Relationship among thermal ageing degradation, dynamic properties, cure systems, and antioxidants in natural rubber vulcanisates

Polymer - Plastics Technology and Engineering

Volumn 46, Issue 2, 2007, Pages 113-121

  Pimolsiriphol, Vorapong ^a   Saeoui, Pongdhorn ^b   Sirisinha, Chakrit ^a  

^a Mahidol University   (Thailand)

^b NATIONAL METAL AND MATERIALS TECHNOLOGY CENTER   (Thailand)

Author keywords

Ageing; Cross link density; Dynamic mechanical properties; Natural rubber; Tensile properties

Indexed keywords

CROSSLINKING; CURING; DYNAMIC MECHANICAL ANALYSIS; PYROLYSIS; TENSILE STRENGTH; THERMAL AGING;

CROSS-LINK DENSITY; THERMAL AGEING STABILITY;

RUBBER;

CROSSLINKING; CURING; DYNAMIC MECHANICAL ANALYSIS; PYROLYSIS; RUBBER; TENSILE STRENGTH; THERMAL AGING;

AGING; ANTIOXIDANT; DEGRADATION; MECHANICAL PROPERTY; NATURAL RUBBER; TENSILE PROPERTY;

EID: 33847144472     PISSN: 03602559     EISSN: 15256111     Source Type: Journal    
DOI: 10.1080/03602550601152861     Document Type: Article

References (20)

1. Fan, R. L., Zhang, Y., Huang, C., Zhang, Y. X., Sun, K. and Fan, Y. Z. (2001) Effect of high-temperature curing on the crosslink structures dynamic mechanical properties of gum and N330-filled natural rubber vulcanizates. Polym. Test., 20, p. 925.
2. Berry, J. P. and Watson, W. F. (1995) Stress relaxation of peroxide and sulfur vulcanizates of natural rubber. J. Polym. Sci., 18, p. 201.
3. Cunneen, J. L. (1968) Rubb. Oxidative aging of natural rubber. Chem. Technol., 41, p. 182.
4. Morand, J. L. (1977) Rubb. Chain scission in the oxidation of polyisoprene. Chem. Technol., 50, p. 370.
5. Keller, R. W. (1985) Oxidation and ozonation of rubber. Rubb. Chem. Technol., 58, p. 637.
6. Hess, W., Herd, C. and Vegari, P. (1993) Characterization of immiscible elastomer, Rubb. Chem. Technol., 66, p. 329.
7. Kern, W. J. and Futamura, S. (1988) Effect of tread polymer structure on tire performance. Polymer., 29, p. 1081.
8. Trexler, H. E. and Lee, M. C. (1986) Effect of types of carbon black and cure conditions on dynamic mechanical properties of elastomers. J. Appl. Polym. Sci., 32, p. 3899.
9. Wang, M. J. (1998) Rubb. Effect of polymer-filler and filler-filler interactions on dynamic properties of filled vulcanizates. Chem. Technol., 71, p. 520.
10. Medalia, A. I. (1978) Rubb. Effect of carbon black on dynamic properties of rubber vulcanizates. Chem. Technol., 51, p. 437.
11. Pattanawanidchai, S., Sae-oui, P. and Sirisinha, C. (2005) Influence of precipitated silica on dynamic mechanical properties and resistance to oil and thermal ageing in CPE/NR blends. J. Appl. Polym. Sci., 96, p. 2218.
12. Dick, J. S. and Pawlowski, H. (1995) Alternate instrumental methods of measuring scorch and cure characteristics. Polym. Test., 14, p. 45.
13. Blackman, E. J. and Mccall, E. B. (1970) Relations between the structures of natural rubber vulcanizates and their thermal and oxidative aging. Rubb. Chem. Technol., 43, p. 651.
14. Heiner, J., Stenberg, B. and Persson, M. (2003) Crosslinking of siloxane elastomers. Polym. Test., 22, p. 253.
15. Sirisinha, C. and Sittichokchuchai, W. J. (2001) Influence of some additives on state-of-mix, rheological, tensile, and dynamic mechanical properties in SBR compounds. Appl. Polym. Sci., 80, p. 2474.
16. Medalia, A.I. Rubb (1991) Heat generation in elastomer compounds: Causes and effects. Chem. Technol., 64, p. 481.
17. Hess, W. and Klamp, W. (1983) The effects of carbon black and othyer compounding variables on the tire rolling resistance and traction. Rubb. Chem. Technol., 56, p. 390.
18. Meinecke, E. Rubb (1990) Effect of carbon black loading and crosslink density on the heat build-up in elastomers. Chem. Technol., 64, p. 269.
19. (1978) Rubber Chemistry, Applied Science Publishers, London
20. Pushpa, S. A. and Goonetilleke, P. (1995) Rubb. Diffusion of antioxidants in rubber. Chem. Technol., 68, p. 705.