Influence of diluent on radiolysis of amides in organic solution

Radiation Physics and Chemistry

Volumn 76, Issue 5, 2007, Pages 794-800

  Sugo, Yumi ^a   Izumi, Yoshinobu ^b   Yoshida, Yoichi ^b   Nishijima, Shigehiro ^b   Sasaki, Yuji ^a   Kimura, Takaumi ^a   Sekine, Tsutomu ^c   Kudo, Hiroshi ^c  

^a JAPAN ATOMIC ENERGY AGENCY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

^c TOHOKU UNIVERSITY   (Japan)

Author keywords

radiolysis; Charge transfer; Diglycolamide; Malonamide; Monoamide; n dodecane; Pulse radiolysis; Radical cation

Indexed keywords

ACRYLICS; ELECTRON BEAMS; IONIZATION; POSITIVE IONS; RADIOLYSIS; SENSITIVITY ANALYSIS;

DILUENT; RADICAL CATIONS; RADIOLYTIC BEHAVIOR;

POLYAMIDES;

AMIDE; DILUENT; DODECANE; HEXANE; ORGANIC SOLVENT; RADICAL;

ARTICLE; GAMMA RADIATION; IONIZATION; IRRADIATION; MOLECULE; RADIOLYSIS; RADIOSENSITIZATION;

EID: 33847365242     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.radphyschem.2006.05.008     Document Type: Article

References (22)

1. Belevskii V.N., Tyurin D.A., and Chuvylkin N.D. Reactivity of radical cations in the radiolysis of amides: an ESR study and quantum chemical calculation. High Energy Chem. 32 5 (1998) 305-315
2. Berthon L., Morel J.M., Zorz N., Nicol C., Virelizier H., and Madic C. DIAMEX process for minor actinide partitioning: hydrolytic and radiolytic degradations of malonamide extractants. Sep. Sci. Technol. 36 5 and 6 (2001) 709-728
3. Brede O., Mehnert R., and Naumann W. Kinetics of excitation and charge transfer reactions in non-polar media. Chem. Phys. 115 (1987) 279-296
4. Cuillerdier C., Musikas C., Hoel P., Nigond L., and Vitart X. Malonamides as new extractants for nuclear waste solutions. Sep. Sci. Technol. 26 9 (1991) 1229-1244
5. Dewar M.J.S., Zoebisch E.G., Healy E.F., and Stewart J.J.P. AM1: a new general purpose quantum mechanical model. J. Am. Chem. Soc. 107 (1985) 3902-3909
6. Gasparini G.M., and Grossi G. Long chain disubstituted aliphatic amides as extracting agents in industrial applications of solvent extraction. Solvent Extract. Ion Exchange 4 6 (1986) 1233-1271
7. Katsumura Y., Yoshida Y., Tagawa S., and Tabata Y. Study on the excited state of liquid alkanes and energy transfer process by means of picosecond pulse. Radiat. Phys. Chem. 21 (1983) 103-111
8. Lias S.G., Bartmess J.E., Liebman J.F., Holmes J.L., Levin R.D., and Mallard W.G. Gas-phase ion and neutral thermochemistry. J. Phys. Chem. Ref. Data 17 S1 (1988) 1-872
9. Mincher B.J., and Curry R.D. Considerations for choice of a kinetic fig. of merit in process radiation chemistry for waste treatment. Appl. Radiat. Isot. 52 (2000) 189-193
10. Mincher B.J., Brey R.R., Rodriguez R.G., Pristupa S., and Ruhter A. Increasing PCB radiolysis rates in transformer oil. Radiat. Phys. Chem. 65 (2002) 461-465
11. Musikas C. Potentiality of nonorganophosphorus extractants in chemical separations of actinides. Sep. Sci. Technol. 23 12 and 13 (1988) 1211-1226
12. Saeki A., Kozawa T., Yoshida Y., and Tagawa S. Study on geminate ion recombination in liquid dodecane using pico- and subpicosecond pulse radiolysis. Radiat. Phys. Chem. 60 4-5 (2001) 319-322
13. 3-n-dodecane system. Solvent Extract. Ion Exchange 19 1 (2001) 91-103
14. Sasaki, Y., Suzuki, S., Tachimori, S., Kimura, T., 2003. An innovative chemical separation process (ARTIST) for treatment of spent nuclear fuel. In: Proceedings of the International Conference Global 2003, New Orleans, USA, pp. 1266.
15. In: Spinks J.W.T., and Woods R.J. (Eds). An Introduction to Radiation Chemistry. third ed. (1990), Wiley-Interscience, USA
16. Sugo Y., Sasaki Y., and Tachimori S. Studies on hydrolysis and radiolysis of N,N,N′,N′-tetraoctyl-3-oxapentane-1,5-diamide. Radiochim. Acta 90 (2002) 161-165
17. Tabuse S., Izumi Y., Kojima T., Yoshida Y., Kozawa T., Miki M., and Tagawa S. Radiation protection effects by addition of aromatic compounds to n-dodecane. Radiat. Phys. Chem. 62 1 (2001) 179-187
18. Tagawa S., Hayashi N., Yoshida Y., Washio M., and Tabata Y. Pulse radiolysis studies on liquid alkanes and related polymers. Radiat. Phys. Chem. 34 4 (1989) 503-511
19. Thiollet G., and Musikas C. Synthesis and uses of the amides extractants. Solvent Extract. Ion Exchange 7 5 (1989) 813-827
20. Tran-Thi T.H., Koulkes-Pujo A.M., Sutton J., and Anitoff O. Pulse radiolysis of amides and their aqueous organic mixtures. Radiat. Phys. Chem. 23 1-2 (1984) 77-87
21. Yoshida Y., and Tagawa S. Dynamics of geminate ion pairs in liquid alkanes studied by LL-twin picosecond pulse radiolysis. In: Mataga N., Okada T., and Masuhara H. (Eds). Dynamics and Mechanisms of Photoinduced Transfer and Related Phenomena (1992), Elsevier, Amsterdam 435-442
22. Yoshida Y., Ueda T., Kobayashi T., Shibata H., and Tagawa S. Studies of geminate ion recombination and formation of excited states in liquid n-dodecane by means of a new picosecond pulse radiolysis system. Nucl. Instrum. Methods A 327 1 (1993) 41-43