High temperature structural and thermoelastic behaviour of mantle orthopyroxene: An in situ neutron powder diffraction study

Physics and Chemistry of Minerals

Volumn 34, Issue 3, 2007, Pages 185-200

  Gatta, Diego G ^a   Rinaldi, Romano ^b   Knight, K S ^c,d   Molin, G ^e   Artioli, G ^a,e  

^a UNIVERSITY OF MILAN   (Italy)

^b UNIVERSITY OF PERUGIA   (Italy)

^c RUTHERFORD APPLETON LABORATORY   (United Kingdom)

^d DEPARTMENT OF LIFE SCIENCES   (United Kingdom)

^e UNIVERSITY OF PADOVA   (Italy)

Author keywords

Cation ordering; High temperature; Neutron powder diffraction; Orthopyroxene; Structural refinement; Thermo elastic behaviour

Indexed keywords

HIGH TEMPERATURE PROPERTIES; LAGRANGE MULTIPLIERS; NEUTRON POWDER DIFFRACTION; PHASE TRANSITIONS; THERMAL EXPANSION; THERMODYNAMIC STABILITY; THERMOELASTICITY;

CATION-ORDERING; HIGH PRESSURE ULTRAMAFIC NODULES; MANTLE ORTHOPYROXENE; STRUCTURAL REFINEMENT;

SILICATE MINERALS;

CRYSTAL STRUCTURE; HIGH TEMPERATURE; ION EXCHANGE; LAGRANGIAN ANALYSIS; MANTLE SOURCE; NEUTRON DIFFRACTION; ORTHOPYROXENE; P-T CONDITIONS; THERMOELASTICITY;

EID: 34047165811     PISSN: 03421791     EISSN: 14322021     Source Type: Journal    
DOI: 10.1007/s00269-006-0138-2     Document Type: Article

References (69)

1. 3. Am Mineral 87:558-561
2. Anovitz LM, Essene EJ, Dunham WR (1988) Order-disorder experiments on orthopyroxene: Implications for the orthopyroxene geospeedometer. Am Mineral 73:1060-1073
3. Balic-Zunic T, Vickovic I (1996) IVTON (Version 2) - program for the calculation of geometrical aspects of crystal structures and some crystal chemical applications. J Appl Cryst 29:305-306
4. Besancon JR (1981) Rate of cation ordering in orthopyroxene. Am Mineral 66:965-973
5. Boysen H, Frey F, Schrader H, Eckhold G (1991) On the proto to ortho/ clino enstatite phase transformation: Single crystal X-ray and inelastic neutron investigation. Phys Chem Miner 17:629-635
6. Càmara F, Nestola F (2006) Anomalous thermal expansion in Ca-rich orthoenstatite. In: Proceedings of EMPG XI, Bristol
7. Càmara F, Doukhan JC, Domeneghetti MC, Zema M (2000) A TEM study of Ca-rich orthopyroxenes with exsolution products: Implications for the Mg-Fe ordering process. Eur J Mineral 12:735-748
8. Cameron M, Papike JJ (1981) Structural and chemical variations in pyroxenes. Am Mineral 66:1-50
9. 3 orthopyroxene. Geochim Cosmochim Acta 47:1597-1603
10. Chopelas A (2000) Thermal expansivity of mantle relevant magnesium silicates derived from vibrational spectroscopy at high-pressure. Am Mineral 85:270-278
11. Chopelas A, Boehler R (1992) High-pressure research: Application to earth and planetary sciences. In: Syono Y, Manghnani MH (eds) Terra Scientific, Tokyo, p 101
12. 2+ distribution in orthopyroxenes. Am Mineral 70:987-995
13. Domeneghetti MC, Molin G, Tazzoli V (1995a) A crystal-chemical model for Pbca orthopyroxenes. Am Mineral 80:253-267
14. Domeneghetti MC, Molin G, Stimpfl M, Tribaudino M (1995b) Orthopyroxene from Serra de Mage' meteorite: Structure refinement and estimation of C2/ c pyroxene contributions to apparent Pbca diffraction violations. Am Mineral 80:923-929
15. Dove MT (2002) An introduction to the use of neutron scattering methods in mineral sciences. Eur J Mineral 14:203-224
16. Ganguly J (1982) Mg-Fe order-disorder in ferromagnesian silicates II. In: Saxena S (ed) ThermKdyamics: kinetics and geological applications (advances physical geochemistry 2). Springer, Berlin, pp 58-99
17. Ganguly J, Ghose S (1979) Aluminous orthopyroxene: Order-disorder, thermodynamic properties and petrologic implications. Contrib Mineral Petrol 69:375-385
18. 6. Z Kristallogr 122:81-99
19. 2+ distribution in metamorphic and volcanic orthopyroxenes. Z Kristallogr 125:1-6
20. 3 ortho- and clinopyroxenes. Am Mineral 82:689-696
21. 3 orthopyroxenes. Phys Chem Miner 24:301-310
22. Jackson JM, Palko J, Sinogeikin SV, Bass JD, Andrault D, Zha C (2001) High-temperature single-crystal elasticity and thermal expansion of orthoenstatite. EOS Trans (Fall Meet. Suppl.), Abstract T31C-0853
23. Jackson JM, Sinogeikin SV, Carpenter MA, Bass JD (2004) Novel phase transition in orthoenstatite. Am Mineral 89:239-245
24. Kroll H, Lueder T, Schlenz H, Kirfel A, Vad T (1997) The Fe2+, Mg distribution in orthopyroxene: A critical assessment of its potential as a geospeedometer. Eur J Mineral 9:705-733
25. Larson AC, Von Dreele RB (2001) GSAS: General structure analysis system. Document LAUR 86-748. Los Alamos National Laboratory, New Mexico
26. Lee WE, Heuer AH (1987) On the polymorphism of enstatite. J Am Ceram Soc 70:349-360
27. Makovicky E, Balic-Zunic T (1998) New measure of distortion for coordination polyhedra. Acta Crystallogr B54:766-773
28. Miyake A, Shimobayashi N, Kitamura M (2004) Isosymmetric structural phase transition of orthoenstatite: Molecular dynamics simulation. Am Mineral 89:1667-1672
29. Molin G (1989) Crystal-chemical study of cation disordering in Al-rich and Al-poor orthopyroxenes from spinel lherzolite xenoliths. Am Mineral 74:593-598
30. Molin G, Stimpfl M (1994) Crystal chemistry and intracrystalline relationships of orthopyroxene in a suite of high pressure ultramafic nodules from the "Newer Volcanics" of Victoria, Australia. Mineral Mag 58:325-332
31. Molin G, Saxena SK, Brizi E (1991) Iron-magnesium order-disorder in an orthopyroxene crystal from the Johnstown meteorite. Earth Planet Sci Lett 105:260-265
32. Murakami T, Takeuchi Y, Yamanaka T (1982) The transition of orthoenstatite to protoenstatite and the structure at 1,080°C. Z Kristallogr 160:299-312
33. 6). Eur J Mineral 15:365-371
34. Nestola F, Gatta GD, Boffa Ballaran T (2006) The effect of Ca substitution on the elastic and structural behaviour of orthoenstatite. Am Mineral 91:809-815
35. Ohashi Y (1982) STRAIN: A program to calculate the strain tensor from two sets of unit-cell parameters. In: Hazen RM, Finger LW (eds) Comparative crystal chemistry, Wiley, New York, pp 92-102
36. 6 system at atmospheric pressure. In: Proceedings of the 19th general meeting of the International mineralogical association (IMA), Kobe, Japan, pp 1-7
37. Pannhorst W (1979) Structural relationship between pyroxenes. N Jb Miner Abh 135:1-7
38. Reid AM, Williams RJ, Takeda H (1974) Coexisting bronzite and clinobronzite and the thermal evolution of the Steinbach meteorite. Earth Planet Sci Lett 22:67-74
39. Rinaldi R (2002) Neutron scattering in mineral sciences. Eur J Mineral 14:195-202
40. 4 olivine at high temperature as studied by in situ neutron powder diffraction. Phys Chem Miner 32:655-664
41. 2+ order-disorder and the thermodynamics of orthopyroxene crystalline solution. Am Mineral 56:532-559
42. 2+ - Mg order-disorder in orthopyroxene: Some kinetic results. Phys Chem Miner 16:421-427
43. Schrader H, Boysen H, Frey F, Convert P (1990) On the phase transformation proto- to clino/orthoenstatite: Neutron powder investigations. Phys Chem Miner 17:409-415
44. Shimobayashi N, Kitamura M (1993) Phase transition of orthoenstatite to high-clinoenstatite: In situ TEM study at high temperatures. Mineral J 16:416-426
45. 3 polymorphs: Physical properties and phase relations of Mg-Fe pyroxenes. Mineral Soc Am Spec Pap 2:3-30
46. Smyth JR (1969) Orthopyroxene high-low clinopyroxene inversions. Earth Planet Sci Lett 6:406-407
47. Smyth JR (1971) Protoenstatite: A crystal structure refinement at 1,100°C. Z Kristallogr 134:262-274
48. Smyth JR (1973) An orthopyroxene structure up to 850°C. Am Mineral 58:636-648
49. Smyth JR (1974) Experimental study on the polymorphism of enstatite. Am Mineral 59:345-352
50. Smyth JR, Burnham CW (1972) The crystal structure of high and low clinohypersthene. Earth Planet Sci Lett 14:183-189
51. Smyth JR, Ito J (1977) The synthesis and crystal structure of a magnesium lithium scandium protopyroxene. Am Mineral 62:857-873
52. 2+ - Mg order-disorder in orthopyroxene: Equilibrium fractionation between octahedral sites and thermodynamic analysis. Contrib Mineral Petrol 136:297-309
53. 2+ - Mg order-disorder in orthopyroxene: Experimental studies and applications to cooling rates of rocks. Contr Mineral Petrol 150:319-334
54. Sueno S, Kimata M (1981) On the ortho-clino phase transition of ferrosilite (FeSiO3) and Fe-rich pyroxenes. Acta Crystallogr A 37:C-111
55. Sueno S, Prewitt CT (1983) Models for phase transition between orthoferrosilite and high clinoferrosilite. Fortschr Mineral 61:223-241
56. Sueno S, Cameron M, Prewitt CT (1976) Orthoferrosilite: High temperature crystal chemistry. Am Mineral 61:38-53
57. Sueno S, Kimata M, Prewitt CT (1984) The crystal structure of high clinoferrosilite. Am Mineral 69:264-269
58. Sueno S, Prewitt CT, Kimata M (1985) Structural aspects of phase transitions in Fe-Mg-Ca pyroxenes. Am Mineral 70:141-148
59. Sykes-Nord JA, Molin G (1993) Mg-Fe order-disorder in Fe-rich orthopyroxene: Structural variations and kinetics. Am Mineral 78:921-931
60. Tazzoli V, Domeneghetti MC (1987) Crystal-chemistry of natural and heated aluminous orthopyroxenes. Phys Chem Miner 15:131-139
61. 6). Eur J Mineral 14:549-555
62. Virgo D, Hafner SS (1969) Order-disorder in heated orthopyroxenes. Mineral Soc Am Spec Pap 2:67-81
63. 6. Am Mineral 79:633-643
64. 3 orthopyroxenes. Phys Chem Miner 20:575-586
65. 6. Am Mineral 80:9-20
66. 6 at 1,360 K. Phys Chem Miner 22: 300-310
67. Yang H, Prewitt CT (2000) Chain and layer silicates at high temperature and pressures. In: Hazen RM, Downs RT (eds) High-temperature and high-pressure crystal chemistry. Reviews in mineralogy and geochemistry, vol 41. Mineralogical Society of America and Geochemical Society, Washington, pp 211-256
68. Zema M, Tarantino SC, Domeneghetti MC, Tazzoli V (2003) Ca in orthopyroxene: Structural variations and kinetics of the disordering process. Eur J Mineral 15:373-380
69. 3 orthoenstatite. Phys Chem Miner 22:393-398