Consistent application of the Boltzmann distribution to residual entropy in crystals

Journal of Chemical Education

Volumn 84, Issue 3, 2007, Pages 493-498

  Kozliak, Evguenii I ^a  

^a UNIVERSITY OF NORTH DAKOTA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOLTZMANN EQUATION; CALORIMETRY; CRYSTAL SYMMETRY; CRYSTALS; PROBABILITY; RANDOM PROCESSES; SPECIFIC HEAT; THERMODYNAMICS;

RESIDUAL ENTROPY;

ENTROPY;

EID: 33947255751     PISSN: 00219584     EISSN: None     Source Type: Journal    
DOI: 10.1021/ed084p493     Document Type: Article

References (36)

1. (a) Munowitz, M. Principles of Chemistry; Norton: New York, 2000; pp 491-501.
2. (b) Zumdahl, S. Chemical Principles, 4th ed.; Houghton Mifflin: Boston, 2002; Chapter 10, pp 395-424.
3. (c) Bell, J. Chemistry: A General Chemistry Project of the American Chemical Society; W. H. Freeman: New York, 2004; Chapter 8.
4. (d) McMurry, J.; Fay, R. C. Chemistry 4th ed.; Prentice Hall: New York, 2004; pp 727-728.
5. (e) Atkins, P. W; Jones, L. Chemical Principles: The Quest for Insight, 3rd ed.; W. H. Freeman: New York, 2005; pp 254-255.
6. Silbey, R. J.; Alberty, R. A. Physical Chemistry, 4th ed.; Wiley: New York, 2001; pp (a) 86,
7. Silbey, R. J.; Alberty, R. A. Physical Chemistry, 4th ed.; Wiley: New York, 2001; pp (b) 93,
8. Silbey, R. J.; Alberty, R. A. Physical Chemistry, 4th ed.; Wiley: New York, 2001; pp (c) 571-573,
9. Silbey, R. J.; Alberty, R. A. Physical Chemistry, 4th ed.; Wiley: New York, 2001; pp (d) 584.
10. (a) Atkins, P.; de Paula, J. Physical Chemistry 7th ed.; Freeman and Co.: New York, 2002; pp 672-673.
11. (b) Atkins, P.; de Paula, J. Physical Chemistry for the Life Sciences, Freeman and Co.: New York, 2005; p 520.
12. (c) Engel, T.; Reid, P. Physical Chemistry; Pearson Benjamin Cummings: San Francisco, 2005; pp 371-372.
13. Novak, I. J. Chem. Educ. 2003, 80, 1428-1431.
14. Kozliak, E. I. J. Chem. Educ. 2004, 81, 1595-1598.
15. Hynne, F. Chem. Educator 2004, 9, 74-79.
16. Hynne, F. Chem. Educator 2004, 9, 262-269.
17. Scott, R. L. J. Chem. Educ. 2006, 83, 1071-1081.
18. Jungermann, A. H. J. Chem. Educ. 2006, 83, 1686-1694.
19. (a) Boswijk, H. K.; van der Heide, J.; Vos, A.; Wiebenga, E. H. Acta Cryst. 1956, 9, 274-247.
20. (b) Calder, G. V.; Giauque, W. F. J. Phys. Chem. 1965, 69, 2443-2452.
21. (c) Lamoreaux, R. H.; Giauque, W. F. J. Phys. Chem. 1969, 73, 755-762.
22. Levine, I. N. Physical Chemistry, 5th ed.; McGraw-Hill: New York, 2002; pp 862-863.
23. Noggle, J. H. Physical Chemistry, 3rd ed.; Harper Collins: New York, 1997; pp (a) 220-221,
24. Noggle, J. H. Physical Chemistry, 3rd ed.; Harper Collins: New York, 1997; pp (b) 222-223,
25. Noggle, J. H. Physical Chemistry, 3rd ed.; Harper Collins: New York, 1997; pp (c) 223-231,
26. Noggle, J. H. Physical Chemistry, 3rd ed.; Harper Collins: New York, 1997; pp (d) 264.
27. Clayton, J. O.; Giauque, W. F. J. Am. Chem. Soc. 1932, 54, 2610-2626.
28. Shimada, T.; Matsuo, T.; Suga, H.; Luty, F. J. Chem. Phys. 1986, 85, 3530-3536.
29. Tozuka, Y.; Yamamura, Y.; Saito, K.; Sorai, M. J. Chem. Phys. 2000, 112, 2355-2360.
30. Tozuka, Y.; Akutsu, H.; Yamamura, Y.; Saito, K.; Sorai, M. Bull. Chem. Soc. Jpn. 2000, 73, 2279-2282.
31. Blue, R. W.; Giauque, W. F. J. Am. Chem. Soc. 1935, 57, 991-997.
32. Ko, G. H.; Fink, W. H. J. Chem. Phys. 2002, 116, 747-754.
33. Gavezzotti, A. J. Phys. Chem. B, 2003, 107, 2344-2353.
34. (a) Pauling, L. J. Am. Chem. Soc. 1935, 57, 2680-2684.
35. (b) Line, C. M. B.; Whitworth, R. W. J. Chem. Phys. 1996, 104, 10008-10013.
36. (c) Petrenko, V. F.; Whitworth, R. W. Physics of Ice; Oxford University Press: New York, 1999; pp 25-27, 257-263.