Analysis of sodium adduct paeoniflorin, albiflorin and their derivatives by (+)ESI-MSn, DFT calculations and computer-aided mass spectrometry analysis program

Journal of Mass Spectrometry

Volumn 42, Issue 3, 2007, Pages 335-345

  Li, Rui ^a   Wang, Xiaoling ^b   Zhou, Yan ^a   Cai, Min ^a   Ding, Lisheng ^a  

^a CHENGDU INSTITUTE OF BIOLOGY   (China)

^b SOUTHWEST UNIVERSITY FOR NATIONALITIES   (China)

Author keywords

Albiflorin and derivatives; Computer aided mass spectrometry analysis program; Dehydration ability; DFT calculations; Diagnostic fragment patterns; Paeonia Lactiflora; Paeoniflorin

Indexed keywords

COMPUTER-AIDED MASS SPECTROMETRY ANALYSIS PROGRAM; DEHYDRATION ABILITY; DIAGNOSTIC FRAGMENT PATTERNS; PAEONIA LACTIFLORA; PAEONIFLORIN;

ACTIVATION ENERGY; DEHYDRATION; DENSITY FUNCTIONAL THEORY; DERIVATIVES; MASS SPECTROMETRY; PROBABILITY DENSITY FUNCTION;

AROMATIC COMPOUNDS;

AGLYCONE; ALBIFLORIN; BENZOYLALBIFLORIN; BENZOYLPAEONIFLORIN; METHYLPAEONIFLORIN; OXYPAEONIFLORIN; PAEONIA LACTIFLORA EXTRACT; PAEONIFLORIN; PLANT EXTRACT; SODIUM; UNCLASSIFIED DRUG;

ADDUCTION; ARTICLE; CALCULATION; COMPUTER AIDED DESIGN; COMPUTER PROGRAM; DEHYDRATION; DENSITY FUNCTIONAL THEORY; DRUG DETERMINATION; DRUG STRUCTURE; ELECTROSPRAY MASS SPECTROMETRY; ENERGY; PAEONIA; PAEONIA LACTIFLORA; PRIORITY JOURNAL;

ALGORITHMS; BENZOIC ACIDS; BRIDGED COMPOUNDS; COMPUTER SIMULATION; GLUCOSIDES; MODELS, CHEMICAL; PAEONIA; SODIUM; SOFTWARE; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION;

PAEONIA LACTIFLORA;

EID: 33947253974     PISSN: 10765174     EISSN: 10969888     Source Type: Journal    
DOI: 10.1002/jms.1164     Document Type: Article

References (13)

1. Terasawa K. In Economic and Medical Plant Research, vol. 4, Wagner H, Famsworth NR (eds). Academic Press: San Diego, 1990; 57.
2. Lang HY, Li SZ, McCabe T, Clardy J. A new monoterpene glycoside of Paeonia lactiflora. Planta Med. 1984; 50: 501.
3. Jin Y, Elix JA, Iskander MN. Lactiflorine, a monoterpene gylcoside from peony root. Phytochemistry 1990; 29: 3859.
4. Kaneda M, Iitaka Y, Shibata S. The absolute structures of paeoniflorin, albiflorin, oxypaeoniflorin and benzoylpaeoniflorin isolated from Chinese paeony root. Tetrahedron 1972; 28: 4309.
5. Murakami N, Saka M, Shimada H, Matsuda H, Yamahara J, Yoshikawa M. New bioactive monoterpene glycoside from paeoniae radix. Chem. Pharm. Bull. 1996; 44: 1279.
6. Ohta H, Ni JW, Matsumoto K, Watanabe H, Shimizu M. Peony and its major constituent, paeoniflorin, improve radial maze performance impaired by scopolamine in rats. Pharmacol. Biochem. Behav. 1993; 45: 719.
7. Wang Q, Yang HY, Liu WN, Feng XL, Zhang LT, Li YL, Bi KS, Guo DA. Determination of paeoniflorin in rat plasma by a liquid chromatography-tandem mass spectrometry method coupled with solid-phase extraction. Biomed. Chromatogr. 2006; 20: 173.
8. Zhao XF, Sun YQ. Analysis of Paeoniae Radix by high-performance liquid chromatography-electrospray ionization-mass spectrometry. Anal. Sci. 2003; 19: 1313.
9. Frisch MJ, Trucks GW, Schlegel HB, Gill PMW, Johnson BG, Robb MA, Cheeseman JR, Keith T, Petersson GA, Montgomery JA, Raghavachari K, AlLaham MA, Zakrzewski VG, Ortiz JV, Foresman JB, Cioslowski J, Stefanov BB, Nanayakkara A, Challacombe M, Peng CY, Ayala PY, Chen W, Wong MW, Andres JL, Replogle ES, Gomperts R, Martin RL, Fox DJ, Binkley JS, Defrees DJ, Baker J, Stewart JP, HeadGordon M, Gonzalez C, Pople JA. GAUSSIAN94. Gaussian Inc: Pittsburgh, 1995.
10. Wang XL, Jiao W, Liao X, Peng SL, Ding LS. Chin. Chem. Lett. 2006; 17: 916.
11. Li R, Zhou Y, Wu ZJ, Ding LS. ESI-QqTOF-MS/MS and APCI-IT-MS/MS analysis of steroid saponins from the rhizomes of Dioscorea panthaica. J. Mass Spectrom. 2006; 41: 1.
12. Li R, Wu ZJ, Zhang F, Ding LS. Differentiation of three pairs of aconite alkaloid isomers from Aconitum nagarum var. lasiandrum by electrospray ionization tandem mass spectrometry. Rapid Commun. Mass Spectrom. 2006; 20: 157.
13. Liang F, Li LJ, Abliz Z, Yang YC, Shi JG. Structural characterization of steroidal saponins by electrospray ionization and fast-atom bombardment tandem mass spectrometry. Rapid Commun. Mass Spectrom. 2002; 16: 1168.