Unexpected product formed by the reaction of [2,6-(MeOCH2)2C6H3]Li with SbCl3: Structure of Sb-O intramolecularly coordinated organoantimony cation

Journal of Organometallic Chemistry

Volumn 692, Issue 11, 2007, Pages 2350-2353

  Dostál, Libor ^a   Jambor, Roman ^a   Císařová, Ivana ^b   Beneš, Ludvík ^c   Růžička, Aleš ^a   Jirásko, Robert ^a   Holeček, Jaroslav ^a  

^a UNIVERSITY OF PARDUBICE   (Czech Republic)

^b CHARLES UNIVERSITY   (Czech Republic)

^c INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Czech Republic)

Author keywords

Antimony; Chloroantimonates; Hypervalent compounds; Pincer ligand

Indexed keywords

ANTIMONY COMPOUNDS; MASS SPECTROMETRY; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; ORGANOMETALLICS; POSITIVE IONS;

ANTIMONY ANIONS; CHLOROANTIMONATES; HYPERVALENT COMPOUNDS; PINCER LIGANDS;

LITHIUM COMPOUNDS;

EID: 34047140324     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2007.02.005     Document Type: Short Survey

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14. 3 for several times, unfortunately in all cases the observed insoluble material was of amorphous nature thus unsuitable for X-ray powder diffraction method.