Modeling the composition of the pore water in a clay-rock geological formation (Callovo-Oxfordian, France)

Geochimica et Cosmochimica Acta

Volumn 71, Issue 5, 2007, Pages 1087-1097

  Leroy, P ^a,b   Revil, A ^a   Altmann, S ^b   Tournassat, C ^c  

^a CNRS   (France)

^b ANDRA   (France)

^c BRGM   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; ARGILLITE; CALLOVIAN; DENSITY; GEOCHEMISTRY; IONIC COMPOSITION; OXFORDIAN; POREWATER; POROSITY;

EURASIA; EUROPE; FRANCE; WESTERN EUROPE;

EID: 33846939820     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2006.11.009     Document Type: Article

References (34)

1. ANDRA, 2005. Dossier 2005 argile-Référentiel du site de Meuse/Haute Marne, Internal Report ANDRA n°C.RP.ADS.04.0022.
2. 2) ant its application to a column experiment. Geochim. Cosmochim. Acta 63 (1999) 3039-3048
3. Avena M.J., and De Pauli C.P. Modeling the interfacial properties of an amorphous aluminosilicate dispersed in aqueous NaCl solutions. Colloids Surf. 118 (1996) 75-87
4. Avena M.J., and De Pauli C.P. Proton adsorption and electrokinetics of an Argentinean montmorillonite. J. Colloid Interface Sci. 202 (1998) 195-204
5. Beaucaire C., Pitsch H., Toulhoat P., Motellier S., and Louvat D. Regional fluid characterization and modelling of water rock equilibria in the Boom clay formation and in the Rupelian aquifer at Mol, Belgium. Appl. Geochem. 15 (2000) 667-686
6. Bourg I.C., Bourg A.C.M., and Sposito G. Modeling diffusion and adsorption in compacted bentonite: a critical review. J. Contam. Hydrol. 61 (2003) 293-302
7. Bradbury M.H., and Baeyens B. A physicochemical characterisation and geochemical modeling approach for determining porewater chemistries in argillaceous rock. Geochim. Cosmochim. Acta 62 5 (1998) 783-795
8. Caceci M., and Cacheris W.P. Fitting curves to data. The simplex algorithm is the answer. Byte 9 (1984) 340-362
9. Gaines G.L., and Thomas H.C. Adsorption studies on clay minerals, II.A formulation of the thermodynamics of exchange adsorption. J. Chem. Phys. 21 (1953) 714-718
10. Gaucher E., Robelin C., Matray J.M., Negrel G., Gros Y., Heitz J.F., Vinsot A., Rebours H., Cassabagnere A., and Bouchet A. ANDRA underground research laboratory: interpretation of the mineralogical and geochemical data acquired in the Callovo-Oxfordian Formation by investigative drilling. Phys. Chem. Earth 29 (2004) 55-77
11. Gaucher E., Blanc P., Barot F., Braibant G., Buschaert S., Crouzet C., Gautier A., Girard J.P., Jacquot E., Lassin A., Negrel G., Tournassat C., Vinsot A., and Altmann S. Modeling the porewater chemistry of the Callovo-Oxfordian formation at a regional scale. Compte Rendus Géosciences 338 12-13 (2006) 917-930
12. Gonçalves J., Violette S., and Wendling J. Analytical and numerical solutions for alternative overpressuring processes: application to the Callovo-Oxfordian sedimentary sequence in the Paris Basin, France. J. Geophys. Res. 109 (2004) B02110 10.1029/2002JB002278
13. Gutierrez M., and Fuentes H.R. A mechanistic modeling of montmorillonite contamination by cesium sorption. Appl. Clay Sci. 11 1 (1996) 11-24
14. Hunter R.J. Zeta Potential in Colloid Science: Principles and Applications (1981), Academic Press, New York
15. Kitamura A., Fujiwara K., Yamamoto T., Nishikawa S., and Moriyama H. Mechanism of Adsorption of cations onto quartz. J. Nucl. Sci. Technol. 36 (1999) 1167-1175
16. Leroy P., and Revil A. A triple-layer model of the surface electrochemical properties of clay minerals. J. Colloid Interface Sci. 270 2 (2004) 371-380
17. Leroy P., Revil A., and Coelho D. Diffusion of ionic species in bentonite. J. Colloid Interface Sci. 296 1 (2006) 248-255
18. Loret B., Gajo A., and Simões F.M.F. A note on the dissipation due to generalized diffusion with electro-chemo-mechanical couplings in heteroionic clays. Eur. J. Mech. A/Solid 23 (2004) 763-782
19. Ochs M., Lothenbach B., Wanner H., Sato H., and Yui M. An integrated sorption-diffusion model for the calculation of consistent distribution and diffusion coefficients in compacted bentonite. J. Contam. Hydrol. 47 (2001) 281-296
20. Ochs M., Lothenbach B., Shibata M., and Yui M. Thermodynamic modeling and sensitivity analysis of porewater chemistry in compacted bentonite. Phys. Chem. Earth 29 (2004) 129-136
21. Parkhurst, D.L., Appelo, C.A.J., 1999. User's guide to phreeqc-a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations, U.S. Geological Survey, Report-99-4259.
22. Perrier F., and Froidefond T. Electrical conductivity and streaming potential coefficient in a moderately alkaline lava series. Earth Planet. Sci. Lett. 210 1-2 (2003) 351-363
23. Persello J. In: Delgado A.V. (Ed). Interfacial Electrokinetics and Electrophoresis. Surf. Sci. Ser. vol. 106 (2002), Dekker, New York 297
24. Revil A., Cathles L.M., Losh S., and Nunn J.A. Electrical conductivity in shaly sands with geophysical applications. J. Geophys. Res. 103 B10 (1998) 23925-23936
25. Revil A., Schwaeger H., Cathles L.M., and Manhardt P. Streaming potential in porous media. 2. Theory and application to geothermal systems. J. Geophys. Res. 104 B9 (1999) 20033-20048
26. Revil A., and Leroy P. Hydroelectric coupling in a clayey material. Geophys. Res. Lett. 28 8 (2001) 1643-1646
27. Revil A., Hermitte D., Spangenberg E., and Cochémé J.J. Electrical properties of zeolitized volcaniclastic materials. J. Geophys. Res. 107 B8 (2002) 2168 10.1029/2001JB000599
28. Revil A., Leroy P., and Titov K. Characterization of transport properties of argillaceous sediments. Application to the Callovo-Oxfordian Argillite. J. Geophys. Res. 110 (2005) B06202 10.1029/2004JB003442
29. Revil A., and Linde N. Chemico-electromechanical coupling in microporous media. J. Colloid Interface Sci. 302 (2006) 682-694
30. Rosanne M., Mammar N., Koudina N., Prunet-Foch B., Thovert J.-F., Tevissen E., and Adler P.M. Transport properties of compact clays II. Diffusion. J. Colloid Interface Sci. 260 (2003) 195-203
31. Sacchi, E., Michelot, J.-L., Pitsch, H., 2000. Porewater Extraction from Argillaceous Rocks for Geochemical Characterization. Methods and Interpretation. Report 66 2000 02. OECD/NEA.
32. Sammartino S., Bouchet A., Prêt D., Parneix J.-C., and Tevissen E. Spatial distribution of porosity and minerals in clay rocks from the Callovo-Oxfordian formation (Meuse/Haute-Marne, Eastern France)-implications on ionic species diffusion and rock sorption capability. Appl. Clay Sci. 23 (2003) 157-166
33. Sondi I., Biscan J., and Pravdic V. Electrokinetics of pure clay minerals revisited. J. Colloid Interface Sci. 178 (1996) 514-522
34. Tournassat C., Ferrage E., Poinsignon C., and Charlet L. The titration of clay minerals. Part II. Structural-based model and implications for clay reactivity. J. Colloid Interface Sci. 273 (2004) 234-246