Polymorphic occurrence and crystallization rates of tristearin/tripalmitin mixtures under non-isothermal conditions

European Journal of Lipid Science and Technology

Volumn 109, Issue 1, 2007, Pages 49-60

  Himawan, Chrismono ^a   MacNaughtan, William ^b   Farhat, Imad A ^b   Stapley, Andrew G F ^a  

^a LOUGHBOROUGH UNIVERSITY   (United Kingdom)

^b UNIVERSITY OF NOTTINGHAM   (United Kingdom)

Author keywords

Crystallization kinetics; Differential scanning calorimetry (DSC); Light microscopy; Metastable zone width; X ray diffraction (XRD)

Indexed keywords

EID: 33846695837     PISSN: 14387697     EISSN: 14389312     Source Type: Journal    
DOI: 10.1002/ejlt.200600179     Document Type: Article

References (17)

1. T. V. Chan, G. D. Shyu, A. I. Isayev: Master curve approach to polymer crystallization kinetics. Polym Eng Sci. 1995, 35, 733-740.
2. K. W. Smith, F. W. Cain, G. Talbot: Kinetic analysis of nonisothermal differential scanning calorimetry of 1,3-dipalmitoyl-2-oleoylglycerol. J Agric Food Chem. 2005, 53, 3031-3040.
3. W. MacNaughtan, I. A. Farhat, C. Himawan, V. M. Starov, A. G. F. Stapley: A differential scanning calorimetry study of crystallization kinetics of tripalmitin-tristearin mixtures. J Am Oil Chem Soc. 2006, 83, 1-9.
4. G. Mazzanti, A. G. Marangoni, S. H. J. Idziak: Modeling phase transitions during the crystallization of a multicomponent fat under shear. Phys Rev E. 2005, 71, 041607.
5. M. Kellens, W. Meeussen, A. Hammersley, H. Reynaers: Synchrotron radiation investigations of the polymorphic transitions in saturated monoacid triglycerides. Part 2: Poly morphism study of a 50:50 mixture of tripalmitin and tristearin during crystallization and melting. Chem Phys Lipids. 1991, 58, 145-158.
6. M. Kellens, H. Reynaers: Study of the polymorphism of saturated monoacid triglycerides. 2. Polymorphic behavior of a 50/50 mixture of tripalmitin and tristearin. Fett Wiss Technol Fat Sci Technol. 1992, 94, 286-293.
7. K. Sato, S. Ueno: Molecular interactions and phase behavior of polymorphic fats. In: Crystallization Processes in Fats and Lipid Systems. Eds. N. Garti, K. Sato, Marcel Dekker, New York, NY (USA) 2001, pp. 177-209.
8. J. D. Menczel: A unique procedure for calibrating power compensation DSCs on cooling. Perkin Elmer Thermal Analysis News 1994, 9, 6-7.
9. E. S. Lutton: Phase behavior of triglyceride mixtures involving primarily tristearin, 2-oleyldistearin, and triolein. J Am Oil Chem Soc. 1955, 32, 49-53.
10. L. Hernqvist: Crystal structures of fats and fatty acids. In: Crystallization and Polymorhism of Fats and Fatty Acids. Eds. N. Garti, K. Sato, Marcel Dekker, New York, NY (USA) 1988, pp. 97-137.
11. M. Takeuchi, S. Ueno, K. Sato: Synchrotron radiation SAXS/ WAXS study of polymorph-dependent phase behavior of binary mixtures of saturated monoacid triacylglycerols. Cryst Growth Des. 2003, 3, 369-374.
12. P. Rousset, M. Rappaz, E. Minner: Polymorphism and solidification kinetics of the binary system POS-SOS. J Am Oil Chem Soc. 1998, 75, 857-864.
13. A. G. Marangoni, T. C. Aurand, S. Martini, M. Ollivon: A probabilistic approach to model the nonisothermal nucleation of triacylglycerol melts. Cryst Growth Des. 2006, 6, 1199-1205.
14. C. Himawan, V. M. Starov, A. G. F. Stapley: Thermodynamic and kinetic aspects of fat crystallization. Adv Colloid Interf Sci. 2006, 122, 3-33.
15. K. Sato, T. Arishima, Z. H. Wang, K. Ojima, N. Sagi, H. Mori: Polymorphism of POP and SOS. 1. Occurrence and polymorphic transformation. J Am Oil Chem Soc. 1989, 66, 664-674.
16. D. Aquilano, G. Sgualdino: Fundamental aspects of equilibrium and crystallization kinetics. In: Crystallization Processes in Fats and Lipid Systems. Eds. N. Garti, K. Sato, Marcel Dekker, New York, NY (USA) 2001, pp. 1-51.
17. M. Kellens, W. Meeussen, H. Reynaers: Study of the polymorphism and the crystallization kinetics of tripalmitin: A microscopic approach. J Am Oil Chem Soc. 1992, 69, 906-911.