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Volumn 95, Issue 10, 1973, Pages 3300-3310

Copper(I) Catalysis in Cyclopropanations with Diazo Compounds. The Role of Olefin Coordination

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EID: 33947085212     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00791a038     Document Type: Article
Times cited : (313)

References (52)
  • 1
    • 0004050551 scopus 로고
    • 2nd ed, Academic Press, New York, N. Y.
    • W. Kirmse, “Carbene Chemistry” 2nd ed, Academic Press, New York, N. Y., 1971.
    • (1971) Carbene Chemistry
    • Kirmse, W.1
  • 23
    • 0008475220 scopus 로고
    • The stability of copper (I) -olefin complexes like the silver (I) analogs28 decreases with alkyl substitution on the olefinic carbon atoms
    • The stability of copper (I) -olefin complexes like the silver (I) analogs28 decreases with alkyl substitution on the olefinic carbon atoms: R. M. Keefer, L. J. Andrews, and R. E. Kepner, J. Amer. Chem. Soc, 71, 3906 (1949).
    • (1949) J. Amer. Chem. Soc , vol.71 , pp. 3906
    • Keefer, R.M.1    Andrews, L.J.2    Kepner, R.E.3
  • 31
    • 37049122975 scopus 로고
    • Recently, stable isoelectronic analogs of such complexes, viz., diazoalkane-nickel (O) complexes containing olefins, have been isolated, but on decomposition do not afford cyclopropanation products, (b) A variety of stable carbene complexes of metals are known, sup but none of copper
    • Recently, stable isoelectronic analogs of such complexes, viz., diazoalkane-nickel (O) complexes containing olefins, have been isolated, but on decomposition do not afford cyclopropanation products: S. Otsuka, A. Nakamura, T. Koyama, and Y. Tatsuno, J. Chem. Soc., Chem. Commun., 1105 (1972). (b) A variety of stable carbene complexes of metals are known, sup but none of copper.
    • (1972) J. Chem. Soc., Chem. Commun. , pp. 1105
    • Otsuka, S.1    Nakamura, A.2    Koyama, T.3    Tatsuno, Y.4
  • 37
    • 49649152526 scopus 로고
    • There is no evidence for copper (II) -olefin complexes except under special circumstances
    • There is no evidence for copper (II) -olefin complexes except under special circumstances: R. A. Zelonka and M. C. Baird, J. Organometal. Chem., 33, 267 (1971).
    • (1971) J. Organometal. Chem. , vol.33 , pp. 267
    • Zelonka, R.A.1    Baird, M.C.2
  • 39
    • 0000922129 scopus 로고
    • cf. for silver (0)
    • cf. for silver (0), M. C. Lea, Amer. J. Sci., 37, 476 (1889).
    • (1889) Amer. J. Sci. , vol.37 , pp. 476
    • Lea, M.C.1
  • 40
    • 0004032955 scopus 로고
    • Formally, no change in oxidation state is required to proceed from carbene RCH to RCH. X. The latter, however, may be formed by two successive free-radical reactions (H atom and ligand transfer) in which case the copper species may suffer reduction, Wiley-Interscience, New York, N. Y., Chapter 11
    • Formally, no change in oxidation state is required to proceed from carbene RCH to RCH. X. The latter, however, may be formed by two successive free-radical reactions (H atom and ligand transfer) in which case the copper species may suffer reduction: J. K. Kochi, “Free Radicals,” Wiley-Interscience, New York, N. Y., 1973, Chapter 11.
    • (1973) Free Radicals
    • Kochi, J.K.1
  • 41
    • 85022389206 scopus 로고    scopus 로고
    • For copper (I) tetrafluoroborate, see (a), U. S. Patent 2, 953, 589
    • For copper (I) tetrafluoroborate, see (a) D. A. McCauley, U. S. Patent 2, 953, 589;
    • McCauley, D.A.1
  • 42
    • 85022423155 scopus 로고
    • Chem. Abstr., 55, P 3050a (1961);
    • (1961) Chem. Abstr. , vol.55 , pp. 3050a
  • 43
    • 85022371693 scopus 로고    scopus 로고
    • private communication
    • M. Dines, private communication.
    • Dines, M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.