Catalytic enantioselective allenylation reactions of aldehydes with tethered bis(8-quinolinolato) (TBOx) chromium complex

Journal of the American Chemical Society

Volumn 129, Issue 3, 2007, Pages 496-497

  Xia, Guoyao ^a   Yamamoto, Hisashi ^a  

^a UNIVERSITY OF CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE DERIVATIVE; CHROMIUM DERIVATIVE; QUINOLINE DERIVATIVE;

ALLENYLATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; ENANTIOSELECTIVITY; OXIDATION REDUCTION REACTION; QUANTUM YIELD; REACTION ANALYSIS;

ALDEHYDES; ALKENES; BENZALDEHYDES; CATALYSIS; CHROMIUM; MODELS, CHEMICAL; ORGANOMETALLIC COMPOUNDS; OXYQUINOLINE; STEREOISOMERISM;

EID: 33846436808     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0679578     Document Type: Article

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46. The silyl group of the propargylic bromide affected the yields and enantioselectivities. See Scheme 1 in Supporting Information.
47. See Scheme 2 in Supporting Information.
48. For example, ref 7 in comparison to entry 1 in Table 3.
49. See Scheme 3 in Supporting Information for the proposed catalytic cycle and transition structures.