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Synlett

Volumn , Issue 4, 2007, Pages 599-602

Chiral P-chlorophospholane: A versatile building block for the synthesis of ligands

(4) Holz, Jens a Monsees, Axel b Kadyrov, Renat b Börner, Armin a

a UNIVERSITY OF ROSTOCK (Germany)

b EVONIK INDUSTRIES AG (Germany)

Author keywords

Ligands; Phosphorus; Phosphorylation; Stereoselective synthesis

Indexed keywords

1 CHLORO 2,5 DIMETHYLPHOSPHOLANE; OXAZOLINEPHOSPHOLANE DERIVATIVE; PHOSPHINE DERIVATIVE; PHOSPHORUS; PICOLINE DERIVATIVE; T TRIMETHYLSILYLPHOSPHOLANE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CHLORINATION; ENANTIOMER; ENANTIOSELECTIVITY; PHOSPHORYLATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 33947318080 PISSN: 09365214 EISSN: None Source Type: Journal
DOI: 10.1055/s-2007-967974 Document Type: Article

Times cited : (17)

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26
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- Solvents were dried and freshly distilled under argon before use. All reactions were performed under an argon atmosphere by using standard Schlenk techniques. 1H, 13C and 31P NMR spectra were recorded on a Bruker ARX 400 spectrometer at the following frequencies: 400.13 MHz (1H, 100.63 MHz (13C, 161.98 MHz (31P, 235 MHz (19F) with CDCl3 as solvent, R,R)-1- Chloro-2,5-dimethylphospholane (2) A solution of 1-trimethylsilyl-2,5- dimethyl-phospholane (1, 10.0 g, 53.1 mmol) in CH2Cl 2 (60 mL) was added via cannula to a solution of hexachloroethane (12.6 g, 53.1 mmol) in CH2Cl2 (80 mL) under stirring at ambient temperature. Then the mixture was stirred under reflux for 30 min. After cooling, the solvent and tetrachlorethene was removed in vacuo (500 mbar) and the residue was distilled to give chlorophospholane 2 7.40 g, 93, a
- 2O (3 mL) was added.

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