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3a: Yield: 72.3, 1H NMR (400 MHz, DMSO-d6, δ ppm, 11.35 (s, 1H, NH, 9.37 (s, 1H, NH, 6.89-8.16 (m, 8H, Ar-H, IR (KBr, ν cm-1, 3377, 3207 (N-H, 1722 (C=O, 1329, 1163 (CF 3, Anal. Calcd. for C16H10F4N 4OS: C 50.26, H 2.64, N 14.65; found: C 50.41, H 2.82, N 14.76. 3b: Yield: 75.6, 1H NMR (400 MHz, DMSO-d6, δ ppm, 11.29 (s, 1H, NH, 9.17 (s, 1H, NH, 7.16-8.15 (m, 8H, Ar-H, IR (KBr, ν cm-1, 3382, 3208 (N-H, 1725 (C=O, 1334, 1159 (CF 3, Anal. Calcd. for C16H10F4N 4OS: C 50.26, H 2.64, N 14.65; found: C 50.35, H 2.43, N 14.50. 3c: Yield: 68.5, 1H NMR (400 MHz, DMSO-d6, δ ppm, 11.83 (s, 1H, NH, 8.83 (s, 1H, NH, 7.13-8.14 (m, 8H, Ar-H, IR (KBr, ν cm-1, 3360, 3186, 2852, 1711 (C=O, 1332, 1164 CF 3, Anal. C
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4OS: C 53.96, H 3.46, N 14.81; found: C 53.79, H 3.61, N 14.96.
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