Phosphorus Ligand Exchange Equilibria on Zerovalent Nickel. A Dominant Role for Steric Effects

Journal of the American Chemical Society

Volumn 92, Issue 10, 1970, Pages 2956-2965

  Tolman, Chadwick A ^a  

^a DUPONT COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33947294776     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00713a007     Document Type: Article

References (38)

1. J. W. Irvine, Jr., and G. Wilkinson, Science, 113, 742 (1951).
2. G. Wilkinson, J. Amer. Chem. Soc., 73, 5501 (1951).
3. “Tables of Wavenumbers for the Calibration of Infrared Spectrometers,” as reprinted in Pure Appl. Chem., 1 (4), 581 (1961).
4. The nickel-phosphorus bond length used of 2.28 Å is probably overestimated. There appear to be no Ni-P bond distances available for tetrahedral Ni(0) complexes; however, a value of 2.22 A has been reported in by W. A. Spofford, III, P. D. Carfagna, and E. L. Amma, Inorg. Chem., 6, 1553 (1967)
5. 2 by C. D. Cook, C. H. Koo, S. C. Nyburg, and M. T. Shiomi, Chem. Commun., 426 (1967).
6. B. Bogdanovic, M. Kroner, and G. Wilke, Justus Liebigs Ann. Chem., 699, 1 (1966).
7. R. S. Vinai and L. T. Reynolds Inorg. Chem., 3, 1062 (1964).
8. H. Bigorgne, Bull. Soc. Chim. Fr., 1986 (1960).
9. N. von Kutepow, H. Seibt, and F. Meier, U. S. Patent 3, 346,608 (1967).
10. J. R. Olechowski, C. G. McAlister, and R. F. Clark, Inorg. Chem., 4, 246 (1965);
11. R. F. Clark, U. S. Patent 3, 152,158 (1964).
12. W. Gerrard, W. J. Green, and R. J. Phillips, J. Chem. Soc., 1148 (1954).
13. F. G. Mann, A. F. Wells, and D. Purdie, J. Chem. Soc., 1828 (1937).
14. n by the general method given by G. M. Kosolapoff, “Organophosphorus Compounds,” John Wiley and Sons, Inc., New York, N. Y., 1950, p 184.
15. C. W. Heitsch and J. G. Verkade, Inorg. Chem., 1, 392 (1962).
16. G. W. Parshall, J. Inorg. Nucl. Chem., 14, 291 (1960).
17. R. N. Haszeldine and B. O. West, J. Chem. Soc., 3631 (1956).
18. L. A. Wall, R. E. Donadio, and W. J. Pummer, J. Amer. Chem. Soc., 82, 4846 (1960).
19. A. Orio, B. B. Chastain, and H. B. Gray, Inorg. Chim. Acta, 3, 8 (1969).
20. Extensive dissociation has been suggested on the basis of molecular weight data by P. Heimbach, Angew. Chem., 76, 586 (1964).
21. C. A. Tolman, J. Amer. Chem. Soc., 92, 2953 (1970).
22. 31P chemical shift on the electronic nature of substituents on phosphorus was also noted by J. R. Van Wazer and J. H. Letcher in “Topics in Phosphorus Chemistry,” Vol. 5, M. Grayson and E. J. Griffith, Ed., Interscience Publishers, Division of John Wiley and Sons, New York, N. Y., 1967, pp 176-179.
23. L. S. Meriwether and J. R. Leto, J. Amer. Chem. Soc., 83, 3192 (1961).
24. M. Meier, F. Basolo, and R. G. Pearson, Inorg. Chem., 8, 795 (1969).
25. 2 by S. O. Grim, D. A. Wheatland, and P. R. McAlister, Inorg. Chem., 7, 161 (1968).
26. W. Reppe and W. J. Schweckendiek, Justus Liebigs Ann. Chem., 560, 104 (1948).
27. L. Malatesta and A. Sacco, Ann. Chim. (Rome), 44, 134 (1954).
28. J. G. Verkade, R. E. McCarley, D. G. Hendricker, and R. W. King, Inorg. Chem., 4, 228 (1965).
29. W. S. Fyfe, J. Chem. Phys., 28, 907 (1958).
30. L. S. Meriwether and M. L. Fiene, J. Amer. Chem. Soc., 81, 4200 (1959).
31. F. Basolo and R. G. Pearson, “Mechanisms of Inorganic Reactions,” John Wiley and Sons, Inc., New York, N. Y., 1967, p 562.
32. R. D. W. Kemmitt, D. I. Nichols, and R. D. Peacock, J. Chem. Soc., 1898 (1968).
33. R. D. W. Kemmitt, D. I. Nichols, and R. D. Peacock, J. Chem. Soc., 2149 (1968).
34. A. B. Burg and W. Mahler, J. Amer. Chem. Soc., 80, 2334 (1958).
35. Th. Kruck, Ange w. Chem. Intern. Ed. Engl., 6, 53 (1967).
36. R. Poilblanc and M. Bigorgne, Bull. Soc. Chim. Fr., 1301 (1962).
37. R. D. Cramer, unpublished results.
38. J. P. Day, F. Basolo, and R. G. Pearson, J. Amer. Chem. Soc., 90, 6927 (1968).