Study of the ozonolysis rate constants' dependence from the degree of oxidation of C60 fullerene and trans-1,4-polychloroprene

Fullerenes Nanotubes and Carbon Nanostructures

Volumn 15, Issue 3, 2007, Pages 181-193

  Anachkov, M P ^a   Cataldo, F ^b   Deneva, M G ^a   Rakovski, S K ^a  

^a INSTITUTE OF CATALYSIS   (Bulgaria)

^b Soc Lupi Chem Research Institute   (Italy)

Author keywords

C60 fullerene; Ozonolysis; Polychloroprene; Rate constants

Indexed keywords

AROMATIC HYDROCARBONS; CHEMICAL BONDS; CHEMICAL REACTORS; FULLERENES; OXIDATION; REACTION KINETICS; SOLUTIONS;

C60 FULLERENES; OZONOLYSIS; POLYCHLOROPRENE;

RATE CONSTANTS;

EID: 34047124958     PISSN: 1536383X     EISSN: 15364046     Source Type: Journal    
DOI: 10.1080/15363830701236373     Document Type: Article

References (22)

1. 60 in carbon tetrachloride solution (In Russian). Dokladyi Akademii Nauk, 367 (6): 780-783.
2. 60. J. Appl. Spectrosc., 69 (2): 7-11.
3. 3. Polym. Degrad. Stab., 77: 111-120.
4. 60 (In Russian). Kinet. Catal., 44 (2): 229-249.
5. 60 fullerene ozonation. Full., Nanot. Carbon Nanostruct., 11 (2): 95-103.
6. 60 fullerenes: the effect of temperature on the reaction kinetics. Full., Nanot. Carbon Nanostruct., 12 (4): 745-752.
7. Murray, R. and Story, P. (1967) Ozonation. In Chemical Reactions of Polymers; Mir: Moscow (In Russian).
8. Razumovskii, S.D. and Zaikov, G.E. (1984) Ozone and its Reactions with Organic Compounds; Elsevier: Amsterdam, Chapters 2 and 3.
9. Rakovsky, S. and Zaikov, G. (1998) Kinetics and Mechanism of Ozone Reactions with Organic and Polymeric Compounds in Liquid Phase, Nova Science Publishers Inc.: New York, Chapters 3 and 4.
10. Cataldo, F. (2001) The action of ozone on polymers having unconjugated and cross- or linearly conjugated unsaturation: chemistry and technological aspects. Polym. Degrad. Stab., 73: 511-520.
11. Razumovskii, S.D. (2000) Comparison of the parameters of the Arrhenius equation describing the kinetics of the reaction of ozone with alkenes in solution and gas phase (In Russian). Khimicheskaja Physika, 19 (7): 58-62.
12. Crigee, R. (1975) Ozonolysis mechanism. Angew. Chem. Int. Ed. Eng., 14: 745-761.
13. Bailey, P.S. (1982) Ozonation in Organic Chemistry; Academic Press: New York; Vols. 1, 2, Chapters IV, VI, and XII.
14. 70 fullerenes. Carbon, 40: 1457-1467.
15. 2. J. Am. Chem, Soc, 122: 11473-11479.
16. Cataldo, F. and Keheyan, Y. (2002) Formation of fullerenes and carbon clusters by laser irradiation of polymeric fullerene oxide (fullerene ozopolymer). Full., Nanot. Carbon Nanostruct., 10: 333-338.
17. Anachkov, M.P., Rakovsky, S.K., Stefanova, R.V., and Stoyanov, A.K. (1993) Ozone degradation of polychloroprene rubber in solution. Polym. Degrad. Stab., 41 (2): 185-190.
18. Becker, G.O. (1977) Einfuhrung in die Elektronentheorie Organisch-chemisher Reaktionen; Mir: Moscow (In Russian).
19. Komissarov, V.D. and Gerchikov, A.Ja. (1974) Study of the kinetics of liquid phase oxidation of organic compounds with ozone (In Russian). Kinet. Katal., 15: 916-921.
20. Rozovskii, A.Ja. (1980) Heterogeneous Chemical Reactions (Kinetics and Macrokinetics); Nauka: Moscow (In Russian).
21. (a) Rozenberg, M.M. and Brun, E.B. (1990) Mathematical model of the mass transfer in bubble absorbers and reactors (In Russian). Teor. Osn. Khim. Teknol., 24 (2): 198-205;
22. (b) Rozenberg, M.M., Brun, E.B., and Heifets, L.I. (1992) Problems in the study of ozonation in air-lift reactors (In Russian). Zh. Fiz. Khim., 66 (4): 911-914.