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Volumn 70, Issue , 2006, Pages 635-646

Enantioselective synthesis of 3-arylindan-1-ones via intramolecular C-H insertion reactions of -diazo--ketoesters catalyzed by chiral dirhodium(II) carboxylates

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Indexed keywords


EID: 33947694406     PISSN: 03855414     EISSN: None     Source Type: Journal    
DOI: 10.3987/com-06-s(w)58     Document Type: Article
Times cited : (26)

References (48)
  • 13
    • 0000709206 scopus 로고
    • For books and reviews, see:
    • For books and reviews, see:. Ye T., and McKervey M.A. Chem. Rev. 94 (1994) 1091
    • (1994) Chem. Rev. , vol.94 , pp. 1091
    • Ye, T.1    McKervey, M.A.2
  • 21
    • 0003445429 scopus 로고    scopus 로고
    • Chapter 16.2. Jacobsen E.N., Pfaltz A., and Yamamoto H. (Eds), Springer, Berlin, Germany
    • Chapter 16.2. Lydon K.M., and McKervey M.A. Comprehensive Asymmetric Catalysis. In: Jacobsen E.N., Pfaltz A., and Yamamoto H. (Eds) (1999), Springer, Berlin, Germany
    • (1999) Comprehensive Asymmetric Catalysis
    • Lydon, K.M.1    McKervey, M.A.2
  • 36
    • 33947633734 scopus 로고    scopus 로고
    • note
    • The use of 4Å MS was found to be advantageous in the rainy season. Otherwise a 10-20% drop in product yield was observed, though no decline in enantioselectivity was observed.
  • 40
    • 33947696421 scopus 로고    scopus 로고
    • note
    • The use of the corresponding tert-butyl ester required 7 h for completion of the reaction to give tert-butyl 3-phenylindan-1-one-2-carboxyl ate in 88% yield, which, upon removal of the ester group, produced (R)-la in 90% yield with 30% ee.
  • 45
    • 33947661143 scopus 로고    scopus 로고
    • note
    • The preferred absolute stereochemistry of 1b was assigned by analogy.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.