Solubility of zirconium(IV) hydrous oxides

Journal of Nuclear Science and Technology

Volumn 44, Issue 1, 2007, Pages 90-94

  Kobayashi, Taishi ^a   Sasaki, Takayuki ^a   Takagi, Ikuji ^a   Moriyama, Hirotake ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Equilibrium; Hydrolysis constants; Hydrous oxides; Solubility; Solubility product; Undersaturation method; Zirconium

Indexed keywords

COLLOIDS; HYDROLYSIS; PH EFFECTS; SOLUBILITY;

HYDROLYSIS CONSTANTS; HYDROUS OXIDES; SOLUBILITY PRODUCT; UNDERSATURATION METHOD;

ZIRCONIUM COMPOUNDS;

EID: 33947126531     PISSN: 00223131     EISSN: None     Source Type: Journal    
DOI: 10.1080/18811248.2007.9711260     Document Type: Article

References (21)

1. P. N. Kovalenko, K. N. Bagdsarov, “The solubility of zirconium hydroxide,” Russ. J. Inorg. Chem., 6, 272 (1961).
2. H. Bilinski, M. Branica, L. G. Sillen, “Preparation and hydrolysis of metallic ions. II. Studies on the solubility of zirconium hydroxide in dilute solutions and 1M NaClO4,” Acta Chem. Scand., 20, 853 (1966).
3. A. J. Zielen, R. E. Connick, “The hydrolytic polymerization of zirconium in perchloric acid solutions,” J. Amer. Chem. Soc., 78, 5785 (1956).
4. G. M. Muha, P. A. Vaughan, “Structure of the complex ion in aqueous solutions of zirconyl and hafnyl oxyhalides,” J. Chem. Phys. 33, 194 (1960).
5. C. F. Baes, R. E. Mesmer, The Hydrolysis of Cations, John Wiley & Sons, New York (1976).
6. C. Hagfeldt, V. Kessler, I. Persson, “Structure of the hydrated, hydrolysed and solvated zirconium(IV) and hafnium(IV) ions in water and aprotic oxygen donor solvents. A crystallograph-ic, EXAFS spectroscopic and large angle X-ray scattering study,” J. Chem. Soc. Dalton Trans. Inorg. Chem., 14, 2142 (2004).
7. A. Veyland, L. Dupont, C. Pierrad et al., “Thermodynamic stability of zirconium(IV) complexes with hydroxy ions, Eur. J. Inorg. Chem. 1765 (1998).
8. C. Ekberg, G. Kallvenius, Y. Albinsson et al., “Studies on the hydrolytic behavior of zirconium(IV),” J. Solution Chem., 33, 47 (2004).
9. P. Brown, E. Curti, B. Grambow et al., Chemical Thermodynamics of Zirconium, Chemical Thermodynamics, F. J. Mompean et al. (eds.), Vol. 8, Elsevier, North-Holland, Amsterdam (2005).
10. H. Moriyama, T. Sasaki, T. Kobayashi et al., “Systematics of hydrolysis constants of tetravalent actinide ions, J. Nucl. Sci. Technol., 42, 626 (2005).
11. J. R. Fryer, J. L. Hutchison, R. Paterson, “An electron microscopic study of the hydrolysis products of zirconyl chloride, J. Colloid Interface Sci., 34, 238 (1970).
12. A. Clearfield, “Structural aspects of zirconium chemistry,” Rev. Pure Appl. Chem., 14, 91 (1964).
13. H. Cho, C. Walther, J. Roche et al., “Combined LIBD and XAFS investigation of the formation and structure of Zr(IV) colloids,” Anal. Bioanal. Chem., 383, 28 (2005).
14. T. Sasaki, T. Kobayashi, I. Takagi et al., “Solubility measurement of zirconium(IV) hydrous oxide, Radiochim. Acta, (in press) (2006).
15. P. Flory, Principles of Polymer Chemistry, Cornell Univ. Press, New York (1953).
16. V. Keramidas, W. White, “Raman scattering study of the crystallization and phase transformations of ZrO2, J. Am. Ceram. Soc., 57, 22 (1974).
17. V. Nazarenko, O. Mandzhgaladze, “Determination of the formation constants of hydroxo-complexes of zirconium by the method of competing reactions,” Russ. J. Inorg. Chem., 14, 639 (1969).
18. 4+,” Acta Chem. Scand., 27, 1369 (1973).
19. E. Curti, Paul Scherrer Institut Rep. TM-44-01-01 (2001).
20. R. Guillaumont, T. Fanghanel, J. Fuger et al., Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium, Chemical Thermodynamics, F. J. Mompean et al. (eds.), Vol. 5, Elsevier, North-Holland, Amsterdam (2003).
21. M. Pouchon, E. Curti, C. Degueldre et al., “The influence of carbonate complexes on the solubility of zirconia: new experimental data,” Progr. Nucl. Energy 38, 443 (2001).