Synthesis and Crystal Structure of Diphenylcarbene(pentacarbonyl)tungsten(0)

Journal of the American Chemical Society

Volumn 99, Issue 7, 1977, Pages 2127-2134

  Casey, Charles P ^a   Burkhardt, Terry J ^a   Bunnell, Charles A ^a   Calabrese, Joseph C ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33847088717     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00449a018     Document Type: Article

References (63)

1. For recent reviews of transition metal-carbene complexes see D. J. Cardin, B. Cetinkaya, and M. F. Lappert, Chem. Rev., 72, 575 (1972);
2. F. A. Cotton and C. M. Lukehart, Prog. Inorg. Chem., 16, 243 (1972).
3. O. S. Mills and A. D. Redhouse, J. Chem. Soc. A, 642 (1968);
4. J. A. Connor and O. S. Mills, J. Chem. Soc. A, 334 (1969).
5. E. O. Fischer and E. Moser, J. Organomet. Chem., 13, 387 (1968);
6. E. O. Fischer and C. G. Kreiter, Angew. Chem., Int. Ed. Engl., 8, 761 (1969).
7. E. O. Fischer, B. Heckl, K. H. D. ötz, H. Müller, and H. Werner, J. Organomet. Chem., 16, P29 (1969);
8. E. O. Fischer and D. Plabst, Chem. Ber., 107, 3326 (1974).
9. C. P. Casey and R. L. Anderson, J. Chem. Soc., Chem. Commun., 895 (1975).
10. K. H. Dötz and E. O. Fischer, Chem. Ber., 105, 1356, 3966 (1972).
11. A preliminary communication has appeared. C. P. Casey and T. J. Burkhardt, J. Am. Chem. Soc., 95, 5833 (1973).
12. K. öfele, Angew. Chem., Int. Ed. Engl., 7, 950 (1968);
13. J. Organomet. Chem., 22, C9 (1970).
14. A. Sanders, L. Cohen, W. P. Giering, D. Kenedy, and C. V. Magatti, J. Am. Chem. Soc., 95, 5430 (1973).
15. R. R. Schrock, J. Am. Chem. Soc., 96, 6796 (1974);
16. J. Am. Chem. Soc., 97, 6577 (1975);
17. R. R. Schrock and L. J. Guggenberger, J. Am. Chem. soc., 97, 6578 (1975).
18. W. A. Hermann, Angew. Chem., Int. Ed. Engl., 13, 599 (1974).
19. W. A. Hermann, Chem. Ber., 108, 486 (1975).
20. E. O. Fischer, W. Held, S. Riedmüller, and F. Köhler, unpublished results, referred to by E. O. Fischer, Angew. Chem., 86, 651 (1974).
21. C. P. Casey and T. J. Burkhardt, J. Am. Chem. Soc., 96, 7808 (1974).
22. C. P. Casey, H. E. Tuinstra, and M. C. Saeman, J. Am. Chem. Soc., 98, 608 (1976).
23. J. McGinnis, T. J. Katz, and S. Hurwltz, J. Am. Chem. Soc., 98, 605 (1976).
24. T. J. Katz, J. McGinnis, and C. Altus, J. Am. Chem. Soc., 98, 606 (1976).
25. U. Klabunde and E. O. Fischer, J. Am. Chem. Soc., 89, 7141 (1967);
26. J. A. Connor and E. O. Fischer, Chem. Commun., 1024 (1967);
27. E. O. Fischer, M. Leupold, C. G. Kreiter, and J. Muller, Chem. Ber., 105, 150 (1972).
28. U. Schubert and E. O. Fischer, Justus Liebigs Ann. Chem., 393 (1975).
29. H. Werner, E. O. Fischer, B. Heckl, and C. G. Kreiter, J. Organomet. Chem., 28, 367 (1971).
30. F. R. Kreissl, E. 0. Fischer, C. G. Kreiter, and K. Weiss, Angew. Chem., Int. Ed. Engl., 12, 563 (1973);
31. F. R. Kreissl, E. O. Fischer, C. G. Kreiter, and H. Fischer, Chem. Ber., 106, 1262 (1973).
32. T. F. Block, R. F. Fenske, and C. P. Casey, J. Am. Chem. Soc., 98, 441 (1976).
33. E. O. Fischer and S. Riedmüller, unpublished results referred to by E. O. Fischer, Pure Appl. Chem., 30, 353 (1972).
34. C. T. Lam, C. V. Senoff, and J. E. H. Ward, J. Organomet. Chem., 70, 273 (1974).
35. P. W. Jolly and R. Pettit, J. Am. Chem. Soc., 88, 5044 (1966).
36. F. A. Cotton and C. S. Kraihanzel, J. Am. Chem. Soc., 84, 4432 (1962).
37. C. P. Casey, S. W. Polichnowski, and R. L. Anderson, J. Am. Chem. Soc., 97, 7375 (1975).
38. A. Danti, F. A. Cotton, J. Chem. Phys., 28, 736 (1958).
39. The 13C spectrum of 1 has been reported. F. R. Kreissl and W. Held, J. Organomet. Chem., 86, C10 (1975).
40. J. Evans and J. R. Norton, Inorg. Chem., 13, 3042 (1974).
41. G. A. Olah and A. M. White, J. Am. Chem. Soc., 91, 5801 (1969).
42. G. M. Bodner, S. B. Kahl, K. Bork, B. N. Storhoff, J. E. Wuller, and L. J. Todd, Inorg. Chem., 12, 1071 (1973).
43. C. G. Kreiter and V. Formacek, Angew. Chem., Int. Ed. Engl., 11, 141 (1972).
44. J. Müller and J. A. Connor, Chem. Ber., 102, 1148 (1969).
45. E. O. Fischer and A. Massböl, Chem. Ber., 100, 2445 (1967).
46. C. P. Casey, R. A. Boggs, and R. L. Anderson, J. Am. Chem. Soc., 94, 8947 (1972).
47. C. P. Casey, R. A. Boggs, W. R. Brunsvold, unpublished results.
48. E. O. Fischer and S. Reidmüller, Chem. Ber., 107, 915 (1974).
49. C. P. Casey and T. J. Burkhardt, J. Am. Chem. Soc., 94, 6543 (1972).
50. E. O. Fischer and H. Fischer, Chem. Ber., 107, 657 (1974).
51. R. J. Hoare and O. S. Mills, J. Chem. Soc., Dalton Trans., 653 (1972). and references therein.
52. C. P. Casey, S. W. Polichnowski, L. D. Albin, and J. C. Calabrese, unpublished results.
53. E. O. Fischer, G. Kreis, C. G. Kreiter, J. Müller, G. Huttner, and H. Lorenz, Angew. Chem., Int. Ed. Engl., 12, 564 (1973).
54. S. P. Arnesen and H. M. Seip, Acta Chem. Scand., 20, 2711 (1966), and references therein.
55. A. H. Gomes de Mesquita, C. H. MacGillavry, and K. Eriks, Acta Crystallogr., 18, 437 (1965).
56. F. H. Allen and S. Converse, “Organic Syntheses”, Collect. Vol. I, Wiley, New York, N.Y., 1941, p 226.
57. L. Horner and E. Lingnau, Justus Liebigs Ann. Chem., 591, 135 (1955).
58. O. A. Gansow, A. R. Burke, and G. N. LaMar, J. Chem. Soc., Chem. Commun., 456 (1972).
59. Programs used in the structure solution were written by J. C. Calabrese. In addition dear, the J. F. Blount absorption correction program; orfls and orfee, the Busing, Martin, Levy least-squares and error analysis program; ortep, the Johnson thermal ellipsoid plotting program were used.
60. T. H. Whitesides, R. W., Slaven, and J. C. Calabrese, Inorg. Chem., 13, 1895 (1974).
61. “International Tables for X-Ray Crystallography,” Vol. I, 2nd ed, The Kynoch Press, Birmingham, England, 1965, p 99.
62. J. D. Lea, and S. Skillman, Acta Crystallogr., 17, 1040 (1964);
63. those for the hydrogen atoms are from R. F. Stewart, E. R. Davidson, and W. T. Simpson, J. Chem. Phys., 42, 3175 (1965).