Highly stereoselective bioreduction and one-way isomerization of 2-alkyl-4,4,4-trichloro-2-butenals

Tetrahedron Letters

Volumn 48, Issue 11, 2007, Pages 1895-1898

  Li, Ning ^a   Zhang, Fanglin ^a   Gong, Yuefa ^a  

^a HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

4,4,4 Trichloro 2 butenal; Baker's yeast; Bioreduction; One way isomerization

Indexed keywords

2 ALKYL 4,4,4 TRICHLORO 2 BUTENAL; ALDEHYDE DERIVATIVE; BUTANE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; ENANTIOSELECTIVITY; INFRARED SPECTROMETRY; ISOMER; ISOMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REDUCTION KINETICS; SACCHAROMYCES CEREVISIAE; STEREOCHEMISTRY; STRUCTURE ANALYSIS;

SACCHAROMYCES CEREVISIAE;

EID: 33846899688     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.01.115     Document Type: Article

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15. 2 = 3.8 Hz, 1H), 1.61-1.65 (m, 1H), 1.19 (d, J = 6.8 Hz, 3H).
16. 3): δ 5.93 (s, 1H), 3.73 (d, J = 11.2 Hz, 1H), 3.55 (d, J = 11.2 Hz, 1H), 1.44 (s, 3H).
17. 2 = 4.8 Hz, 1H), 1.71-1.74 (m, 1H), 1.61-1.65 (m, 2H), 1.03 (t, J = 7.2 Hz, 3H).
18. 3): δ 129.44, 122.76, 80.95, 63.34, 25.67, 7.80.
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