Sodium zinc hydroxide sulfite with a novel Zn3OH geometry

Inorganic Chemistry

Volumn 45, Issue 26, 2006, Pages 10410-10412

  Nguyen, Dan Tam ^a   Bu, Xianhui ^a  

^a CALIFORNIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROXIDE; SULFITE; UNCLASSIFIED DRUG; ZINC DERIVATIVE; ZINC HYDROXIDE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY;

HYDROXIDES; MOLECULAR STRUCTURE; SULFITES; ZINC COMPOUNDS;

EID: 33846481880     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic061672e     Document Type: Article

References (17)

1. (a) Chen, L.; Bu, X. Chem. Mater. 2006, 18, 1857.
2. (b) Chen, L.; Bu, X. Inorg. Chem. 2006, 45, 4654.
3. (c) Gier, T. E.; Bu, X.; Wang, S.; Stucky, G. D. J. Am. Chem. Soc. 1996, 118, 3039.
4. (a) Johnstone, J. A.; Harrison, W. T. A. Inorg. Chem. 2004, 43, 4567.
5. (b) Gordon, L. E.; Harrison, W. T. A. Inorg. Chem. 2004, 43, 1808.
6. Allen, F. H. Acta Crystallogr. 2002, B58, 380.
7. (a) Rosi, N. L.; Kim, J.; Eddaoudi, M.; Chen, B.; O'Keeffe, M.; Yaghi, O. M. J. Am. Chem. Soc. 2005, 127, 1504.
8. (b) Mukherjee, P. S.; Min, K. S.; Stang, P. J. Inorg. Chem. 2004, 43, 6345.
9. (c) Hanson, K.; Calin, N.; Bugaris, D.; Scancella, M.; Sevov, S. C. J. Am. Chem. Soc. 2004, 126, 10502.
10. (a) Livage, C.; Egger, C.; Ferey, G. Chem. Mater. 2001, 13, 410.
11. (b) Long, L.; Chen, X.; Tong, M.; Sun, Z.; Ren, Y.; Huang, R.; Zheng, L. J. Chem. Soc., Dalton Trans. 2001, 2888.
12. In a typical synthesis, a total of 0.1236 g of zinc carbonate, 0.2583 g of sodium sulfite, and 5.288 g of water were mixed in a 23-mL Teflon-lined stainless steel autoclave and stirred for 30 min. The pH of the resulting mixture was adjusted to 6.79 using 0.2429 g of 1,4-bis(3-aminopropyl)piperazine and 0.254 g of acetic acid. The vessel was sealed and heated at 120°C for 7 days. After cooling to room temperature, clear hexagonal-prism-shaped crystals were obtained with a 32.8% yield.
13. max = 90°, R(F′) = 1.89% for 29 parameters and 1094 reflections with I > 2σ(I).
14. (a) Baerlocher, Ch.; Meier, W. M.; Olson, D. H. Atlas of Zeolite Framework Types; Elsevier: Amsterdam, The Netherlands, 2001.
15. (b) O'Keeffe, M.; Hyde, B. G. Crystal Structures, I. Patterns and Symmetry; Mineralogical Society of America: Washington, DC, 1996.
16. Brown, I. D.; Altermatt, D. Acta Crystallogr. 1985, B41, 244.
17. The X-ray-derived bond distances involving H sites are less accurate because of the asymmetric distribution of the electron density around the H nucleus.