Cathode of a fuel cell with a solid polymer electrolyte: Calculating overall currents in the presence of a gas-diffusion layer

Russian Journal of Electrochemistry

Volumn 43, Issue 1, 2007, Pages 25-33

  Chirkov, Yu G ^a   Rostokin, V I ^b  

^a FRUMKIN INSTITUTE OF PHYSICAL CHEMISTRY AND ELECTROCHEMISTRY   (Russian Federation)

^b NATIONAL RESEARCH NUCLEAR UNIVERSITY MEPHI   (Russian Federation)

Author keywords

Cathode; Current voltage curves; Darcy law; Effective diffusion coefficient; Fuel cell with a solid polymer electrolyte; Gas penetrability; Gas diffusion layer; Limiting overall currents; Stephanian flows

Indexed keywords

CATHODES; CURRENT VOLTAGE CHARACTERISTICS; DIFFUSION; ELECTRIC CURRENTS; ELECTROLYTES; PARTIAL PRESSURE;

DARCY LAW; EFFECTIVE DIFFUSION COEFFICIENT; GAS PENETRABILITY; GAS-DIFFUSION LAYERS; LIMITING OVERALL CURRENTS; STEPHANIAN FLOWS;

FUEL CELLS;

EID: 33847195806     PISSN: 10231935     EISSN: 16083342     Source Type: Journal    
DOI: 10.1134/S1023193507010041     Document Type: Article

References (26)

1. Weber, A.Z. and Newman, J., Chem. Rev., 2004, vol. 104, p. 4679.
2. Wilson, M.S., DeCaro, D., Zawodzinski, T., and Gottesfeld, S., 192nd Meet. Electrochem. Soc., 1997, vol. 97-2, p. 72.
3. Jordan, L.R., Shukla, A.K., Behrsing, T., Avery, N.R., Muddle, B.C., and Forsyth, M., J. Appl. Electrochem., 2000, vol. 30, p. 641.
4. Kong, C.S., Kirn, D.-Y., Lee, H.-K., Shul, Y.-G., and Lee, T., J. Power Sources, 2002, vol. 108, p. 185.
5. Wilson, M.S., Valeria, J.A., and Gottesfeld, S., Electrochim. Acta, 1995, vol. 40, p. 355.
6. Kara, N., Tsurumi, K., and Watanabe, M., J. Electroanal. Chem., 1996, vol.413, p. 81.
7. Janssen, G.J.M. and Overvelde, M.L.J., J. Power Sources, 2001, vol. 101, p. 117.
8. Paganin, V.A., Ticianelli, R.A., and Gonzalez, E.R., J. Appl. Electrochem., 1996, vol. 26, p. 297.
9. Passalacqua, E., Lufrano, F., Squadrito, G., Patti, A., and Giorgi, L., Electrochim. Acta, 1998, vol. 43, p. 3665.
10. Lufrano, F., Passalacqua, E., Squadrito, G., Patti, A., and Giorgi, L., J. Appl. Electrochem., 1999, vol. 29, p. 445.
11. Qi, Z.G. and Kaufman, A., J. Power Sources, 2002, vol. 109, p. 38.
12. Weber, A.Z. and Newman, J., J. Electrochem. Soc., 2005, vol. 152, p. A677.
13. Chirkov, Yu.G. and Rostokin, V.I., Elektrokhimiya, 2004, vol. 40, p. 1036.
14. Chirkov, Yu.G. and Rostokin, V.I., Elektrokhimiya, 2005, vol. 41, p. 1109.
15. Kim, J., Lee, S., Srinivasan, S., and Chamberlin, C.E., J. Electrochem. Soc., 1995, vol. 142, p. 2670.
16. Stephan, J., Ann. Phys., (New York), 1882, vol. 17, p. 550; 1890, vol. 41, p. 725.
17. Frank-Kamenetskii, D.A., Diffuziya i teploperedacha v khimicheskoi kinetike (Diffusion and Heat Transfer in the Chemical Kinetics), Moscow: Nauka, 1987.
18. Kheifets, L.I. and Neimark, A.V., Mnogofaznye protsessy v poristykh sredakh (The Multiphase Processes in Porous Media), Moscow: Khimiya, 1982.
19. Mulder, M., Basic Principles of Membrane Technology, Dordrecht: Kluwer, 1996.
20. Landau, L.D. and Lifshits, E.M., Mekhanika sploshnykh sred (Continuum Mechanics), Gostekhizdat, 1954.
21. Chizmadzhev, Yu.A., Markin, V.S., Tarasevich, M.R., and Chirkov, Yu.T., Makrokinetika protsessov v poristykh sredakh (The Macrokinetics of Processes in Porous Media), Moscow: Nauka, 1971.
22. Korovin, N.V., Kicheev, A.G., and Luzhin V.K, Elektrokhimiya, 1972, vol. 8, p. 146.
23. Fizicheskii entsiklopedicheskii slovar' (Encyclopedic Dictionary of Physics), Moscow: Sovetskaya Entsiklopediya, 1960, vol. 1.
24. Mukerjee, S. and Srinivasan, S., J. Electroanal. Chem., 1993, vol. 357, p. 201.
25. Springer, T.E., Wilson, M.S., and Gottsfeld, S., J. Electrochem. Soc., 1993, vol. 140, p. 3513.
26. Wakizoe, M., Velev, O.A., and Srinivasan, S., Electrochim. Acta, 1995, vol. 40, p. 335.