Methane partial oxidation catalyzed by platinum and rhodium in a high-temperature stagnation flow reactor

Industrial and Engineering Chemistry Research

Volumn 46, Issue 4, 2007, Pages 1114-1119

  Rice, Steven F ^a   McDaniel, Anthony H ^a   Hecht, Ethan S ^a   Hardy, Alicia J J ^b  

^a SANDIA NATIONAL LABORATORIES   (United States)

^b Massachusetts Institute of Technology Cambridge   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC SUBSTRATES; PARTIAL OXIDATION; STAGNATION FLOW REACTOR;

CHEMICAL REACTORS; HIGH TEMPERATURE EFFECTS; MASS SPECTROMETRY; OXIDATION; PLATINUM; RHODIUM;

METHANE;

CHEMICAL REACTORS; HIGH TEMPERATURE EFFECTS; MASS SPECTROMETRY; METHANE; OXIDATION; PLATINUM; RHODIUM;

EID: 33847658285     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie060892x     Document Type: Article

References (29)

1. Vernon, P. D. F.; Green, M. L. H.; Cheethan, A. K.; Ashcroft, A. T. Partial Oxidation of Methane to Synthesis Gas. Catal. Lett. 1990, 6, 181.
2. Hickman, D. A.; Schmidt, L. D. Synthesis Gas Formation by Direct Oxidation of Methane over Pt Monoliths. J. Catal. 1992, 138, 267.
3. Hickman, D. A.; Haupfear, E. A.; Schmidt, L. D. Synthesis Gas Formation by Direct Oxidation of Methane over Rh Monoliths. Catal. Lett. 1993, 17, 223.
4. Bharadwaj, S. S.; Schmidt, L. D. Catalytic Partial Oxidation of Natural Gas to Syngas. Fuel Process. Technol. 1995, 42, 109.
5. Veser, G.; Frauhammer, J.; Friedle, U. Syngas Formation by Direct Oxidation of Methane. Reaction Mechanisms and New Reactor Concepts. Cotal. Today 2000, 61, 55.
6. Hohn, K. L.; Schmidt, L. D. Partial Oxidation of Methane to Syngas at High Space Velocities over Rh-Coated Spheres. Appl. Catal., A 2001, 211, 53.
7. Lyubovsky, M.; Roychoudhury, S.; LaPierrre, R. Catalytic Partial Oxidation of Methane to Syngas at Elevated Pressures. Catal. Lett. 2005, 99, 113.
8. Fichtner, M.; Mayer, J.; Wolf, D.; Schubert, K. Microstructured Rhodium Catalysts for the Partial Oxidation of Methane to Syngas under Pressure. Ind. Eng. Chem. Res. 2001, 40, 3475.
9. 2. Transient Studies on Its Mechanism. Catal. Lett. 1994, 29, 249.
10. 2. In Situ DRIFTS Studies on Surface Intermediates. Catal. Lett. 1994, 29, 261.
11. 2. Catal. Lett. 1996, 38, 81.
12. Deutschmann, O.; Behrendt, F.; Warnatz, J. Formal Treatment of Catalytic Combustion and Catalytic Conversion of Methane. Catal. Today 1998, 46, 155.
13. Fathi, M.; Monnet, F.; Schuurman, Y.; Holmen, A.; Mirodatos, C. Reactive Oxygen Species on Platinum Gauzes during Partial Oxidation of Methane into Synthesis Gas. J. Catal. 2000, 190, 439.
14. Veser, G.; Frauhammer, J. Modelling Steady State and Ignition during Catalytic Methane Oxidation in a Monolith Reactor. Chem. Eng. Sci. 2000, 55, 2271.
15. Wolf, M.; Deutschmann, O.; Behrendt, F.; Warnatz, J. Kinetic Model of an Oxygen-Free Methane Conversion on a Platinum Catalyst. Catal. Lett. 1999, 67, 15.
16. Veser, G.; Frauhammer, J.; Schmidt, L. D.; Eigenberger, G. Catalytic Ignition during Methane Oxidation on Platinum: Experiments and Modeling. In Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis; Froment, G. F., Waugh, K. C., Eds.; Studies in Surface Science and Catalysis. Vol. 109; Elsevier: Amsterdam, 1997; pp. 273-284.
17. 4 Oxidation on Pt and Rh Surfaces: High-Temperature Reactor Simulations. AIChE J. 1993, 39, 1164.
18. Aghalayam, P.; Park, Y. K.; Fernandes, N.; Papavassiliou, V.; Mhadeshwar, A. B.; Vlachos, D. G. A C1 Mechanism for Methane Oxidation on Platinum. J. Catal. 2003, 213, 23.
19. Mhadeshwar, A. B.; Vlachos, D. G. Hierarchical Multiscale Mechanism Development for Methane Partial Oxidation and Reforming and for Thermal Decomposition of Oxygenates on Rh. J. Phys. Chem. B 2005, 109, 16819.
20. Taylor, J. D.; Allendorf, M. D.; McDaniel, A. H.; Rice, S. F. In Situ Diagnostics and Modeling of Methane Catalytic Partial Oxidation on Pt in a Stagnation Flow Reactor. Ind. Eng. Chem. Res. 2003, 42, 6559.
21. McDaniel, A. H.; Lutz, A. E.; Allendorf, M. D.; Rice, S. F. Effects of Methane and Ethane on the Heterogeneous Production of Water from Hydrogen and Oxygen over Platinum in Stagnation Flow. J. Catal. 2002, 208, 21.
22. 2 to Pyrolysis over a Platinum Catalyst. React. Kinet. Catal. Lett. 1993, 51, 143.
23. 4 Reforming over Pt Catalysts. J. Catal. 1999, 183, 336.
24. 2. J. Catal. 2001, 197, 34.
25. Sun, Q.; Tang, Y.; Gavalas, G. R. Methane Pyrolysis in a Hot Filament Reactor. Energy Fuels 2000, 14, 490.
26. 3 Catalysts. Appl. Catal., A 2005, 281, 19.
27. 2 Reforming over Supported Platinum Catalysts. Catal. Lett. 2003, 91, 11.
28. Grünert, W.; Wolf, D; Buyevskaya, O. V.; Walter, K.; Baerns, M. Active Surface Sites in the Rhodium-Catalyzed Partial Oxidation of Methane to Syngas. Z. Phys. Chem. 1996, 197, 49.
29. Takeno, T.; Nishioka, M. Species Conservation and Emission Indices for Flames Described by Similarity Solutions. Combust. Flame 1993, 92, 465.