Quantitative analysis of the reactivity of formate species seen by DRIFTS over a Au/Ce(La)O2 water-gas shift catalyst: First unambiguous evidence of the minority role of formates as reaction intermediates

Journal of Catalysis

Volumn 247, Issue 2, 2007, Pages 277-287

  Meunier, F C ^a   Reid, D ^a   Goguet, A ^a   Shekhtman, S ^a   Hardacre, C ^a   Burch, R ^a   Deng, W ^b   Flytzani Stephanopoulos, M ^b  

^a QUEEN'S UNIVERSITY BELFAST   (United Kingdom)

^b Tufts University   (United States)

Author keywords

Carbonate; Ceria; DRIFT; Formate; FTIR; Gold; In situ; Operando; Reaction mechanism; Spectator; Spectroscopy; SSITKA; Surface species; Water gas shift

Indexed keywords

CARBONATES; CATALYSTS; PHASE SHIFT; QUARTZ; REACTION KINETICS;

DIFFUSE REFLECTANCE FOURIER TRANSFORM SPECTROSCOPY (DRIFTS); PLUG FLOW REACTOR; REACTION INTERMEDIATES; STEADY STATE DURING ISOTOPIC TRANSIENT KINETIC ANALYSES (SSITKA); SURFACE SPECIES;

GOLD COMPOUNDS;

EID: 33947629151     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2007.02.013     Document Type: Article

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