre, CCDC-631875. Copies of this information may be obtained free of charge from: The Director, CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK (Fax: +44 1223 336033; e-mail: deposit@ccdc.cam.ac.uk or http://www.ccdc.cam.ac.uk).