메뉴 건너뛰기




Volumn 86, Issue 3-4, 2007, Pages 121-130

Europium separation from a middle rare earths concentrate derived from Egyptian black sand monazite

Author keywords

Europium separation; Monazite; Precipitation; Reduction; Zinc reductor

Indexed keywords

CHLORIDE MINERALS; EUROPIUM; OXIDATION; PRECIPITATION (CHEMICAL); RARE EARTHS; REDUCTION; SULFATE MINERALS;

EID: 33947110012     PISSN: 0304386X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.hydromet.2006.10.007     Document Type: Article
Times cited : (34)

References (42)
  • 1
    • 33947111967 scopus 로고    scopus 로고
    • Modified spectrophotometric procedures for europium analysis in presence of samarium and gadolinium
    • Abdel Hamied M.A., Rabie K.A., Sayed S.A., and Salama I.E. Modified spectrophotometric procedures for europium analysis in presence of samarium and gadolinium. Al-Azhar Bull. Sci. 15 1 (2004) 311-324
    • (2004) Al-Azhar Bull. Sci. , vol.15 , Issue.1 , pp. 311-324
    • Abdel Hamied, M.A.1    Rabie, K.A.2    Sayed, S.A.3    Salama, I.E.4
  • 2
    • 33947171126 scopus 로고    scopus 로고
    • Roskill Information Services, London 359-364 pp.
    • Anon. The Economics of Rare Earths and Yttrium (1998), Roskill Information Services, London 359-364 pp.
    • (1998) The Economics of Rare Earths and Yttrium
  • 3
    • 85050055491 scopus 로고
    • Europium (II) salts
    • Fernelius W.C. (Ed), McGraw Hill, New York
    • Cooley R.A., and Yost D.M. Europium (II) salts. In: Fernelius W.C. (Ed). Inorganic Synthesis (1946), McGraw Hill, New York 69-73
    • (1946) Inorganic Synthesis , pp. 69-73
    • Cooley, R.A.1    Yost, D.M.2
  • 5
    • 0000932610 scopus 로고
    • Photochemical separation of europium from lanthanide mixtures in aqueous solution
    • Donohue T. Photochemical separation of europium from lanthanide mixtures in aqueous solution. J. Chem. Phys. 67 11 (1977) 5402-5404
    • (1977) J. Chem. Phys. , vol.67 , Issue.11 , pp. 5402-5404
    • Donohue, T.1
  • 6
    • 0018444703 scopus 로고
    • Laser purification of the rare earths
    • Donohue T. Laser purification of the rare earths. Opt. Eng. 18 2 (1979) 181-186
    • (1979) Opt. Eng. , vol.18 , Issue.2 , pp. 181-186
    • Donohue, T.1
  • 7
    • 33947147284 scopus 로고    scopus 로고
    • Dumousseau, J.U., Rollat, A., Sabot, J.L., 1990. Recovery of europium (II) values by electrolysis. US Patent 4,938,852, USA.
  • 8
    • 27444434830 scopus 로고
    • Preparation of high purity europium oxide using combined reduction-ion exchange method
    • Elbanowski M., and Baranowska J. Preparation of high purity europium oxide using combined reduction-ion exchange method. J. Less-Common Met. 112 (1985) 267-270
    • (1985) J. Less-Common Met. , vol.112 , pp. 267-270
    • Elbanowski, M.1    Baranowska, J.2
  • 9
    • 70350315430 scopus 로고
    • Separation of samarium and europium from Egyptian monazite sands by sodium amalgam. Part I
    • Farah M.Y., Saleh F.A., and Moustafa M. Separation of samarium and europium from Egyptian monazite sands by sodium amalgam. Part I. Z. Anorg. Allg. Chem. 392 1 (1972) 69-80
    • (1972) Z. Anorg. Allg. Chem. , vol.392 , Issue.1 , pp. 69-80
    • Farah, M.Y.1    Saleh, F.A.2    Moustafa, M.3
  • 10
    • 0036138156 scopus 로고    scopus 로고
    • Recovery of europium by electrochemical reduction from sulphate solutions
    • Girgin I., and Yorukoglu A. Recovery of europium by electrochemical reduction from sulphate solutions. Hydrometallurgy 63 (2002) 85-91
    • (2002) Hydrometallurgy , vol.63 , pp. 85-91
    • Girgin, I.1    Yorukoglu, A.2
  • 12
    • 0029209327 scopus 로고
    • Separation of Eu from Sm/Eu/Gd mixture by photoreductive stripping in solvent extraction process
    • Hirai T., and Komasawa I. Separation of Eu from Sm/Eu/Gd mixture by photoreductive stripping in solvent extraction process. Ind. Eng. Chem. Res. 34 (1995) 237
    • (1995) Ind. Eng. Chem. Res. , vol.34 , pp. 237
    • Hirai, T.1    Komasawa, I.2
  • 13
    • 0027492103 scopus 로고
    • Separation of europium from samarium and gadolinium by combination of photochemical reduction and solvent extraction
    • Hirai T., Onoe N., and Komasawa I. Separation of europium from samarium and gadolinium by combination of photochemical reduction and solvent extraction. J. Chem. Eng. Jpn. 26 (1993) 64
    • (1993) J. Chem. Eng. Jpn. , vol.26 , pp. 64
    • Hirai, T.1    Onoe, N.2    Komasawa, I.3
  • 14
    • 33947127759 scopus 로고    scopus 로고
    • Hugh, B.J., 1964. Purification of europium. US Patent 3,153,571, USA.
  • 15
    • 33947176222 scopus 로고    scopus 로고
    • Jingjun, Z., Shubin, W., Guifen, G., 1996. Method for removing europium oxide from high pure gadolinium oxide. China Patent 1,125,260.
  • 17
    • 3543015534 scopus 로고    scopus 로고
    • Estimation of the optimum concentration interval of the constants of praseodymium, neodymium, europium, holmium, and erbium in solution
    • Kostyuk N.N., Dik T.A., and Trebnikov A.G. Estimation of the optimum concentration interval of the constants of praseodymium, neodymium, europium, holmium, and erbium in solution. J. Appl. Spectrosc. 71 1 (2004) 147-150
    • (2004) J. Appl. Spectrosc. , vol.71 , Issue.1 , pp. 147-150
    • Kostyuk, N.N.1    Dik, T.A.2    Trebnikov, A.G.3
  • 18
    • 33947099051 scopus 로고    scopus 로고
    • Lanping, L., Fangchun, X., Zhi, Q., 1994. Process for extracting high-purity europium oxide. China Patent 1087126.
  • 19
    • 0011368012 scopus 로고
    • Rapid radiochemical separations. II. Separation of europium from other lanthanides
    • Malan H.P., and Muenzel H. Rapid radiochemical separations. II. Separation of europium from other lanthanides. Radiochim. Acta 15 (1966) 20-23
    • (1966) Radiochim. Acta , vol.15 , pp. 20-23
    • Malan, H.P.1    Muenzel, H.2
  • 20
    • 0040732083 scopus 로고
    • The separation of europium from other rare earths
    • McCoy H.N. The separation of europium from other rare earths. J. Am. Chem. Soc. 57 (1935) 1756
    • (1935) J. Am. Chem. Soc. , vol.57 , pp. 1756
    • McCoy, H.N.1
  • 21
    • 0347451610 scopus 로고
    • The extraction of europium from monazite residues and the preparation of pure europium compounds
    • McCoy H.N. The extraction of europium from monazite residues and the preparation of pure europium compounds. J. Am. Chem. Soc. 58 (1936) 2279-2280
    • (1936) J. Am. Chem. Soc. , vol.58 , pp. 2279-2280
    • McCoy, H.N.1
  • 22
    • 0007677550 scopus 로고
    • An improved method of purifying europium
    • McCoy H.N. An improved method of purifying europium. J. Am. Chem. Soc. 59 (1937) 1131-1134
    • (1937) J. Am. Chem. Soc. , vol.59 , pp. 1131-1134
    • McCoy, H.N.1
  • 23
    • 0039094542 scopus 로고
    • The electrolysis of rare earth acetates and the separation of europium as amalgam from other rare earths
    • McCoy H.N. The electrolysis of rare earth acetates and the separation of europium as amalgam from other rare earths. J. Am. Chem. Soc. 63 (1941) 3432-3433
    • (1941) J. Am. Chem. Soc. , vol.63 , pp. 3432-3433
    • McCoy, H.N.1
  • 24
    • 13344274310 scopus 로고
    • Europium and ytterbium amalgams
    • McCoy H.N. Europium and ytterbium amalgams. J. Am. Chem. Soc. 63 (1941) 1622-1624
    • (1941) J. Am. Chem. Soc. , vol.63 , pp. 1622-1624
    • McCoy, H.N.1
  • 25
    • 27444440732 scopus 로고
    • Reduction of europium (III) by zinc amalgam in acetate medium
    • Melnik M.I., and Filimonov V.G. Reduction of europium (III) by zinc amalgam in acetate medium. Radiokhimiya 34 6 (1992) 69-72
    • (1992) Radiokhimiya , vol.34 , Issue.6 , pp. 69-72
    • Melnik, M.I.1    Filimonov, V.G.2
  • 26
    • 27444438662 scopus 로고
    • Separation of europium from a rare earth concentrate, a by product of the apatite processing
    • Minkova N. Separation of europium from a rare earth concentrate, a by product of the apatite processing. Khim. Fak. 88 (1995) 25-30
    • (1995) Khim. Fak. , vol.88 , pp. 25-30
    • Minkova, N.1
  • 27
    • 27444442986 scopus 로고    scopus 로고
    • Influence of the eluent concentration on the ion exchange separation of europium (II) from rare earth concentrate
    • Minkova N., and Todorovsky S. Influence of the eluent concentration on the ion exchange separation of europium (II) from rare earth concentrate. Bulg. Chem. Commun. 29 1 (1997) 84-89
    • (1997) Bulg. Chem. Commun. , vol.29 , Issue.1 , pp. 84-89
    • Minkova, N.1    Todorovsky, S.2
  • 28
    • 0032100052 scopus 로고    scopus 로고
    • Recovery of europium from a rare earth chloride solution
    • Morais C.A., and Ciminelli V.S.T. Recovery of europium from a rare earth chloride solution. Hydrometallurgy 49 (1998) 167-177
    • (1998) Hydrometallurgy , vol.49 , pp. 167-177
    • Morais, C.A.1    Ciminelli, V.S.T.2
  • 29
    • 0035341793 scopus 로고    scopus 로고
    • Recovery of europium by chemical reduction of a commercial solution of europium and gadolinium chlorides
    • Morais C.A., and Ciminelli V.S.T. Recovery of europium by chemical reduction of a commercial solution of europium and gadolinium chlorides. Hydrometallurgy 60 (2001) 247-253
    • (2001) Hydrometallurgy , vol.60 , pp. 247-253
    • Morais, C.A.1    Ciminelli, V.S.T.2
  • 30
    • 0141746209 scopus 로고
    • Comparative liquid-liquid extraction behaviour of europium (II) and europium (III)
    • Peppard D.F., Horwitz E.P., and Masson G.W. Comparative liquid-liquid extraction behaviour of europium (II) and europium (III). J. Inorg. Nucl. Chem. 24 (1962) 429-439
    • (1962) J. Inorg. Nucl. Chem. , vol.24 , pp. 429-439
    • Peppard, D.F.1    Horwitz, E.P.2    Masson, G.W.3
  • 31
    • 33947180032 scopus 로고    scopus 로고
    • Peppard, D.F., Horwitz, E.P., Masson, G.W., 1962b. Separation of europium from other lanthanides by solvent extraction. Belgian Patent 620 084.
  • 32
    • 0029657223 scopus 로고    scopus 로고
    • The separation of europium from a middle rare earth concentrate by combined chemical reduction, precipitation, and solvent extraction methods
    • Preston J.S., and Du Preez A.C. The separation of europium from a middle rare earth concentrate by combined chemical reduction, precipitation, and solvent extraction methods. J. Chem. Tech. Biotechnol. 65 (1996) 93-101
    • (1996) J. Chem. Tech. Biotechnol. , vol.65 , pp. 93-101
    • Preston, J.S.1    Du Preez, A.C.2
  • 33
    • 0030243790 scopus 로고    scopus 로고
    • The recovery of rare earth oxides rom a phosphoric acid by-product. Part 3. The separation of middle and light rare earth fraction and the preparation of pure europium oxide
    • Preston J.S., Du Preez A.C., Cole M.H., and Fox P.M. The recovery of rare earth oxides rom a phosphoric acid by-product. Part 3. The separation of middle and light rare earth fraction and the preparation of pure europium oxide. Hydrometallurgy 42 (1996) 131-149
    • (1996) Hydrometallurgy , vol.42 , pp. 131-149
    • Preston, J.S.1    Du Preez, A.C.2    Cole, M.H.3    Fox, P.M.4
  • 34
    • 0025843313 scopus 로고
    • A study on photochemical separation of rare earths: the separation of europium from an industrial concentrate material of samarium, europium, and gadolinium
    • Qiu L., Kang X., and Wang T. A study on photochemical separation of rare earths: the separation of europium from an industrial concentrate material of samarium, europium, and gadolinium. Sep. Sci. Technol. 26 2 (1991) 199-221
    • (1991) Sep. Sci. Technol. , vol.26 , Issue.2 , pp. 199-221
    • Qiu, L.1    Kang, X.2    Wang, T.3
  • 35
    • 33947156816 scopus 로고    scopus 로고
    • Rabie, K.A., 1996. Studies on The Separation of some rare earth elements from Egyptian monazite sand. Ph. D Thesis, Cairo University, Faculty of Science, Egypt, Cairo.
  • 36
    • 33846609750 scopus 로고    scopus 로고
    • Separation of cerium (III) from Egyptian monazite by oxidation to cerium (IV)
    • Rabie K.A., et al. Separation of cerium (III) from Egyptian monazite by oxidation to cerium (IV). Third Conf. On Peaceful Uses of Atomic Energy, Damascus (1996) 355-360
    • (1996) Third Conf. On Peaceful Uses of Atomic Energy, Damascus , pp. 355-360
    • Rabie, K.A.1
  • 37
    • 33845379780 scopus 로고
    • Chemistry and thermodynamics of europium and some of its simpler inorganic compounds and aqueous species
    • Rard J.A. Chemistry and thermodynamics of europium and some of its simpler inorganic compounds and aqueous species. Chem. Rev. 85 (1985) 555-582
    • (1985) Chem. Rev. , vol.85 , pp. 555-582
    • Rard, J.A.1
  • 38
    • 33947170629 scopus 로고    scopus 로고
    • Salama, I.E., 2005. Studies on the separation of europium middle rare earth concentrate derived from Egyptian black sand monazite. M. Sc. Thesis, Helwan University, Helwan.
  • 39
    • 27444436636 scopus 로고    scopus 로고
    • Studies on europium separation from a middle rare earth concentrate by in-situ zinc reduction technique
    • Sayed S.A., Rabie K.A., and Salama I.E. Studies on europium separation from a middle rare earth concentrate by in-situ zinc reduction technique. Sep. Purif. Technol. 46 (2005) 145-154
    • (2005) Sep. Purif. Technol. , vol.46 , pp. 145-154
    • Sayed, S.A.1    Rabie, K.A.2    Salama, I.E.3
  • 40
    • 33947157751 scopus 로고    scopus 로고
    • Selin, D.L., Malkov, A.V., Tarasova, N.P., 1990. Europium separation from sulphuric acid solutions. USSR Patent 1,604,741, USSR.
  • 41
    • 0022875613 scopus 로고
    • Radiation chemical separation of europium from aqueous lanthanide mixtures
    • Shastri L.V., Lalitha J., Mittal J., and Mittal P. Radiation chemical separation of europium from aqueous lanthanide mixtures. Radiat. Phys. Chem. 28 4 (1986) 359-361
    • (1986) Radiat. Phys. Chem. , vol.28 , Issue.4 , pp. 359-361
    • Shastri, L.V.1    Lalitha, J.2    Mittal, J.3    Mittal, P.4
  • 42
    • 0011431535 scopus 로고
    • Reduction by amalgamated zinc: significant factors in efficiency
    • Stone H.W., and Hume D.N. Reduction by amalgamated zinc: significant factors in efficiency. Ind. Eng. Chem. 11 11 (1939) 598-603
    • (1939) Ind. Eng. Chem. , vol.11 , Issue.11 , pp. 598-603
    • Stone, H.W.1    Hume, D.N.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.