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For a comprehensive review of the synthesis and properties of organo sulfur derivatives of the group 4 atoms see
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For a comprehensive review of the synthesis and properties of organo sulfur derivatives of the group 4 atoms see; E. W. Abel and D. A. Armitage, Adv. Organomet. Chem., 5, 2 (1967).
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There is a disappointing lack of accurate bond energy data available for silicon derivatives cf. Part 1, A. G. MacDiarmid, Ed., Marcel Dekker, New York, N.Y., Chapter 1. Equilibration studies have suggested that the Si-S and C-S bond energies are comparable; M. Schmeisser and H. Muller, 69, (1957)
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There is a disappointing lack of accurate bond energy data available for silicon derivatives : cf. E. A. V. Ebsworth in “Organometallic Compounds of the Group IV Elements”;, Vol. 1, Part 1, A. G. MacDiarmid, Ed., Marcel Dekker, New York, N.Y., 1968, Chapter 1. Equilibration studies have suggested that the Si-S and C-S bond energies are comparable; M. Schmeisser and H. Muller, Angew. Chem., 69, 781 (1957).
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For a brief description of related reversed polarity equivalents see:
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For a brief description of related reversed polarity equivalents see : D. A. Evans and G. C. Andrews, Acc. Chem. Res., 7, 5 (1974);
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Hurst, unpublished observations
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The formation and synthetic utility of phosphonium salts will be published In due course.
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D. A. Evans and K. M. Hurst, unpublished observations. The formation and synthetic utility of phosphonium salts will be published In due course.
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Evans, D.A.1
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33847805314
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For a convenient synthesis of
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For a convenient synthesis of 18-crown-6 see : G. W. Gokel, D. J. Cram, C. L. Liotta, H. P. Harris, and F. L. Cook, J. Org. Chem., 39, 2445 (1974).
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J. W. Ralls and B. Riegel, J. Am. Chem. Soc., 76, 4479 (1954). For a recent highly regioselective thioketalization of 50 see J. R. Williams and G. M. Sarkisian, Synthesis, 32 (1974).
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For recent innovations in the design of ketals which may be removed under nonacidic conditions see :
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For recent innovations in the design of ketals which may be removed under nonacidic conditions see : E. J. Corey and J. W. Suggs, Tetrahedron Lett., 3775 (1975);
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Professor Glass has kindly informed us that these thermal and imidazole-catalyzed thiosilane carbonyl insertion reactions do not appear to be general for ketonic substrates.
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R. S. Glass, Synth. Commun., 6, 47 (1976). Professor Glass has kindly informed us that these thermal and imidazole-catalyzed thiosilane carbonyl insertion reactions do not appear to be general for ketonic substrates.
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