Ligand-to-Metal Intramolecular Electron Transfer in the Reduction of p-Nitrobenzoatopentaamminecobalt(III) Ion

Journal of the American Chemical Society

Volumn 94, Issue 5, 1972, Pages 1757-1759

  Hoffman, Morton Z ^a   Simic, M ^a  

^a BOSTON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33947088899     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00760a063     Document Type: Article

References (16)

1. E. J. Hart and M. Anbar, “The Hydrated Electron,” Wiley-Interscience, New York, N. Y., 1970.
2. D. Katakis and A. O. Allen, J. Phys. Chem., 68, 1359 (1964).
3. N. Zevos, J. Phys. Chem., 72, 1506 (1968).
4. J. H. Baxendale, E. M. Fielden, and J. P. Keene, Proc. Roy. Soc., Ser. A, 286, 320 (1965).
5. M. Z. Hoffman and M. Simic, J. Amer. Chem. Soc., 92, 5533 (1970).
6. 3+ has been attributed to low-spin Co(II): W. L. Waltz and R. G. Pearson, J. Phys. Chem., 73, 1941 (1969).
7. –: E. P. Vanek and M. Z. Hoffman, manuscript in preparation.
8. M. Anbar in “Fundamental Processes in Radiation Chemistry,” P. Ausloos, Ed., Wiley-Interscience, New York, N. Y., 1968, p 651.
9. The complex was synthesized using the procedure of E. S. Gould and H. Taube, J. Amer. Chem. Soc., 86, 1318 (1964).
10. M. Simic, P. Neta, and E. Hayon, J. Phys. Chem., 73, 3794 (1969).
11. 2+ were performed as described by E. R. Kantrowitz, M. Z. Hoffman, and J. F. Endicott, J. Phys. Chem., 75, 1914 (1971).
12. M. Simic and M. Z. Hoffman, J. Phys. Chem., in press.
13. K. D. Asmus, A. Wigger, and A. Henglein, Ber. Bunsenges. Phys. Chem., 70, 862 (1966).
14. W. GrUnbein, A. Fojtic, and A. Henglein, Z. Naturforsch., B, 24, 1336 (1969).
15. H. Taube, “Electron Transfer Reactions of Complex Ions in Solution,” Academic Press, New York, N. Y., 1970.
16. E. S. Gould, J. Amer. Chem. Soc., 88, 2987 (1966).