Oxidation of methane at the CH4/H2O-(CO2) transition zone in the external part of the Central Alps, Switzerland: Evidence from stable isotope investigations

Chemical Geology

Volumn 237, Issue 3-4, 2007, Pages 329-357

  Tarantola, Alexandre ^a,b   Mullis, Josef ^a   Vennemann, Torsten ^c   Dubessy, Jean ^b   de Capitani, Christian ^a  

^a UNIVERSITY OF BASEL   (Switzerland)

^b UNIVERSITÉ DE LORRAINE   (France)

^c Inst de Mineral et Petrogr   (Switzerland)

Author keywords

Calcite; Carbon dioxide; Deuterium; Fluid inclusions; Methane oxidation; Stable isotope; Water

Indexed keywords

CALCITE; DEUTERIUM; FLUID INCLUSION; IMMISCIBILITY; ISOTOPIC COMPOSITION; METAMORPHISM; METHANE; OXIDATION; STABLE ISOTOPE; TRANSITION ZONE;

ALPS; CENTRAL ALPS; CENTRAL EUROPE; EURASIA; EUROPE; SWITZERLAND;

EID: 33846850145     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemgeo.2006.07.007     Document Type: Article

References (91)

1. Angus S., Armstrong B., and De Reuk K.M. International Thermodynamic Tables of the Fluid State-5 Methane. International Union of Pure and Applied Chemistry, Chemical Data Series. No.16. Pergamon (1976)
2. Arkai P., Ferreiro Mählmann R., Suchy V., Balogh K., Sykorova I., and Frey M. Possible effects of tectonic shear strain on phyllosilicates: a case study from the Kandersteg area, Helvetic domain, Central Alps, Switzerland. Schweiz. Mineral. Petrogr. Mitt. 82 (2002) 273-290
3. Arkai P., Livi K.J.T., Frey M., Brukner-Wein A., and Sajgo C. White micas with mixed interlayer occupancy: A possible cause of pitfalls in applying illite Kübler index ("crystallinity") for the determination of metamorphic grade. Eur. J. Mineral. 16 (2004) 469-482
4. Badertscher N., Abart R., Burkhard M., and McCaig A. Fluid flow pathways along the Glarus overthrust derived from stable and Sr-isotope patterns. Am. J. Sci. 302 (2002) 517-547
5. 2-NaCl system. Chem. Geol. 154 (1999) 225-236
6. Bakker R.J. Package FLUIDS 1. Computer programs for analysis of fluid inclusion data and for modelling bulk fluid properties. Chem. Geol. 194 (2003) 3-23
7. 2O-NaCl solutions. Geochim. Cosmochim. Acta 57 (1993) 683-684
8. Bodnar R.J. Reequilibration of fluid inclusions. Mineralogical Association of Canada. Fluid inclusions, Analysis and Interpretation vol. 32 (2003) 213-231
9. Bottinga Y. Calculated fractionation factors for carbon and hydrogen isotope exchange in the system calcite-carbon dioxide-graphite-methane-hydrogen-water vapor. Geochim. Cosmochim. Acta 33 (1969) 49-64
10. 2-NaCl fluids at high pressures and temperatures. Geochim. Cosmochim. Acta 47 (1983) 1247-1275
11. Breitschmid A. Diagenese und schwache Metamorphose in den sedimentären Abfolgen der Zentralschweizer Alpen (Vierwaldstätter See, Urirotstock). Eclogae Geol. Helv. 75 2 (1982) 331-380
12. Burkhard M. L'Helvétique de la bordure occidentale du massif de l'Aar (évolution tectonique et métamorphique). Eclogae Geol. Helv. 81 1 (1988) 63-114
13. Burkhard M., and Kerrich R. Fluid regimes in the deformation of the Helvetic nappes, Switzerland, as inferred from stable isotope data. Contrib. Mineral. Petrol. 99 (1988) 416-429
14. 2O system: I. Pure systems from 0 to 1000 °C and 0 to 8000 bar. Geochim. Cosmochim. Acta 56 (1992) 2605-2617
15. 2O system: II. Mixtures from 50 to 1000 °C and 0 to 1000 bar. Geochim. Cosmochim. Acta 56 (1992) 2619-2631
16. Dubessy J., Poty B., and Ramboz C. Advances in C-O-H-N-S fluid geochemistry based on micro-Raman spectrometric analysis of fluid inclusions. Eur. J. Mineral. 1 (1989) 517-534
17. Dubessy J., Buschaert S., Lamb W., Pironon J., and Thiéry R. Methane-bearing aqueous fluid inclusions: Raman analysis, thermodynamic modelling and application to petroleum basins. Chem. Geol. 173 (2001) 193-205
18. Essene E.J., and Peacor D.R. Clay mineral thermometry - a critical perspective. Clays Clay Miner. 43 5 (1995) 540-553
19. Faure K. δD values of fluid inclusion water in quartz and calcite ejecta from active geothermal systems: do values reflect those of original hydrothermal water?. Econ. Geol. 98 (2003) 657-660
20. Frey M. Very low-grade metamorphism of clastic sedimentary rocks. In: Frey M. (Ed). Low Temperature Metamorphism (1987), Blackie and Son Ltd, Glasgow
21. Frey M. Discontinuous inverse metamorphic zonation, Glarus Alps, Switzerland: evidence from illite "crystallinity" data. Schweiz. Mineral. Petrogr. Mitt. 68 (1988) 171-183
22. Frey M., and Ferreiro Mählmann R. Alpine metamorphism of the Central Alps. Schweiz. Mineral. Petrogr. Mitt. 76 (1999) 159-164
23. Frey M., and Robinson D.B. Low-grade Metamorphism (1999), Blackwell Science 313 pp.
24. Frey M., Bucher K., Franck E., and Mullis J. Alpine metamorphism along the Geotraverse Basel-Chiasso - a review. Eclogae Geol. Helv. 73 2 (1980) 527-546
25. Frey M., Teichmüller M., Teichmüller R., Mullis J., Künzi B., Breitschmid A., Gruner U., and Schwizer B. Very low-grade metamorphism in external parts of the Central Alps: illite crystallinity, coal rank and fluid inclusion data. Eclogae Geol. Helv. 73 1 (1980) 173-203
26. Gautschi A., Faber E., Meyer J., Mullis J., Schenker F., and Ballentine C. Hydrocarbon and noble gases in fluid inclusions of alpine calcite veins - implications for hydrocarbon exploration. Bull. Swiss. Assoc. Petrol. Geol. Eng. 56 131 (1990) 13-36
27. 4 under geothermal conditions. Geochim. Cosmochim. Acta 46 (1982) 159-165
28. Gilg H.A., and Sheppard S.M.F. Hydrogen isotope fractionation between kaolinite and water revisited. Geochim. Cosmochim. Acta 60 3 (1996) 529-533
29. Gleeson S., Grant K., and Roberts S. Fluid inclusion δD in quartz does not always indicate the source of palaeo-hydrothermal fluids. J. Conf. Abstr. 5 (2000) 445
30. 4 fluid inclusions. Chem. Geol. 194 (2003) 41-49
31. Hoefs J., and Frey M. The isotopic composition of carbonaceous matter in a metamorphic profile from the Swiss Alps. Geochim. Cosmochim. Acta 40 (1976) 945-951
32. Horibe Y., and Craig H. D/H fractionation in the system methane-hydrogen-water. Geochim. Cosmochim. Acta 59 24 (1995) 5209-5217
33. 4 at elevated temperatures. Geochim. Cosmochim. Acta 65 12 (2001) 1907-1919
34. Hunzicker J.C., Frey M., Clauer N., Dallmeyer R.D., Friedrichsen H., Flehmig W., Hochstrasser K., Roggwiler P., and Schwander H. The evolution of illite to muscovite: mineralogical and isotopic data from the Glarus Alps, Switzerland. Contrib. Mineral. Petrol. 92 (1986) 157-180
35. Hurai V., Kihle J., Kotulova J., Marko F., and Swierczewska A. Origin of methane in quartz crystals from the Tertiary accretionary wedge and fore-arc basin of the Western Carpathians. Appl. Geochem. 17 (2002) 1259-1271
36. Jaboyedoff M., Kübler B., and Thélin P. An empirical Scherrer equation for weakly swelling mixed-layer minerals, especially illite-smectite. Clay Miner. 34 4 (1999) 601-617
37. Kasemann S., Meixner A., Rocholl A., Vennemann T., Schmitt A., and Wiedenbeck M. Boron and oxygen isotope composition of certified reference materials NIST SRM 610/612, and reference materials JB-2G and JR-2G. Geostand. Newsl. 25 (2001) 405-416
38. Kesler S.E., Vennemann T.W., Frederickson C., Breithaupt A., Vazquez R., and Furman F.C. Hydrogen and oxygen isotope evidence for origin of MVT-forming brines, Southern Appalachians. Geochim. Cosmochim. Acta 61 (1997) 1513-1523
39. Kisch H.J. Illite crystallinity: recommendations on sample preparation, X-ray diffraction settings, and interlaboratory samples. J. Metamorph. Geol. 9 (1991) 665-670
40. Krumgalz B.S., Pogorelsky R., and Pitzer K.S. Volumetric properties of single aqueous electrolytes from zero to saturation concentration at 298.15 K represented by Pitzer's ion-interaction equations. J. Phys. Chem. Ref. Data 25 (1996) 639-663
41. Kübler B., and Jaboyedoff M. Illite crystallinity. C. R. Acad. Sci. 331 (2000) 75-89
42. Lemmlein G.G. The origin of "white-band" quartz. O proiskhozhdenii ploskich kvartsev s «beloi polosoi». Vopr. Mineral. Geokhim. Petrogr. (Izdat Akad. Nauk SSSR, Moskva) (1946) 98-110 (in Russian)
43. Matsuhisa Y., Goldsmith J.R., and Clayton R.N. Oxygen isotopic fractionation in the system quartz-albite-anorthite-water. Geochim. Cosmochim. Acta 43 (1979) 1131-1140
44. Mazurek M. Evolution of gas and aqueous fluid in low-permeability argillaceous rocks during uplift and exhumation of the central Swiss Alps. Appl. Geochem. 15 (1999) 223-246
45. Mullis J. Das Wachstumsmilieu der Quarzkristalle im Val d'Illiez (Wallis Schweiz). Schweiz. Mineral. Petrogr. Mitt. 56 (1976) 219-268
46. Mullis J. The system methane-water as a geological thermometer and barometer from the external part of the Central Alps. Bull. Minéral. 102 (1979) 526-536
47. Mullis J. Fluid inclusion studies during very low-grade metamorphism. In: Frey M. (Ed). Low Temperature Metamorphism (1987), Blackie, Glasgow 162-199
48. Mullis J. P-T-t path of quartz formation in extensional veins of the Central Alps. Schweiz. Mineral. Petrogr. Mitt. 76 (1996) 159-164
49. Mullis J., Dubessy J., Poty B., and O'Neil J. Fluid regimes during late stages of a continental collision: physical, chemical, and stable isotope measurements of fluid inclusions in fissure quartz from a geotraverse through the Central Alps, Switzerland. Geochim. Cosmochim. Acta 58 10 (1994) 2239-2267
50. Mullis J., Rahn M., Schwer P., de Capitani C., Stern W.B., and Frey M. Correlation of fluid inclusion temperatures with illite "crystallinity" data and clay mineral chemistry in sedimentary rocks from the external part of the Central Alps. Schweiz. Mineral. Petrogr. Mitt. 82 (2002) 325-340
51. Mullis J., Wolf M., and Ferreiro Mählmann R. Geophys. Res. Abstr. 5 (2003) 04334
52. Pfiffner O.A. Evolution of the north Alpine foreland basin in the Central Alps. Spec. Publ. Int. Assoc. Sedimentol. 8 (1986) 219-228
53. Pichavant M., Ramboz C., and Weisbrod A. Fluid immiscibility in natural processes: use and misuse of fluid inclusion data. I. Phase equilibria analysis - a theoretical and geometrical approach. Chem. Geol. 37 (1982) 1-27
54. Poty B., Leroy J., and Jachimowicz L. Un nouvel appareil pour la mesure des températures sous le microscope: L'installation de la platine microthermométrique CHAIXMECA. Bulletin de la SFMC 99 (1976) 182-186
55. Rahn M., Mullis J., Erdelbrock K., and Frey M. Very low-grade metamorphism of the Taveyanne greywacke, Glarus Alps, Switzerland. J. Metamorph. Geol. 12 (1994) 625-641
56. Rahn M., Mullis J., Erdelbrock K., and Frey M. Alpine metamorphism in the North Helvetic Flysch of the Glarus Alps. Eclogae Geol. Helv. 88 1 (1995) 157-178
57. Rahn M.K., Hurford A.J., and Frey M. Rotation and exhumation of a thrust plane: apatite fission-track data from the Glarus thrust, Switzerland. Geology 25 7 (1997) 599-602
58. Ramboz C., Pichavant M., and Weisbrod A. Fluid immiscibility in natural processes: use and misuse of fluid inclusion data. II. Interpretation of fluid inclusion data in terms of immiscibility. Chem. Geol. 37 (1982) 39-48
59. Ramsay J.G. Folding and Fracturing of Rocks (1967), McGraw-Hill
60. Ramsay J.G. The crack-seal mechanism of rock deformation. Nature 284 (1980) 135-139
61. Ramsay J.G. In: London T.G.S.o. (Ed). Tectonics of the Helvetic Nappes, Thrust and Nappe Tectonics (1981) 293-309
62. Ring U., Brandon M.T., and Ramthun A. Solution-mass-transfer deformation adjacent to the Glarus Thrust, with implications for the tectonic evolution of the Alpine wedge in eastern Switzerland. J. Struct. Geol. 23 (2001) 1491-1505
63. Schmid S.M. The Glarus overthrust: field evidence and mechanical model. Eclogae Geol. Helv. 68 2 (1975) 247-280
64. Schmidt D., Livi K.J.T., and Frey M. Reaction progress in chloritic material: an electron microbeam study of the Taveyanne greywacke, Switzerland. J. Metamorph. Geol. 17 (1999) 229-241
65. Schoell M. The hydrogen and carbon isotopic composition of methane from natural gases of various origins. Geochim. Cosmochim. Acta 44 (1980) 649-661
66. Schwab V., Spangenberg J.E., and Grimalt J.O. Chemical and carbon isotopic evolution of hydrocarbons during prograde metamorphism from 100 °C to 550 °C: case study in the Liassic black shale formation of Central Swiss Alps. Geochim. Cosmochim. Acta 69 7 (2005) 1825-1840
67. Sharp Z.D. Application of stable isotope geochemistry to low-grade metamorphic rocks. In: Frey M., and Robinson D.B. (Eds). Low-Grade Metamorphism (1999), Blackwell Science
68. Sharp Z.D., and Kirschner D.L. Quartz-calcite oxygen isotope thermometry: a calibration based on natural isotopic variations. Geochim. Cosmochim. Acta 58 21 (1994) 4491-4501
69. Sharp Z.D., Frey M., and Livi K.J.T. Stable isotope variations (H, C, O) in a prograde metamorphic Triassic red bed formation Central Swiss Alps. Schweiz. Mineral. Petrogr. Mitt. 75 (1995) 147-161
70. Sharp Z.D., Atudorei V., and Durakiewicz T. A rapid method for determination of hydrogen and oxygen isotope ratios from water and hydrous minerals. Chem. Geol. 178 (2001) 197-210
71. Sheppard S.M.F. Characterization and isotopic variations in natural waters. In: Valley J.W., Taylor H.P., and O'Neil J.R. (Eds). Stable Isotopes in High Temperature Geological Processes (1986), Mineralogical Society of America, Chelsea 165-183
72. Sheppard S.M.F., and Gilg H.A. Stable isotope geochemistry of Clay Miner. Clay Miner. 31 (1996) 1-24
73. Simon K. Does δD from fluid inclusion in quartz reflect the original hydrothermal fluid?. Chem. Geol. 177 (2001) 483-495
74. Soave G. Equilibrium constants from a modified Redlich-Kwong equation of state. Chem. Eng. Sci. 27 (1972) 1197-1203
75. Spötl C., and Vennemann T. Continuous-flow IRMS analysis of carbonate minerals. Rapid Commun. Mass Spectrom. 17 (2003) 1004-1006
76. Stach E., Mackowsky M.-T., Teichmüller M., Taylor G.H., Chandra D., and Teichmüller R. Stach's Textbook of Coal Petrology. third ed (1982), Gebrüder Borntraeger, Berlin
77. Stalder H.A., and Touray J.C. Fensterquarze mit Methan-Einschlüssen aus dem westlichen Teil der schweizerischen Kalkalpen. Schweiz. Mineral. Petrogr. Mitt. 50 1 (1970) 109-130
78. 4-zone in the External part of the Central Alps, Switzerland.
79. 2 fluid inclusions: modelling for T < 31 °C and P > 400 bars. Eur. J. Mineral. 6 (1994) 753-771
80. 2 system. Geochim. Cosmochim. Acta 58 (1994) 1073-1082
81. Trümpy R. Die helvetischen Decken der Ostschweiz: Versuch einer palinspastischen Korrelation und Ansätze zu einer kinematischen Analyse. Eclogae Geol. Helv. 62 1 (1969) 105-142
82. Vazquez R., Vennemann T.W., Kesler S.E., and Russell N. Carbon and oxygen isotope halos in the host limestone, El Mochito Zn, Pb (Ag) skarn massive sulfide/oxide deposit, Honduras. Econ. Geol. 93 (1998) 15-31
83. Vrolijk P., Myers G., and Moore J.C. Warm fluid migration along tectonic melanges in the Kodiak accretionary complex, Alaska. J. Geophys. Res. 93 B9 (1988) 10313-10324
84. Wang H., Frey M., and Stern W.B. Diagenesis and metamorphism of Clay Miner. in the Helvetic Alps of Eastern Switzerland. Clays Clay Miner. 44 1 (1996) 96-112
85. Warr L.N., and Rice A.H.N. Interlaboratory standardization and calibration of clay mineral crystallinity and crystallite size data. J. Metamorph. Geol. 12 (1994) 141-152
86. Whiticar M.J. A geochemical perspective of natural gas and atmospheric methane. Org. Geochem. 16 (1990) 531-547
87. Whiticar M.J. Correlation of natural gases with their sources. In: Magoon L., and Dow W. (Eds). The Petroleum System - From Source to Trap. AAPG Memoir vol. 60 (1994) 261-284
88. Whiticar M.J. Carbon and hydrogen isotope systematics of bacterial formation and oxidation of methane. Chem. Geol. 161 (1999) 291-314
89. 2 reduction vs acetate fermentation - isotope evidence. Geochim. Cosmochim. Acta 50 (1986) 693-709
90. Wyss R. Der Gasausbruch aus einer Erdsondenbohrung in Wilen (OW). Bull. Angew. Geol. 6 1 (2001) 25-40
91. Zwahlen P. Das Bundstock-Element, eine diskontinuierliche helvetische Teildecke an der Kandertal-Störung. Eclogae Geol. Helv. 86 1 (1993) 65-86