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Volumn 94, Issue 4, 1972, Pages 1219-1238

Titanocene as an Intermediate in Reactions Involving Molecular Hydrogen and Nitrogen

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EID: 33947089307     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00759a032     Document Type: Article
Times cited : (428)

References (75)
  • 10
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    • and literature cited therein
    • E. E. van Tamelen, Accounts Chem. Res., 3, 361 (1970), and literature cited therein.
    • (1970) Accounts Chem. Res. , vol.3 , pp. 361
    • van Tamelen, E.E.1
  • 15
    • 4243714250 scopus 로고
    • 3 was first obtained by treatment of TiCU with isobutene at 300° and 30–60 atm pressure
    • 3 was first obtained by treatment of TiCU with isobutene at 300° and 30–60 atm pressure: H. Rohl, E. Lange, T. Gossel, and G. Roth, Angew. Chem., 74, 155 (1962).
    • (1962) Angew. Chem. , vol.74 , pp. 155
    • Rohl, H.1    Lange, E.2    Gossel, T.3    Roth, G.4
  • 31
    • 0000148679 scopus 로고
    • 2 toward tetrahydrofuran could explain some of the earlier observations concerning green and brown titanocene THF adducts: see
    • 2 toward tetrahydrofuran could explain some of the earlier observations concerning green and brown titanocene THF adducts: see, A. K. Fischer and G. Wilkinson, J. Inorg. Nucl. Chem., 2, 149 (1956)
    • (1956) J. Inorg. Nucl. Chem. , vol.2 , pp. 149
    • Fischer, A.K.1    Wilkinson, G.2
  • 40
    • 85021468949 scopus 로고
    • Thesis, Rijksuniversiteit te Groningen
    • H. A. Martin, Thesis, Rijksuniversiteit te Groningen, 1967.
    • (1967)
    • Martin, H.A.1
  • 45
    • 34250535162 scopus 로고
    • and earlier references quoted there
    • V. Gutmann and M. Michmayr, Monatsh. Chem., 99, 316 (1968), and earlier references quoted there.
    • (1968) Monatsh. Chem. , vol.99 , pp. 316
    • Gutmann, V.1    Michmayr, M.2
  • 52
    • 37049133143 scopus 로고
    • This exchange between Ds and all the ring hydrogen positions has been observed before by
    • This exchange between Ds and all the ring hydrogen positions has been observed before by H. A. Martin and R. O. de Jongh (Chem. Commun., 1366 (1969))
    • (1969) Chem. Commun. , pp. 1366
    • Martin, H.A.1    de Jongh, R.O.2
  • 53
    • 0007885481 scopus 로고
    • 2 and the aromatic solvent, as has been observed with tantalocene and niobocene hydrides
    • 2 and the aromatic solvent, as has been observed with tantalocene and niobocene hydrides (E. K. Barefield, G. W. Parshall, and F. N. Tebbe, J. Amer. Chem. Soc., 92, 5235 (1970);
    • (1970) J. Amer. Chem. Soc. , vol.92 , pp. 5235
    • Barefield, E.K.1    Parshall, G.W.2    Tebbe, F.N.3
  • 63
    • 85021471937 scopus 로고
    • 2 and in the reduction of molecular nitrogen
    • 2 and in the reduction of molecular nitrogen.
    • (1968)
    • Schurig, V.1
  • 69
    • 85021464425 scopus 로고
    • For a recent review see
    • For a recent review see A. D. Allen, Advan. Chem. Ser., No. 100, 79 (1971).
    • (1971) Advan. Chem. Ser. , Issue.100 , pp. 79
    • Allen, A.D.1
  • 70
    • 0000314775 scopus 로고
    • The resulting bonding situation is then comparable to that of those alkyne complexes in which the acetylene ligand substitutes for two monodentate ligand groups, i.e., where the acetylene ligand is bound to a 14-electron species. In these complexes the red-shift of the C≡C stretching vibration is several times larger than in those alkyne complexes where the acetylene is coordinated to a species with 16 valence electrons
    • The resulting bonding situation is then comparable to that of those alkyne complexes in which the acetylene ligand substitutes for two monodentate ligand groups, i.e., where the acetylene ligand is bound to a 14-electron species. In these complexes the red-shift of the C≡C stretching vibration is several times larger than in those alkyne complexes where the acetylene is coordinated to a species with 16 valence electrons (E. O. Graves, C. J. L. Lock, and P. M. Maitlis, Can. J. Chem., 46, 3879 (1968)).
    • (1968) Can. J. Chem. , vol.46 , pp. 3879
    • Graves, E.O.1    Lock, C.J.L.2    Maitlis, P.M.3
  • 73
    • 85021469960 scopus 로고    scopus 로고
    • personal communication
    • A. J. Ashe III, personal communication.
    • Ashe, A.J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.