메뉴 건너뛰기




Volumn 129, Issue 8, 2007, Pages 2246-2247

Electrochemical generation of cationic Pd catalysts and application to Pd/TEMPO double-mediatory electrooxidative Wacker-type reactions

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; CATALYSIS; CATION TRANSPORT; COMPLEX FORMATION; ELECTROCHEMICAL ANALYSIS; LIGAND BINDING; OXIDATION; OXIDATION KINETICS; WACKER TYPE REACTION;

EID: 33847685137     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja069043r     Document Type: Article
Times cited : (69)

References (31)
  • 1
    • 8444236288 scopus 로고    scopus 로고
    • For reviews of recent works, see: a
    • For reviews of recent works, see: (a) Jutand, A. Appl. Organomet. Chem. 2004, 18, 574.
    • (2004) Appl. Organomet. Chem , vol.18 , pp. 574
    • Jutand, A.1
  • 25
    • 33847615449 scopus 로고    scopus 로고
    • 2 was recovered.
    • 2 was recovered.
  • 26
    • 33847622311 scopus 로고    scopus 로고
    • For reviews concerning the Kolbe reaction, see: a, 4th ed, Lund, H, Hammerich, O, Eds, Marcel Dekker, Inc, New York
    • For reviews concerning the Kolbe reaction, see: (a) Torii, S.; Tanaka, H. In Organic Electrochemistry, 4th ed.; Lund, H., Hammerich, O., Eds.; Marcel Dekker, Inc.: New York, 2001; 499-543.
    • (2001) Organic Electrochemistry , pp. 499-543
    • Torii, S.1    Tanaka, H.2
  • 29
    • 33847631483 scopus 로고    scopus 로고
    • Torii and co-workers reported that the isomerized ketones were obtained as by-products from higher molecular weight alkenes in the electrooxidative Wacker-type reactions using (p-Br-C6H4)3N or hydroquinone as a mediator.3b
    • 3b
  • 30
    • 0001529531 scopus 로고    scopus 로고
    • Hayashi and Uozumi reported the high efficiency of cationic Pd, catalysts in a Wacker-type reaction, see
    • Hayashi and Uozumi reported the high efficiency of cationic Pd, catalysts in a Wacker-type reaction, see: Uozumi, Y.; Kato, K.; Hayashi, T. J. Org. Chem. 1998, 63, 5071.
    • (1998) J. Org. Chem , vol.63 , pp. 5071
    • Uozumi, Y.1    Kato, K.2    Hayashi, T.3
  • 31
    • 33847666268 scopus 로고    scopus 로고
    • In the presence of triphenylamine and Bu4NX, the electrooxidation of Pd(OAc)2 gave cationic Pd complex [Pd(CH 3CN)4][X]2. On the other hand, when Pd(OAc)2 was electrooxidized in the presence of TEMPO, the Pd complex bearing TEMPO was also obtained. The complex also might work as an active catalyst for the Wacker-type reaction. While the exact structure has not been clear yet, elemental analyses suggested that the complex might be [Pd(CH 3CN)4tempo, X, The identification of the exact structure is undertaken
    • 4(tempo)][X]. The identification of the exact structure is undertaken.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.