Determination of organochlorine pesticides and polychlorinated biphenyls in human serum using headspace solid-phase microextraction and gas chromatography-electron capture detection

Journal of Chromatography B: Analytical Technologies in the Biomedical and Life Sciences

Volumn 846, Issue 1-2, 2007, Pages 298-305

  López, Raul ^a   Goñi, Fernando ^b   Etxandia, Arsenio ^c   Millán, Esmeralda ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^b Direccion de Salud de Guipuzcoa   (Spain)

^c Laboratorio Normativo de Salud Publica   (Spain)

Author keywords

Central composite design; GC ECD; Headspace solid phase microextraction; Human serum; Organochlorine pesticides (OCPs); Plackett Burman design; Polychlorinated biphenyls (PCBs)

Indexed keywords

BODY FLUIDS; DRUG PRODUCTS; ELECTRONS; EXTRACTION; GAS CHROMATOGRAPHY; OPTIMIZATION;

CENTRAL COMPOSITE DESIGN; GC-ECD; HEADSPACE SOLID PHASE MICROEXTRACTION; HUMAN SERUM; ORGANOCHLORINE PESTICIDES (OCP); PLACKETT BURMAN DESIGN; POLYCHLORINATED BIPHENYL (PCB);

PESTICIDES;

1,1 DICHLORO 2,2 BIS(4 CHLOROPHENYL)ETHYLENE; ORGANOCHLORINE PESTICIDE; POLYCHLORINATED BIPHENYL DERIVATIVE; SOLVENT;

ACCURACY; ACIDITY; ARTICLE; CHEMICAL ANALYSIS; ELECTRON CAPTURE DETECTION; EXTRACTION; GAS CHROMATOGRAPHY; HUMAN; PRIORITY JOURNAL; RELIABILITY; SCREENING; SERUM; SOLID PHASE MICROEXTRACTION; TEMPERATURE; VALIDATION PROCESS;

GAS CHROMATOGRAPHY-MASS SPECTROMETRY; HUMANS; HYDROCARBONS, CHLORINATED; PESTICIDES; POLYCHLORINATED BIPHENYLS; REFERENCE STANDARDS; REPRODUCIBILITY OF RESULTS;

EID: 33846438260     PISSN: 15700232     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jchromb.2006.09.009     Document Type: Article

References (29)

1. Stockholm Convention on Persistent Organic Pollutants, http://www.pops.int/documents/convtext/context-en.pdf.
2. U.S. Environmental Protection Agency, Polychlorinated biphenyls (PCBs), http://www.epa.gov/opptintr/pcb/effects.html, last updated on September 8th, 2004.
3. Cruz S., Lino C., and Silveira M.I. Sci. Total Environ. 317 (2003) 23
4. Axmon A., Rylander L., Strömberg U., Jönsson B., Nilsson-Ehle P., and Hagmar L. Environ. Res. 96 (2004) 186
5. Bates M.N., Buckland S.J., Garrett N., Ellis H., Needham L.L., Patterson Jr. D.G., Turner W.E., and Russell D.G. Chemosphere 54 (2004) 1431
6. Apostoli P., Magoni M., Bergonzi R., Carasi S., Indelicato A., Scarcella C., and Donato F. Chemosphere 61 (2005) 413
7. Najam A.R., Korver M.P., Williams C.C., Burse V.W., and Needham L.L. J. AOAC Int. 82 (1999) 177
8. Rogers E., Petreas M., Park J.-S., Zhao G., and Charles M.J. J. Chromatogr. B 813 (2004) 269
9. Conka K., Drobná B., Kocan A., and Petrík J. J. Chromatogr. A 1084 (2005) 33
10. Pitarch E., Serrano R., López F.J., and Hernández F. Anal. Bioanal. Chem. 376 (2003) 189
11. Covaci A., and Schepens P. Chemosphere 43 (2001) 439
12. Barr J.R., Maggio V.L., Barr D.B., Turner W.E., Sjödin A., Sandau C.D., Pirkle J.L., Needham L.L., and Patterson Jr. D.G. J. Chromatogr. B 794 (2003) 137
13. Focant J.F., Sjödin A., Turner W.E., and Patterson Jr. D.G. Anal. Chem. 76 (2004) 6313
14. Pawliszyn J. Solid-Phase Microextraction. Theory and Practice (1997), Wiley-VCH, New York
15. Ulrich S. J. Chromatogr. A 902 (2000) 167
16. Mills G.A., and Walker V. J. Chromatogr. A 902 (2000) 267
17. Shu Y.Y., Wang S.S., Tardif M., and Huang Y. J. Chromatogr. A 1008 (2003) 1
18. Li H.-P., Li G.-C., and Jen J.F. J. Chromatogr. A 1012 (2003) 129
19. Fidalgo-Used N., Centineo G., Blanco-González E., and Sanz-Medel A. J. Chromatogr. A 1017 (2003) 35
20. Dong C., Zeng Z., and Yang M. Water. Res. 35 (2005) 4204
21. López F.J., Pitarch E., Egea S., Beltran J., and Hernández F. Anal. Chim. Acta 433 (2001) 217
22. Beltran J., Pitarch E., Egea S., López F.J., and Hernández F. Chromatographia 54 (2001) 757
23. Zuba D., Parczewski A., and Reichenbächer M. J. Chromatogr. B 773 (2002) 75
24. Poli D., Manini P., Andreoli R., Franchini I., and Mutti A. J. Chromatogr. B 820 (2005) 95
25. Brereton R.G. Chemometrics. Data Analysis for the Laboratory and Chemical Plant (2003), John Wiley & Sons, Chichester
26. Aguilar C., Peñalver A., Pocurull E., Feré J., Borrull F., and Marcé R.M. J. Chromatogr. A 844 (1999) 425
27. Arambarri I., Lasa M., Garcia R., and Millán E. J. Chromatogr. A 1033 (2004) 193
28. Valor I., Pérez M., Cortada C., Apraiz D., Moltó J.C., and Font G. J. Sep. Sci. 24 (2001) 39
29. Miller J.N., and Miller J.C. Statistics and Chemometrics for Analytical Chemistry. fourth ed. (2000), Pearson Education Ltd, Harlow p. 120