Cooxidation of ammonia and ethanol in supercritical water, part 1: Experimental results

AIChE Journal

Volumn 53, Issue 4, 2007, Pages 941-947

  Ploeger, Jason M ^a   Mock, Michael A ^a   Tester, Jefferson W ^a  

^a Massachusetts Institute of Technology   (United States)

Author keywords

Ammonia; Co oxidation; Ethanol; Kinetics; Supercritical water oxidation

Indexed keywords

AMMONIA OXIDATION; OXYGEN CONCENTRATIONS; SUPERCRITICAL WATER OXIDATION;

AMMONIA; COMBUSTION; CONCENTRATION (PROCESS); ETHANOL; OXIDATION; REACTION KINETICS;

SUPERCRITICAL FLUIDS;

AMMONIA; COMBUSTION; CONCENTRATION (PROCESS); ETHANOL; OXIDATION; REACTION KINETICS; SUPERCRITICAL FLUIDS;

EID: 34047215820     PISSN: 00011541     EISSN: 15475905     Source Type: Journal    
DOI: 10.1002/aic.11127     Document Type: Article

References (26)

1. Modell M. Supercritical water oxidation. In: Freeman HM, editor. Standard Handbook of Hazardous Waste Treatment and Disposal. New York: McGraw Hill, 1989;8.153-158.168.
2. Tester JW, Holgate HR, Armellini FJ, Webley PA, Killilea WR, - Hong GT, Barner HE. Supercritical water oxidation technology. In: Tedder WD, Pohland FG, editors. Emerging Technologies in Hazardous Waste Management, Vol. 518. Washington, DC: American Chemical Society, 1993:35-76.
3. Gloyna EF, Li L. Supercritical water oxidation research and development update. Environ Progress. 1995;14:182.
4. Savage PE, Gopalan S, Mizan TI, Martino CJ, Brock EE. Reactions at supercritical conditions: Applications and fundamentals. AIChE J. 1995;41:1723-1778.
5. Tester JW, Cline JA. Hydrolysis and oxidation in sub- and supercritical water: Connecting process engineering science to molecular interactions. Corrosion. 1999;55:1088.
6. Savage PE. Organic chemical reactions in supercritical water. Chem Rev. 1999;99:603.
7. Shaw RW, Dahmen N. Destruction of toxic organic materials using supercritical water oxidation: Current state of the technology. In: Kiran E, editor. Supercritical Fluids. Netherlands: Kluwer Academic, 2000.
8. Kritzer P, Dinjus E. An assessment of supercritical water oxidation (SCWO) - Existing problems, possible solutions and new reactor concepts. Chem Eng J. 2001;83:207-214.
9. Holgate HR, Tester JW. Fundamental kinetics and mechanisms of hydrogen oxidation in supercritical water. Combust Sci Technol. 1993;88(5/6):369-397.
10. Holgate HR, Tester JW. Oxidation of hydrogen and carbon monoxide in sub- and supercritical water: Reaction kinetics, pathways, and water-density effects, Part 1: Experimental results. J Phys Chem. 1994;98:800-809.
11. Webley PA, Tester JW. Fundamental kinetics of methane oxidation in supercritical water. Energy Fuels. 1991;5:411-419.
12. DiNaro J, Tester J, Howard J, Swallow K. Experimental measurements of benzene oxidation in supercritical water. AICHE J. 2000;46:2274-2284.
13. Sullivan PA, Tester JW. Methylphosphonic acid oxidation kinetics in supercritical water. AIChE J. 2004;50:673-683.
14. Schanzenbacher J, Taylor JD, Tester JW. Ethanol oxidation and hydrolysis rates in supercritical water. J Supercrit Fluid. 2002;22:139-147.
15. Taylor JD, Steinfeld JI, Tester JW. Experimental measurement of the rate of methyl fert-butyl ether hydrolysis in sub- and supercritical water. Ind Eng Chem Res. 2001;40:67-74.
16. Webley PA, Tester JW, Holgate HR. Oxidation kinetics of ammonia and ammonia-methanol mixtures in supercritical water in the temperature range 530-700°C at 246 bar. Ind Eng Chem Res. 1991;30:1745-1754.
17. Ploeger JM, Madlinger AC, Tester JW. Revised global kinetic measurements of ammonia oxidation in supercritical water. Ind Eng Chem Res. 2006;45:6842-6845.
18. Segond N, Matsumura Y, Yamamoto K. Determination of ammonia oxidation rate in sub- and supercritical water. Ind Eng Chem Res. 2002;41:6020-6027.
19. Hong GT, Fowler PK, Killilea WR, Swallow KC. Supercritical water oxidation: Treatment of human waste and system configuration tradeoff study. Proceedings of 17th Intersociety Conference on Environmental Systems. July 13-15, 1987; Seattle, WA.
20. Cocero MJ, Alonso E, Torío R, Vallelado D, Fdz-Polanco F. Supercritical water oxidation in a pilot plant of nitrogenous compounds: 2-Propanol mixtures in the temperature range 500-750°C. Ind Eng Chem Res. 2000:39:3707-3716.
21. Ploeger JM, Green WH, Tester JW. Co-oxidation of methylphosphonic acid and ethanol in supercritical water: II. Elementary reaction rate model. J Supercrit Fluids. 2006;39:239-245.
22. DiNaro JL. Oxidation of benzene in supercritical water: experimental measurements and development of an elementary reaction mechanism. PhD Thesis. Cambridge, MA: Department of Chemical Engineering, Massachusetts Institute of Technology, 1999.
23. Phenix B, Dinaro J, Tester J, Howard J, Smith K. The effects of mixing and oxidant choice on laboratory-scale measurements of supercritical water oxidation kinetics. Ind Eng Chem Res. 2002;41:624-631.
24. Dean JA. Lange's Handbook of Chemistry. New York: McGraw-Hill, 1992.
25. Ploeger JM, Bielenberg PA, Lachance RP, Tester JW. Co-oxidation of methylphosphonic acid and ethanol in supercritical water: I. Experimental results. J Supercrit Fluids. 2006;39:233-238.
26. Ploeger JM, Bielenberg PA, DiNaro Blanchard JL, Lachance RP, Taylor JD, Green WH, Tester JW. Modeling oxidation and hydrolysis reactions in supercritical water - Free radical elementary reaction networks and their applications. Comb Sci Tech. 2006;178(1-3):363-398.