The effect of agitation intensity on alkali-catalyzed methanolysis of sunflower oil

Bioresource Technology

Volumn 98, Issue 14, 2007, Pages 2688-2699

  Stamenković, Olivera S ^a   Lazic M L ^a   Todorovic Z B ^a   Veljkovic V B ^a   Skala, D U ^b  

^a UNIVERSITY OF NI   (Serbia)

^b UNIVERSITY OF BELGRADE   (Serbia)

Author keywords

Biodiesel; Kinetics; Methanolysis; Sauter mean diameter; Sunflower oil

Indexed keywords

BIODIESEL; CHEMICAL REACTORS; DROPS; INTERFACES (MATERIALS); REACTION KINETICS;

INTERFACIAL AREA; METHANOLYSIS; SAUTER-MEAN DIAMETER;

VEGETABLE OILS;

ALKALI; METHANOL; SUNFLOWER OIL;

BIODIESEL; CHEMICAL REACTORS; DROPS; INTERFACES (MATERIALS); REACTION KINETICS; VEGETABLE OILS;

BIOFUEL; CATALYSIS; INTERFACE; REACTION KINETICS; REACTION RATE; STEADY-STATE EQUILIBRIUM; VEGETABLE OIL;

ARTICLE; CATALYSIS; EQUILIBRIUM CONSTANT; MEASUREMENT; METHANOLYSIS; NONHUMAN; PARTICLE SIZE; PRIORITY JOURNAL; REACTION ANALYSIS; STIRRED REACTOR;

EMULSIONS; HYDROXIDES; METHANOL; PLANT OILS; POTASSIUM COMPOUNDS;

HELIANTHUS;

EID: 34047146614     PISSN: 09608524     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.biortech.2006.09.024     Document Type: Article

References (36)

1. Alcantara R., Amores J., Canoira L., Fidalgo E., Franco M.J., and Navarro A. Catalytic production of biodiesel from soy-bean oil, used frying oil and tallow. Biomass Bioenergy 18 (2000) 515-527
2. Azbel D.S., and Cheremisinoff N.P. Fluid Mechanics and Unit Operations (1983), Ann Arbor Science Publisher, Ann Arbor, MI p. 708
3. Baldyga J., and Bourne J.R. Drop breakup and intermittent turbulence. J. Chem. Eng. Jpn 26 (1993) 738-741
4. Ban T., Kawaizumi F., Nii S., and Takahashi K. Effects of surface activities of extractants on drop coalescence and breakage in a mixer-settler. Ind. Eng. Chem. Res. 41 (2002) 5477-5482
5. Boocock D.G.B., Konar S.K., Mao V., and Sidi H. Fast one-phase oil-rich processes for the preparation of vegetable oil methyl esters. Biomass Bioenergy 11 (1996) 43-50
6. Chiu C.-W., Goff M.J., and Suppes G.J. Distribution of methanol and catalysts between biodiesel and glycerin phases. AIChE J. 51 (2005) 1274-1278
7. Darnoko D., and Cheryan M. Kinetics of palm oil transesterification in a batch reactor. JAOCS 77 (2000) 1263-1267
8. Freedman B., Pryde E.H., and Mounts T.L. Variables affecting the yields of fatty esters from transesterified vegetable oils. JAOCS 61 (1984) 1638-1643
9. Freedman B., Butterfield R.O., and Pryde E.H. Transesterification kinetics of soybean oil. JAOCS 63 (1986) 1375-1380
10. Fukuda H., Kondo A., and Noda H. Biodiesel fuel production by transesterification of oils. J. Biosci. Bioeng. 92 (2001) 405-416
11. Harvey A.P., Mackley M.R., and Seliger T. Process intensification of biodiesel production using a continuous oscillatory flow reactor. J. Chem. Technol. Biotechnol. 78 (2003) 338-341
12. Holčapek M., Jandera P., Fischer J., and Prokeš B. Analytical monitoring of the production of biodiesel by high-performance liquid chromatography with various detection methods. J. Chromatogr. A 858 (1999) 13-31
13. Kaieda M., Samukawa T., Matsumoto T., Ban K., Kondo A., Shimada Y., Noda H., Nomoto F., Ohtsuka K., Izumoto E., and Fukuda H. Biodiesel fuel production from plant oil catalyzed by Rhizopus oryzae lipase in a water-containing system without an organic solvent. J. Biosci. Bioeng. 88 (1999) 627-631
14. Kimmel, T., 2004. Kinetic investigation of the base-catalyzed glycerolysis of fatty acid methyl esters. PhD Thesis. The Technical University, Berlin.
15. Komers K., Tichy J., and Skopal F. Ternary phase diagram biodiesel fuel-methanol-glycerol. J. Prakt. Chem. 337 (1995) 328-331
16. Komers K., Skopal F., Stloukal R., and Machek J. Kinetics and mechanism of the KOH-catalyzed methanolysis of rapeseed oil for biodiesel production. Eur. J. Lipid Sci. Technol. 104 (2002) 728-737
17. Ma F., and Hanna M.A. Biodiesel production: a review. Biores. Technol. 70 (1999) 1-15
18. Ma F., Clements L.D., and Hanna M.A. The effect of mixing on transesterfication of beef tallow. Biores. Technol. 69 (1999) 289-293
19. Mittelbach M., and Trathnigg B. Kinetics of alkaline catalyzed methanolysis of sunflower oil. Fat. Sci. Technol. 92 (1990) 145-148
20. Nagata S. Mixing: Principles and Applications (1975), Wiley, New York p. 300
21. Noureddini H., and Zhu D. Kinetics of transesterification of soybean oil. JAOCS 74 (1997) 1457-1463
22. Noureddini H., Harkey D., and Medikonduru V. A continuous process for the conversion of vegetable oils into methyl esters of fatty acids. JAOCS 75 (1998) 1775-1783
23. Noureddini H., Harkey D.W., and Gutsman M.R. A continuous process for the glycerolysis of soybean oil. JAOCS 81 (2004) 1-5
24. Oldshue J.Y. Fluid Mixing Technology (1983), Chemical Engineering McGraw-Hill Pub. Co., New York p. 157
25. Peterson C.L., Feldman M., Korus R., and Auld D.L. Batch type transesterification process for winter rape oil. Appl. Eng. Agric. 7 (1991) 711-716
26. Podgórska W., and Baldyga J. Drop break-up in a stirred tank. Task Quart. 7 (2003) 409-424
27. Sajjadi S., Zerfa M., and Brooks B.W. Dynamic behaviour in oil/water/oil dispersions. Chem. Eng. Sci. 57 (2002) 663-675
28. Schuchardt U., Sercheli R., and Vargas M.R. Transesterification of vegetable oils: a review. J. Braz. Chem. Soc. 9 (1998) 199-210
29. Shimizu K., Minekawa K., Hirose T., and Kawase Y. Drop breakage in stirred tanks with Newtonian and non-Newtonian fluid systems. Chem. Eng. J. 72 (1999) 117-124
30. Stahl E. Dunshicht Chromatographie (1967), Springer-Verlag, Berlin p. 362
31. Stamenković O.S., Lazić M.L., Veljković V.B., and Skala D.U. Biodiesel production by enzyme-catalyzed transesterification. Chem. Ind. 59 (2005) 49-59
32. Stavarache C., Vinatoru M., Nishimura R., and Maeda Y. Fatty acids methyl esters from vegetable oil by means of ultrasonic energy. Ultrason. Sonochem. 12 (2005) 367-372
33. Taylor G.I. The viscosity of a fluid containing small drops of another fluid. Proc. R. Soc. London Ser. A 138 (1932) 41-48
34. Vicente G., Martinez M., Aracil J., and Esteban A. Kinetics of sunflower oil methanolysis. Ind. Eng. Chem. Res. 44 (2005) 5447-5454
35. von Blottnitz, H., Sadat-Rezai, S.A., Vardy, J., 2004. Conversion of plant oils to methyl-ester fuels: consideration for reactor design in commercial and small-scale production. In: 16th International Congress of Chemical and Process Engineering, CHISA 2004, 22-26 August, Prague, Czech Republic. CD ROM of Full Texts 1361.pdf.
36. Wichterle K. Drop breakup by impellers. Chem. Eng. Sci. 50 (1995) 3581-3586