Solubility and microstructural development of TiO2-containing 3Al2O3·2SiO2 and 2Al2O3·SiO2 mullites obtained from single-phase gels

Journal of the European Ceramic Society

Volumn 27, Issue 7, 2007, Pages 2647-2654

  Ruiz de Sola, Esther ^a   Serrano, Francisco Javier ^a   Delgado Pinar, Estefanía ^a   Reventós, María Mercedes ^a   Pardo, Ana Isabel ^a   Kojdecki, Marek Andrzej ^b   Amigó, José María ^a   Alarcón, Javier ^a  

^a UNIVERSITY OF VALENCIA   (Spain)

^b MILITARY UNIVERSITY OF TECHNOLOGY   (Poland)

Author keywords

Microstructure final; Mullite; Sol gel processes; Solid solutions

Indexed keywords

ANISOTROPY; GRAIN GROWTH; INFRARED SPECTROSCOPY; LATTICE CONSTANTS; SOL-GELS; SOLID SOLUTIONS; SOLUBILITY;

GEL PRECURSOR; MULLITES; SEMIALKOXIDE METHOD;

TITANIUM OXIDES;

ANISOTROPY; GRAIN GROWTH; INFRARED SPECTROSCOPY; LATTICE CONSTANTS; SOL-GELS; SOLID SOLUTIONS; SOLUBILITY; TITANIUM OXIDES;

EID: 33846798212     PISSN: 09552219     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jeurceramsoc.2006.10.015     Document Type: Article

References (30)

1. Aksay I.A., Dabbs D.M., and Sarikaya M. Mullite for structural, electronic and optical applications. J. Am. Ceram. Soc. 74 (1991) 2343-2358
2. Angel R.J., and Prewitt C.T. Crystal-structure of mullite: a re-examination of the average structure. Am. Mineral. 71 (1986) 1476-1482
3. Cameron W.E. Mullite: a substituted alumina. Am. Mineral. 62 (1977) 747-755
4. Rager H., Schneider H., and Graetsch H. Chromium incorporation in mullite. Am. Mineral. 75 (1990) 392-397
5. Schneider H. Zirconium incorporation in mullite. N. Jb. Miner. Mh. 4 (1986) 172-180
6. Schneider H., and Vasudevan R. Structural deformation of manganese substituted mullites: X-ray line broadening and lattice parameter studies. N. Jb. Miner. Mh. 4 (1989) 165-178
7. Saalfeld H., and Gerlach H. Solid-solution and optical properties of (Al, Ge)-mullites. Z. Kristallogr. 195 (1991) 65-73
8. Meng G.Y., and Huggins R.A. A new chemical method for preparation of both pure and doped mullite. Mater. Res. Bull. 18 (1983) 581-588
9. Nass R., Tkalcec E., and Ivankovic H. Single-phase mullite gels doped with chromium. J. Am. Ceram. Soc. 78 (1995) 3097-3106
10. 2). J. Am. Ceram. Soc. 43 (1960) 267-273
11. 2. Trans. Br. Ceram. Soc. 73 (1974) 73-75
12. Schneider H. Transition metal distribution in mullite. In: Somiya S., Davis R.F., and Pask J.A. (Eds). Ceramic Transactions, Vol 6, Mullite and Mullite Matrix Composites (1990), American Ceramic Society, Westerville, OH 135-157
13. 3-doped aluminosilicate gels. J. Am. Ceram. Soc. 80 (1997) 1551-1559
14. Hong S.H., and Messing G.L. Anisotropic grain growth in diphasic-gel-derived titania-doped mullite. J. Am. Ceram. Soc. 81 (1998) 1269-1277
15. Sales M., Valentin C., and Alarcón J. Spinel-mullite composites with optical properties. J. Sol-Gel Sci. Technol. 8 (1997) 871-875
16. 4 spinel-mullite composites by sol-gel. J. Am. Ceram. Soc. 80 (1997) 1798-1804
17. Sales M., Valentin C., and Alarcón J. Cobalt aluminate spinel-mullite composites synthesized by sol-gel. J. Eur. Ceram. Soc. 17 (1997) 41-47
18. 2 mullite formation and microstructure from gels. J. Mater. Sci. 33 (1998) 4435-4446
19. Li D.X., and Thomson W.J. Mullite formation kinetics of a single-phase gel. J. Am. Ceram. Soc. 73 (1990) 964-969
20. Huling J.C., and Messing G.L. Epitactic nucleation of spinel in aluminosilicate gels and its effect on mullite crystallization. J. Am. Ceram. Soc. 74 (1991) 2374-2381
21. Gerardin C., Sundaresan S., Benziger J., and Navrotsky A. Structural investigation and energetics of mullite formation from sol-gel precursors. Chem. Mater. 6 (1994) 160-170
22. Parmentier J., and Vilminot S. Influence of synthesis and composition on mullite crystallization. Chem. Mater. 9 (1997) 1134-1137
23. Taylor A., and Holland D. The chemical synthesis and crystallisation sequence of mullite. J. Non-Cryst. Solids 152 (1993) 1-17
24. Ruiz de Sola E., Torres F.J., and Alarcón J. Thermal evolution and microstructural study of 2:1 mullites from monophasic gels. J. Eur. Ceram. Soc. 26 (2006) 2279-2284
25. Huling J.C., and Messing G.L. Chemistry-crystallization relations in molecular mullite gels. J. Non-Cryst. Solids 147/148 (1992) 213-221
26. Ruiz de Sola E., Torres F.J., Estevan F., and Alarcón J. Effect of thermal treatment on the structural evolution of 3:2 and 2:1 mullite monophasic gels. J. Non-Cryst. Solids 351 (2005) 1202-1209
27. Baudin C., and Moya J.S. Influence of titanium oxide on the sintering and microstructural evolution of mullite. J. Am. Ceram. Soc. 67 (1984) C134-C136
28. 4. J. Solid State Chem. 112 (1994) 381-386
29. Percival H.J., Duncan J.F., and Foster P.K. Interpretation of kaolinite-mullite reaction sequence from infrared-absorption spectra. J. Am. Ceram. Soc. 57 (1974) 57-61
30. Joe I.H., Vasudevan A.K., Aruldhas G., Damodaran A.D., and Warrier K.G.K. J. Solid State Chem. 131 (1997) 181-184