Crystallization of a rare earth-rich aluminoborosilicate glass with varying CaO/Na2O ratio

Journal of the American Ceramic Society

Volumn 90, Issue 3, 2007, Pages 712-719

  Quintas, Arnaud ^a   Majérus, Odile ^a   Caurant, Daniel ^a   Dussossoy, Jean Luc ^b   Vermaut, Philippe ^a  

^a PSL RESEARCH UNIVERSITY   (France)

^b CEA Marcoule   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL GROWTH; CRYSTALLIZATION; NUCLEATION; PHASE SEPARATION; SOLUBILITY;

ALUMINOBOROSILICATE GLASS; SILICATE APATITE;

GLASS;

EID: 33847700499     PISSN: 00027820     EISSN: 15512916     Source Type: Journal    
DOI: 10.1111/j.1551-2916.2006.01455.x     Document Type: Conference Paper

References (18)

1. I. Bardez, "Structure and Crystallization Properties of Rare-Earth Rich Aluminoborosilicate Glasses Devoted to Nuclear Waste Immobilization"; Ph.D. thesis of the University of Paris, 6, 2004.
2. I. Bardez, D. Caurant, P. Loiseau, J.-L. Dussossoy, C. Gervais, F. Ribol, D. R. Neuville, and N. Baffler, "Structural Characterization of Rare-Earth Rich Glasses for Nuclear Waste Immobilization," Phys. Chem. Glasses, 46, 320-9 (2006).
3. I. Bardez, D. Cauranl, J. L. Dussossoy, P. Loiseau, C. Gervais, F. Ribot, D. R. Neuville, N. Baffler, and C. Fillet, "Development and Characterization of RareEarth Rich Glass Matrices Envisaged for the Immobilization of Concentrated Nuclear Waste Solutions," Nucl. Sci. Eng., 153, 272-84 (2006).
4. E. R. Vance, C. J. Ball, B. D. Begg, M. L. Carter, R. A. Day, and G. J. Thorogood, "Pu, U and Hf Incorporation in Gd Silicate Apatite," J. Am. Ceram. Soc., 86, 1223-5 (2003).
5. D. Zhao, L. Li, L. L. Davis, W. J. Weber, and R. C. Ewing, "Gadolinium Borosilicate Glass-Bonded Gd-Silicate Apatite: A Glass-Ceamic Nuclear Waste Form for Actinides," Mater. Res. Soc. Symp. Proc., 663, 199-206 (2001).
6. D. Cauranl. O. Majérus, P. Loiseau, I. Bardez, N. Baffler, and J. L. Dussossoy, "Crystallization of Neodymium-Rich Phases in Silicate Glasses Developed for Nuclear Waste Immobilization," J. Nucl. Mater., 354, 143-62 (2006).
7. 2," Radiat. Eff., 77, 295-308 (1983).
8. W. J. Weber, "Alpha-Decay-Indviced Amorphization in Complex Silicate Structures," J. Am. Ceram. Soc., 76 [7] 1729-38 (1993).
9. J. Felsche. "The Crystal Chemistry of the Rare-Earth Silicates"; pp. 99-197 in Structure and Bonding, Vol. 13. Springer-Verlag, Heidelberg, 1973.
10. J. Felsche, "Rare-Earth Silicates With the Apatite Structure," J. Solid State Chem., 5, 266-75 (1972).
11. L. Delorme, "Volatility Mechanisms in Borosilicate Glasses and Melts of Nuclear Interest. Influence of their structure"; Ph.D. Thesis, University of Orléans, France, 1998.
12. R. D. Shannon, "Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides," Acta Crystallogr., A32, 751-67 (1976).
13. 3-CaO Glasses. Part II. Surface and Internal Crystallization Processes Investigated by Differential Thermal Analysis (DTA)." J. Mater. Sci., 38, 853-64 (2003).
14. 2-0.5x System," J. Solid State Chem., 60, 145-58 (1985).
15. L. Li, D. M. Strachan, H. Li, L. L. Davis, and M. Qian, "Crystallization of Gadolinium and Lanthanum-Containing Phases from Sodium Alumino-Borosilicate Glasses," J. Nnn-Cryst. Solids, 272, 46-56 (2000).
16. 5," Izv. Akad. Nauk SSSR. Neorg. Mater., 8 [12] 2180-2 (1972);
17. Inorg. Mater. (Engl. Transl.), 8 [12] 1919-1921 (1972).
18. D. G. Burnell and R. W. Douglas, "Liquid-Liquid Phase Separation in the Soda-Lime-Silica System," Phys. Chem. Glasses, 11 [5] 125-35 (1970).