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This equivalence between peroxo connpiexes resulting from O2 or from H2O2 has been best iliustrateid by Sharpiess et al., who obtained the formaiiy equivalent oxazlridino structure either from the reaction of W-phenylhy-droxylamlne with c/s-dioxobis(N,N-dlethyldithiocarbamato)molybdenum(Vl) or from the interaction of nitrosobenzene with oxobis(W,W-diethyldithio-carbamato)molybdenum(IV): L. S. Liebeskind, K. B. Sharpiess, R. D. Wilson, and J. A. ibers, J. Am. Chem. Soc., 100, 7061 (1978).
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H. Mimoun and R. Charpentier, French Patent 7 900 828 (1979). Palladium dithiolate complexes have been claimed to be active catalysts in the oxidation of terminal olefins to methyl ketones by alkyl hydroperoxides: P. G. S. Field and D. A. Lock, U.S. Patent 3 891 711 (1975).
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Currently used following an original design of W. Fetter, E.T.H., Zurich, private communication.
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private communication.
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