A novel S-bridged PdII2HgII metallacycle of D-penicillaminate that forms a unique supramolecular structure combined with tetraamminepalladium(II)

Chemistry Letters

Volumn 36, Issue 3, 2007, Pages 434-435

  Hirai, Yusuke ^a   Igashira Kamiyama, Asako ^a   Kawamoto, Tatsuya ^a   Konno, Takumi ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 34047266405     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2007.434     Document Type: Article

References (19)

1. a) S. Leininger, B. Olenyuk, P. J. Stang, Chem. Rev. 2000, 100, 853.
2. b) B. J. Holliday, C. A. Mirkin, Angew. Chem., Int. Ed. 2001, 40, 2022.
3. c) M. Fujita, K. Umemoto, M. Yoshizawa, N. Fujita, T. Kusukawa, K. Biradha, Chem. Commun. 2001, 509.
4. d) O. Kahn, Acc. Chem. Res. 2000, 33, 647.
5. a) T. Konno, Bull. Chem. Soc. Jpn. 2004, 77, 627.
6. b) Y. Chikamoto, T. Kawamoto, A. I.-Kamiyama, T. Konno, Inorg. Chem. 2005, 44, 1601.
7. c) T. Konno, Y. Shimazaki, T. Yamaguchi, T. Ito, M. Hirotsu, Angew. Chem., Int. Ed. 2002, 41, 4711.
8. d) T. Konno, M. Usami, M. Hirotsu, T. Yoshimura, T. Kawamoto, Chem. Commun. 2004, 2296.
9. a) M. Taguchi, A. I.-Kamiyama, T. Kawamoto, T. Konno, The 55th Symposium on Coordination Chemistry of Japan, Nigata, September 21-23, 2005, Abstr., No. PA-066, p. 177.
10. b) A. Toyota, T. Yamaguchi, A. I.-Kamiyama, T. Kawamoto, T. Konno, Angew. Chem., Int. Ed. 2005, 44, 1088.
11. 2O: C, 18.74; H, 4.40; N, 4.37%. Found: C, 18.64; H, 4.03; N, 4.21%. Yield: 47%.
12. K. Nakamoto, Infrared and Roman Spectra of Inorganic and Coordination Compounds, 5th ed., Wiley Interscience, Chichester, 1997, Part B, pp. 62-67.
13. 1 = 0.085 (I > 2σ(I)).
14. 2O: C, 13.56; H, 2.65; N, 3.95%. Found: C, 13.30; H, 2.72; N, 3.85%. Yield: 50%.
15. 3 molecule: Pd-O = 2.043(9), Pd-N = 2.073(10), Pd-S = 2.268(3) Å. CCDC: 631461.
16. 3]·7/8KCl, has been prepared and structurally characterized. G. Cervantes, V. Moreno, E. Molins, M. Quirós, Polyhedron 1998, 17, 3343.
17. 2O: C, 12.68; H, 4.13; N, 8.22%. Found: C, 12.88; H, 4.08; N, 8.20%. Yield: 46%.
18. 4] gave an orange solution at pH ≈7, the absorption and CD spectra of which coincided well with those of 2, and this orange solution turned to a yellow solution containing 3 on further adding aqueous ammonia to pH ≈11. This fact also implies that 2 is an intermediate of the reaction from 1 to 3.
19. II anion: Pd-N = 2.061(3), Pd-S = 2.274(1), Hg-S = 2.502(1), Hg-Br = 2.6574(5) Å. CCDC: 631462.