Phenyl Participation in the Cleavage of β-Phenethyl-Palladium Bonds by Cupric Chloride

Journal of the American Chemical Society

Volumn 102, Issue 1, 1980, Pages 393-395

  Bäckvall, Jan E ^a   Nordberg, Ruth E ^a  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33847087486     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00521a075     Document Type: Letter

References (40)

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31. Prepared from the Grignard reagent of 8 and mercuric chloride. The deuterated chloride 8 was prepared by reaction of 1,1-dideuterio-2-phenethyl alcohol with thionyl chloride. The alcohol was prepared by a known procedure: W. H. Saunders, S. Asperger, and D. H. Edison, J. Am. Chem. Soc., 80, 2421 (1958).
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35. NMR analysis indicated a ratio of PhCH(OAc)CHD2 to PhCD(OAc)CH2D of 1:1.9, which reflects the isotope effect in the /3-eliminatlon.
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