Influence of fillers and additives on the cure kinetics of an epoxy/anhydride resin

European Polymer Journal

Volumn 43, Issue 4, 2007, Pages 1168-1178

  Harsch, Margit ^a   Karger Kocsis, József ^b   Holst, Marco ^a  

^a ROBERT BOSCH GMBH   (Germany)

^b INSTITUT FÜR VERBUNDWERKSTOFFE GMBH   (Germany)

Author keywords

Additives; Calorimetry; Fillers; Kinetics; Resin

Indexed keywords

ADDITIVES; DIFFERENTIAL SCANNING CALORIMETRY; FILLERS; REACTION KINETICS; SURFACE TREATMENT;

ANHYDRIDE RESINS; AUTOCATALYTIC MODEL; DIFFUSION FACTORS; PHENOMENOLOGICAL KAMAL MODELS;

EPOXY RESINS;

EID: 33947590375     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2007.01.025     Document Type: Article

References (37)

1. Beyer M. Epoxidharze in der Elektrotechnik (1983), Expert Verlag, Grafenau/Württ p. 13-39
2. Prime R.B. In: Turi E.A. (Ed). Thermal characterization of polymeric materials (1981), Academic Press, New York 435-569
3. Barton JM. In: Dusek K. (Ed). Advances in polymer sciences (1985), Springer, Berlin, Heidelberg, New York 111-154
4. Duswalt A.A. The practice of obtaining kinetic data by differential scanning calorimetry. Thermochim Acta 8 (1974) 57-68
5. Fava R.A. Differential scanning calorimetry of epoxy resins. Polymer 9 (1968) 137-151
6. Shim J.S., Lee W., and Jang J. DSC cure studies of high performance epoxy resins I. The reaction with 4,4′-diaminodiphenyl sulfone (DDS). Polym J 23 7 (1991) 903-910
7. Li Y., Zhu X., and Yan D. Isothermal and nonisothermal crystallization kinetics of Nylon 10 12. Polym Eng Sci 40 9 (2000) 1989-1995
8. Cedeno A.J., and Vazquez-Torres H. Kinetic study of the effect of poly(phenylsulfone) on the curing of an epoxy/amine resin by conventional and by temperature-modulated differential scanning calorimetry. Polym Int 54 (2005) 1141-1152
9. Lee J.Y., Choi H.K., Shim M.J., and Kim S.W. Kinetic Studies of an epoxy cure reaction by isothermal DSC analysis. Thermochim Acta 343 (2000) 111-117
10. Hwang S.-H., and Jung J.-C. Curing kinetics and thermal properties of diglycidylether of bisphenol A with various diamines. J Appl Polym Sci 81 (2001) 279-284
11. Ivankovic M., Brnardic I., Ivankovic H., and Mencer H.J. DSC study of the cure kinetics during nanocomposite formation: epoxy/poly(oxypropylene) diamine/organically modified montmorillonite system. J Appl Polym Sci 99 (2006) 550-557
12. Du S., Guo Z.-S., Zhang B., and Wu Z. Cure kinetics of epoxy resin used for advanced composites. Polym Int 53 (2004) 1343-1347
13. Blanco M., Corcuera A., Riccardi C.C., and Mondragon I. Mechanistic kinetic model of an epoxy resin cured with a mixture of amines of different functionalities. Polymer 46 (2005) 7989-8000
14. Wenzel M. Spannungsbildung und Relaxationsverhalten bei der Aushärtung von Epoxidharzen. Dissertation, Darmstadt; 2005.
15. Park W.H., and Lee J.K. A study on isothermal cure behavior of an epoxy-rich/anhydride system by differential scanning calorimetry. J Appl Polym Sci 67 (1998) 1101-1108
16. Montserrat S., Flaque C., Pagès P., and Málek J. Effect of the crosslinking degree on curing kinetics of an epoxy-anhydride system. J Appl Polym Sci 56 (1995) 1413-1421
17. Montserrat S., and Pia X. Use of temperature-modulated DSC in kinetic analysis of a catalysed epoxy-anhydride system. Polym Int 53 (2004) 326-331
18. Hedreul C., Galy J., Dupuy J., Delmotte M., and More C. Kinetics modeling of a modified epoxy-amine formulation cured by thermal and microwave energy. J Appl Polym Sci 68 (1998) 543-552
19. Costa M.L., Pardini L.C., and Rezende M.C. Influence of aromatic hardeners in the cure kinetics of an epoxy resin used in advanced composites. Mater Res 8 1 (2005) 65-70
20. Fernandez X., Ramis X., and Salla J.M. Cationic copolymerization of cycloaliphatic epoxy resin with an spirobislactone with lanthanum triflate as initiator. Thermochim Acta 438 1-2 (2005) 144-154
21. Wu S., and Soucek M.D. Crosslinking of acrylic latex coatings with cycloaliphatic diepoxide. Polymer 41 6 (2000) 2017-2028
22. Keenan M. Autocatalytic cure kinetics from DSC measurements: zero initial cure rate. J Appl Polym Sci 33 (1987) 1725-1734
23. Brown M.E. Introduction to thermal analysis. Techniques and applications (1988), Chapman and Hall, London
24. Kissinger H.E. Reaction kinetics in differential thermal analysis. Anal Chem 29 11 (1957) 1702-1706
25. Ozawa T. A new method of analyzing thermogravimetric data. Bull Chem Soc Jpn 38 11 (1965) 1881-1886
26. Ozawa T. Kinetic analysis of derivative curves in thermal analysis. J Therm Anal 2 (1970) 301-324
27. Horie K., Hiura H., Sawada M., Mita I., and Kambe H. Calorimetric investigation of polymerization reactions III - Curing reaction of epoxides with amines. J Polym Sci Part A-1 8 (1970) 1357-1372
28. Kamal M.R. Kinetics and thermal characterization of thermoset cure. Polym Eng Sci 13 (1973) 59-64
29. Sourour S., and Kamal M.R. Differential scanning calorimetry of epoxy cure: isothermal cure kinetics. Thermochim Acta 14 (1976) 41-59
30. Mortimer C.E. Chemie. Stuttgart (1987), Georg Thieme Verlag, New York p. 229-52
31. Holst M. Reaktionsschwindung von Epoxidharz-Systemen, Darmstadt. Dissertation; 2001.
32. Liu Y., Zhao M., Shen S., and Gao J. Curing kinetics, thermal property, and stability of tetrabromo-bisphenol-A epoxy resin with 4,4′-diaminodiphenyl ether. J Appl Polym Sci 70 (1998) 1991-2000
33. Fournier J., Williams G., Duch C., and Aldridge G.A. Changes in molecular-dynamics during bulk-polymerization of an epoxide-amine system as studied by dielectric-relaxation spectroscopy. Macromolecules 29 22 (1996) 7097-7107
34. Grohens Y., Touyeras F., George B., and Vebrel J. Effects of inhibitor and cure promoter on unsaturated polyester cure and mechanical properties. J Mater Sci Lett 14 (1995) 1460-1462
35. Chu T.-M.G., and Halloran J.W. Curing of highly-loaded ceramic suspension in acrylates. J Am Ceram Soc 83 (2000) 2375-2380
36. Lem K.W., and Han C.D. Chemorheology of thermosetting resins. II. Effect of particulates on the chemorheology and curing kinetics of unsaturated polyester resin. J Appl Polym Sci 28 (1983) 3185-3206
37. Dutta A., and Ryan M. Effect of fillers on kinetics of epoxy cure. J Appl Polym Sci 24 (1979) 635-649